Related papers: Microscopic derivation of transition-state theory …
To gain deeper insight into the dynamics of complex quantum systems we need a quantum leap in computer simulations. We can not translate quantum behaviour arising with superposition states or entanglement efficiently into the classical…
Classical phase transitions, like solid-liquid-gas or order-disorder spin magnetic phases, are all driven by thermal energy fluctuations by varying the temperature. On the other hand, quantum phase transitions happen at absolute zero…
Fluctuation Theorems are central in stochastic thermodynamics, as they allow for quantifying the irreversibility of single trajectories. Although they have been experimentally checked in the classical regime, a practical demonstration in…
The perturbative approach was adopted to develop a temperature-dependent version of non-relativistic quantum mechanics in the limit of low-enough temperatures. A generalized, self-consistent Hamiltonian was therefore constructed for an…
We consider a quantum system strongly driven by forces that are periodic in time. The theorem concerns the probability $P(e)$ of observing a given energy change $e$ after a number of cycles. If the system is thermostated by a (quantum)…
We consider the problem of quantum and classical phase transitions in double-layer quantum Hall systems at $\nu=1/m$ (m odd integers) from a long-wavelength statistical mechanics viewpoint. We derive an explicit mapping of the…
The time evolution of many physical, chemical, and biological systems can be modelled by stochastic transitions between the minima of the potential energy surface describing the system of interest. We show that in cases where there are two…
A dynamical study of the decay of a metastable state by quantum tunneling through an anisotropic, non separable, two-dimensional potential barrier is performed by the numerical solution of the time-dependent Schrodinger equation. Initial…
Recent developments in the understanding of real-time path integrals led to the development of the ``steadyon picture'' for the semi-classical calculation of quantum tunneling rates. We discuss tunneling out of a generic localized initial…
Quantum transmissions of a free particle passing through a rectangular potential barrier with dissipation are studied using a path decomposition technique. Dissipative processes strongly suppress the transmission probability at resonance…
Quantum linear response theory considers only the response of a closed quantum system to a perturbation up to first order in the perturbation. This theory breaks down when the system subjects to environments and the response up to second…
Systems that are driven out of thermal equilibrium typically dissipate random quantities of energy on microscopic scales. Crooks fluctuation theorem relates the distribution of these random work costs with the corresponding distribution for…
The simulation of open quantum systems coupled to a reservoir through multiple channels remains a substantial challenge. This kind of open quantum system arises when considering the radiationless decay of excited states that are coupled to…
In Part I [J. Chem. Phys. 138, 084108 (2013)] we derived a quantum transition-state theory by taking the t->0+ (short-time) limit of a new form of quantum flux-side time-correlation function containing a ring-polymer dividing surface. This…
Quantum phase transitions are sudden changes in the ground-state wavefunction of a many-body system that can occur as a control parameter such as a concentration or a field strength is varied. They are driven purely by the competition…
The fluctuation-dissipation theorem is a fundamental result in statistical physics that establishes a connection between the response of a system subject to a perturbation and the fluctuations associated with observables in equilibrium.…
We study the fidelity approach to quantum phase transitions (QPTs) and apply it to general thermal phase transitions (PTs). We analyze two particular cases: the Stoner-Hubbard itinerant electron model of magnetism and the BCS theory of…
The dynamics of open quantum systems is formulated in a minimally extended state space comprising the degrees of freedom of a system of interest and a finite set of non-unitary, pure-state reservoir modes. This formal structure, derived…
Interactions of quantum systems with their environment play a crucial role in resource-theoretic approaches to thermodynamics in the microscopic regime. Here, we analyze the possible state transitions in the presence of "small" heat baths…
Von Neumann entropy rate for open quantum systems is, in general, written in terms of entropy production and entropy flow rates, encompassing the second law of thermodynamics. When the open-quantum-system evolution corresponds to a quantum…