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Hybrid quantum-classical embedding methods for correlated materials simulations provide a path towards potential quantum advantage. However, the required quantum resources arising from the multi-band nature of $d$ and $f$ electron materials…

Quantum Physics · Physics 2023-01-09 Anirban Mukherjee , Noah F. Berthusen , João C. Getelina , Peter P. Orth , Yong-Xin Yao

In this paper, we propose a parallel optimization method for electronic structure calculations based on a single orbital-updating approximation. It is shown by our numerical experiments that the method is efficient and reliable for atomic…

Numerical Analysis · Mathematics 2015-11-20 Xiaoying Dai , Zhuang Liu , Xin Zhang , Aihui Zhou

We consider gradient descent and quasi-Newton algorithms to optimize the full configuration interaction (FCI) ground state wavefunction starting from an arbitrary reference state $|0 \rangle$. We show that the energies obtained along the…

Chemical Physics · Physics 2021-02-03 Carlos A. Jiménez-Hoyos

The execution of quantum algorithms on modern hardware is often constrained by noise and qubit decoherence, limiting the circuit depth and the number of gates that can be executed. Circuit optimization techniques help mitigate these…

We present quantum algorithms, for Hamiltonians of linear combinations of local unitary operators, for Hamiltonian matrix-vector products and for preconditioning with the inverse of shifted reduced Hamiltonian operator that contributes to…

Quantum Physics · Physics 2020-09-09 Zhiyong Zhang

This paper presents a quantum-enhanced optimization approach for solving optimal power flow (OPF) by integrating the interior point method (IPM) with a coherent variational quantum linear solver (CVQLS). The objective is to explore the…

Quantum Physics · Physics 2025-08-29 Farshad Amani , Amin Kargarian

Quantum computing methods for excited-state calculations remain underexplored in Noisy Intermediate-Scale Quantum (NISQ) hardware, despite their critical role in photochemistry and material science. Herein, we propose a resource-efficient…

Quantum Physics · Physics 2025-06-16 Qianjun Yao , He Li

The feedback-based algorithm for quantum optimization (FALQON) has recently been proposed to solve quadratic unconstrained binary optimization problems. This paper efficiently generalizes FALQON to tackle quadratic constrained binary…

Quantum Physics · Physics 2025-04-15 Salahuddin Abdul Rahman , Özkan Karabacak , Rafal Wisniewski

Imaginary-time evolution has been shown to be a promising framework for tackling combinatorial optimization problems on quantum hardware. In this work, we propose a classical quantum-inspired strategy for solving combinatorial optimization…

Quantum Physics · Physics 2025-12-05 Erik M. Åsgrim , Ahsan Javed Awan

We simulate the excited states of the Lipkin model using the recently proposed Quantum Equation of Motion (qEOM) method. The qEOM generalizes the EOM on classical computers and gives access to collective excitations based on quasi-boson…

Variational quantum algorithms involve training parameterized quantum circuits using a classical co-processor. An important variational algorithm, designed for combinatorial optimization, is the quantum approximate optimization algorithm.…

H\"uckel molecular orbital (HMO) theory provides a semi-empirical treatment of the electronic structure in conjugated {\pi}-electronic systems. A scalable system-agnostic execution of HMO theory on a quantum computer is reported here based…

Quantum Physics · Physics 2024-05-22 Harshdeep Singh , Sonjoy Majumder , Sabyashachi Mishra

We propose a hybrid quantum-classical algorithm for approximating the ground state and ground state energy of a Hamiltonian. Once the Ansatz has been decided, the quantum part of the algorithm involves the calculation of two overlap…

Quantum Physics · Physics 2020-10-13 Kishor Bharti

Inspired by recent advances in the manipulation of superconducting circuits coupled to mechanical modes in the quantum regime, we propose a protocol for generating superpositions of orthogonally squeezed states in a quantum harmonic…

Quantum Physics · Physics 2026-03-05 Marius K. Hope , Jonas Lidal , Francesco Massel

We present a universal algorithm for the optimal quantum state estimation of an arbitrary finite dimensional system. The algorithm specifies a physically realizable positive operator valued measurement (POVM) on a finite number of…

Quantum Physics · Physics 2009-10-30 Radoslav Derka , Vladimir Buzek , Artur Ekert

Preparation of a target quantum many-body state on quantum simulators is one of the significant steps in quantum science and technology. With a small number of qubits, a few quantum states, such as the Greenberger-Horne-Zeilinger state,…

Quantum Physics · Physics 2023-07-28 Donggyu Kim , Eun-Gook Moon

The famous, yet unsolved, Fermi-Hubbard model for strongly-correlated electronic systems is a prominent target for quantum computers. However, accurately representing the Fermi-Hubbard ground state for large instances may be beyond the…

We introduce a novel quantum optimization paradigm: the Fixed-Parameter-Count Quantum Approximate Optimization Algorithm (FPC-QAOA). It is a scalable variational framework that maintains a constant number of trainable parameters regardless…

We present a framework that formulates the quest for the most efficient quantum state tomography scheme as an optimization problem which can be solved numerically. This approach can be applied to a broad spectrum of relevant setups…

Quantum Physics · Physics 2021-12-17 Violeta N. Ivanova-Rohling , Guido Burkard , Niklas Rohling

We present a quantum algorithm for combinatorial optimization using the cost structure of the search states. Its behavior is illustrated for overconstrained satisfiability and asymmetric traveling salesman problems. Simulations with…

Quantum Physics · Physics 2007-05-23 Tad Hogg , Dmitriy Portnov