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Since hydrogen fuel involves the highest energy density among all fuels, production of this gas through the solar water splitting approach has been suggested as a green remedy for greenhouse environmental issues due to extensive consumption…

Computational Physics · Physics 2018-03-22 Meysam Makaremi , Sean Grixti , Keith T. Butler , Geoffrey A. Ozin , Chandra Veer Singh

This study deals with cubic crystals where the contents of the simple cubic unit cells are close to n$\times$n$\times$n-bcc sublattices ($n$ = 2: diamond- and zinc-blende type, $n$ = 3: $\gamma$-brasses). First-principle results on the…

Materials Science · Physics 2023-03-23 Heinrich Solbrig

The emergence of transition metal dichalcogenides (TMDs) as 2D electronic materials has stimulated proposals of novel electronic and photonic devices based on TMD heterostructures. Here we report the determination of band offsets in TMD…

Search for low-dimensional materials with unique electronic properties is important for the development of electronic devices in nano scale. Through systematic first-principles calculations, we found that the band gaps of the…

Materials Science · Physics 2018-03-23 Xiaoxuan Ma , Jun Hu , Bicai Pan

Using first-principles density functional theory calculations, we investigate a family of stable two-dimensional crystals with chemical formula $A_2B_2$, where $A$ and $B$ belong to groups IV and V, respectively ($A$ = C, Si, Ge, Sn, Pb;…

Materials Science · Physics 2018-08-01 B. Ozdamar , G. Ozbal , M. N. Cinar , K. Sevim , G. Kurt , B. Kaya , H. Sevincli

Integrating atomic quantum memories based on color centers in diamond with on-chip photonic devices would enable entanglement distribution over long distances. However, efforts towards integration have been challenging because color centers…

Using density functional theory calculations we show that the recently-synthesized, superhard diamond-like BC$_5$ is superconducting with a critical temperature of the same order than that of MgB$_2$. The average electron-phonon coupling is…

Superconductivity · Physics 2009-11-13 Matteo Calandra , Francesco Mauri

Successful synthesis of the nitrogenated holey two-dimensional structures C2N (Nat. Commun. 2015, 6, 1-7) using simply wet-chemical reaction offer a cost-effective way to generate other 2D materials with novel optical and electronic…

Materials Science · Physics 2015-05-12 Ruiqi Zhang , Bin Li , Jinlong Yang

We present a combined experimental and theoretical approach for the determination of the low-temperature valence band offset (VBO) at CdSe/ZnTe heterojunctions with underlying zincblende crystal structure. On the experimental side, the…

Materials Science · Physics 2015-06-11 Daniel Mourad , Jan-Peter Richters , Lionel Gérard , Régis André , Joël Bleuse , Henri Mariette

Several IV-VI semiconductor compounds made of heavy atoms, such as Pb$_{1-x}$Sn$_{x}$Te, may undergo band-inversion at the $L$ point of the Brillouin zone upon variation of their chemical composition. This inversion gives rise to…

Mesoscale and Nanoscale Physics · Physics 2018-05-28 A. Diaz-Fernandez , N. del Valle , F. Dominguez-Adame

The high performance of hybrid perovskite based devices is attributed to its excellent bulk-transport properties. However, carrier dynamics, especially at the metal-perovskite interface, and its influence on device operation are not widely…

Materials Science · Physics 2022-02-25 N. Ganesh , A. Z. Ashar , Sumukh Purohit , K. L. Narasimhan , K. S. Narayan

X-ray absorption (XAS) and emission (XES) spectroscopy near B-K and C-K edges have been performed on metallic (~1at%B, B-diamond) and semiconducting (~0.1at%B and N, BN-diamond) doped-diamond films. Both B-K XAS and XES spectra shows…

Using the hybrid exchange-correlation functional within the density-functional theory, we have systematically investigated the structural and electronic properties of MO (M = Be, Mg, Ca, Sr, Ba, Zn, Cd) in binary rocksalt (B1), zincblende…

Materials Science · Physics 2019-03-19 Jinying Yu , Mingke Zhang , Zihan Zhang , Shangwei Wang , Yelong Wu

Ultra-wide band gap (UWBG) materials are poised to play an important role in the future of power electronics. Devices made from UWBG materials are expected to operate at higher voltages, frequencies, and temperatures than current silicon…

Materials Science · Physics 2023-01-19 Cody Milne , Arunima Singh , Tathagata Biswas

The emerging interest in van der Waals heterostructures as new materials for opto-electronics and photonics poses questions about their stability and structure-property relations. In the framework of density-functional and many-body…

The topic of superconductivity in strongly disordered materials has attracted a significant attention. In particular vivid debates are related to the subject of intrinsic spatial inhomogeneity responsible for non-BCS relation between the…

Halide perovskites are known for their rich phase diagram and superior performance in diverse optoelectronics applications. The latter property is often attributed to the long electron-hole recombination time, whose underlying physical…

We present a polarization resolved study of the low energy band structure in the optimally doped iron pnictide superconductor Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ (T$_c$=37K) using angle resolved photoemission spectroscopy.…

Superconductivity · Physics 2013-10-22 L. A. Wray , R. Thomale , C. Platt , D. Hsieh , D. Qian , G. F. Chen , J. L. Luo , N. L. Wang , M. Z. Hasan

The modified Becke-Johnson meta-GGA potential of density functional theory has been shown to be the best exchange-correlation potential to determine band gaps of crystalline solids. However, it cannot be consistently used for the electronic…

Mesoscale and Nanoscale Physics · Physics 2020-04-02 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

For heterostructures of ultrathin, strongly correlated copper-oxide films and dielectric perovskite layers, we predict inhomogeneous electronic interface states. Our study is based on an extended Hubbard model for the cuprate film. The…

Strongly Correlated Electrons · Physics 2007-05-23 Natalia Pavlenko , Thilo Kopp