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We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…

Statistical Mechanics · Physics 2008-07-30 Antonin Coutant , S. G. Rajeev

A classical particle system coupled with a thermostat driven by an external constant force reaches its steady state when the ensemble-averaged drift velocity does not vary with time. The statistical mechanics of such a system is derived…

Statistical Mechanics · Physics 2020-12-02 Jie Yao , Yanting Wang

A numerical experiment of ideal stochastic motion of a particle subject to conservative forces and Gaussian noise reveals that the path probability depends exponentially on action. This distribution implies a fundamental principle…

Statistical Mechanics · Physics 2020-10-16 Qiuping A. Wang , Aziz El Kaabouchi

The formulation of the First and Second Principles of thermodynamics for a particle in contact with a heat bath and submitted to an external force is analyzed, by means of the Boltzmann-Lorentz kinetic equation. The possible definitions of…

Statistical Mechanics · Physics 2018-02-14 J. Javier Brey , M. J. Ruiz-Montero , Alvaro Dominguez

We present technical results required for the description and understanding of correlations and fluctuations of the empirical density and current as well as diverse time-integrated and time-averaged thermodynamic currents of diffusion…

Statistical Mechanics · Physics 2023-01-09 Cai Dieball , Aljaž Godec

We study experimentally and theoretically the probability density functions of the injected and dissipated energy in a system of a colloidal particle trapped in a double well potential periodically modulated by an external perturbation. The…

Statistical Mechanics · Physics 2008-10-21 Alberto Imparato , Pierre Jop , Artyom Petrosyan , Sergio Ciliberto

We give a perturbative analysis of Crooks relation and Jarzynski equality in an arbitrary driven quantum system weakly coupled to a heat bath. Invoking no efficient Hamiltonian nor any restriction on the form of the coupling, we derive the…

Statistical Mechanics · Physics 2017-09-15 Yi Peng , Heng Fan

We develop a general framework to investigate fluctuations of non-commuting observables. To this end, we consider the Keldysh quasi-probability distribution (KQPD). This distribution provides a measurement-independent description of the…

Quantum Physics · Physics 2017-10-13 Patrick P. Hofer

Non-equilibrium quantum thermodynamics is essential to describe new devices that operate far from the regime where the usual thermodynamical laws are obeyed. When quantum fluctuations dominate, defining and measuring work and heat, two…

We study current fluctuations in lattice gases in the macroscopic limit extending the dynamic approach for density fluctuations developed in previous articles. More precisely, we establish a large deviation principle for a space-time…

Statistical Mechanics · Physics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

We derive and solve a differential equation satisfied by the probability distribution of the work done on a single biomolecule in a mechanical unzipping experiment. The unzipping is described as a thermally activated escape process in an…

Soft Condensed Matter · Physics 2007-05-23 Alberto Imparato , Luca Peliti

The Fluctuation Theorem describes the probability ratio of observing trajectories that satisfy or violate the second law of thermodynamics. It has been proved in a number of different ways for thermostatted deterministic nonequilibrium…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

The probability density distributions for the ground states of certain model systems in quantum mechanics and for their classical counterparts are considered. It is shown, that classical distributions are remarkably improved by…

Quantum Physics · Physics 2025-01-23 Tomasz Radozycki

The probability distribution for vacuum fluctuations of the energy flux in two dimensions will be constructed, along with the joint distribution of energy flux and energy density. Our approach will be based on previous work on probability…

High Energy Physics - Theory · Physics 2025-04-11 Christopher J. Fewster , L. H. Ford

We test a hypothesis for the origin of dynamical heterogeneity in slowly relaxing systems, namely that it emerges from soft (Goldstone) modes associated with a broken continuous symmetry under time reparametrizations. We do this by…

Disordered Systems and Neural Networks · Physics 2013-10-30 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

We consider the usual Langevin equation depending on an internal time. This parameter is substituted by a first passage time of a self-similar Markov process. Then the Gaussian process is parent, and the hitting time process is directing.…

Statistical Mechanics · Physics 2011-11-15 Aleksander Stanislavsky

We analyze the microscopic evolution of a system undergoing a far-from-equilibrium thermodynamic process. Explicitly accounting for the degrees of freedom of participating heat reservoirs, we derive a hybrid result, similar in form to both…

Statistical Mechanics · Physics 2007-05-23 C. Jarzynski

We study the symmetry of large deviation functions associated with time-integrated currents in Markov pure jump processes. One current known to have this symmetry is the fluctuating entropy production and this is the content of the…

Statistical Mechanics · Physics 2012-12-03 A. C. Barato , R. Chetrite

Within path sampling framework, we show that probability distribution divergences, such as the Chernoff information, can be estimated via thermodynamic integration. The Boltzmann-Gibbs distribution pertaining to different Hamiltonians is…

Methodology · Statistics 2013-10-18 Silia Vitoratou , Ioannis Ntzoufras

In the limit of large quantum excitations, the classical and quantum probability distributions for a Schr\"odinger equation can be compared by using the corresponding WKBJ solutions whose rapid oscillations are averaged. This result is…

Quantum Physics · Physics 2016-05-18 Claude Semay , Ludovic Ducobu
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