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We develop a method in which the electronic densities of small fragments determined by Kohn-Sham density functional theory (DFT) are embedded using stochastic DFT to form the exact density of the full system. The new method preserves the…

Chemical Physics · Physics 2015-06-19 Daniel Neuhauser , Roi Baer , Eran Rabani

Density functional theory (DFT) is a widespread and effective tool in electronic structure calculations for ground-state electron systems. Its success has prompted exploration into the use of DFT for non-collective excited states. The delta…

Chemical Physics · Physics 2025-08-12 Ethan Pollack , Rohan Maniar , John P. Perdew

Linear-response time-dependent (TD) density-functional theory (DFT) has been implemented in the pseudopotential wavelet-based electronic structure program BigDFT and results are compared against those obtained with the all-electron…

The Dicke model describes the cooperative interaction of an ensemble of two-level atoms with a single-mode photonic field and exhibits a quantum phase transition as a function of light--matter coupling strength. Extending this model by…

Quantum embedding approaches involve the self-consistent optimization of a local fragment of a strongly correlated system, entangled with the wider environment. The `energy-weighted' density matrix embedding theory (EwDMET) was established…

Strongly Correlated Electrons · Physics 2021-02-23 P. V. Sriluckshmy , Max Nusspickel , Edoardo Fertitta , George H. Booth

Understanding physical properties of quantum emitters strongly interacting with quantized electromagnetic modes is one of the primary goals in the emergent field of waveguide quantum electrodynamics (QED). When the light-matter coupling…

Quantum Physics · Physics 2023-05-30 Yuto Ashida , Takeru Yokota , Atac Imamoglu , Eugene Demler

The formalism of density functional theory (DFT) can be easily extended to the time dependent case (TDDFT). However, while in the static case the theory is well established and is expected to be, at least in principle, an exact approach for…

Condensed Matter · Physics 2007-05-23 Sandro Stringari

Density Functional Theory (DFT) is widely used for atomistic simulations. However, its reach stays limited due to several limitations such as lack of accurate exchange-correlation functional, requirement of costly O(N 3) diagonalization…

Quantum Physics · Physics 2026-05-18 Namrata Manglani , Samrit Kumar Maity , Shashank Sharma , Soham Phulare , Sanjay Wandhekar

We discuss the simulation of non-perturbative cavity-QED effects using systems of trapped ions. Specifically, we address the implementation of extended Dicke models with both collective dipole-field and direct dipole-dipole interactions,…

Quantum Physics · Physics 2020-02-28 Tuomas Jaako , Juan José Garcia-Ripoll , Peter Rabl

We analyze the methodology and the performance of subsystem density functional theory (DFT) with meta-generalized gradient approximation (meta-GGA) exchange-correlation functionals for non-bonded systems. Meta-GGA functionals depend on the…

Other Condensed Matter · Physics 2015-05-05 S. Śmiga , E. Fabiano , S. Laricchia , L. A. Constantin , F. Della Sala

We present an alternative to the Kohn-Sham formulation of density functional theory for the ground-state properties of strongly interacting electronic systems. The idea is to start from the limit of zero kinetic energy and systematically…

Strongly Correlated Electrons · Physics 2015-05-13 Paola Gori-Giorgi , Michael Seidl , G. Vignale

Photonic states with large and fixed photon numbers, such as Fock states, enable quantum-enhanced metrology but remain an experimentally elusive resource. A potentially simple, deterministic and scalable way to generate these states…

Quantum Physics · Physics 2019-04-17 V. Paulisch , M. Perarnau-Llobet , A. González-Tudela , J. I. Cirac

We analytically investigate the ground-state properties of two-component Bose-Einstein condensates with few ⁸⁷Rb atoms inside a high-quality cavity quantum electrodynamics. In the SU(2) representation for atom, this quantum…

Quantum Physics · Physics 2009-11-13 Gang Chen , Zidong Chen , J. -Q. Liang

Density functional theory constitutes the workhorse of modern electronic structure calculations due to its favourable computational cost despite the fact that it usually fails to describe strongly correlated systems. A particularly…

Quantum Gases · Physics 2022-05-06 Julia Liebert

Cavity modification of material properties and phenomena is a novel research field largely motivated by the advances in strong light-matter interactions. Despite this progress, exact solutions for extended systems strongly coupled to the…

Quantum Physics · Physics 2022-01-13 Vasil Rokaj , Michael Ruggenthaler , Florian G. Eich , Angel Rubio

Density functional theory (DFT) is an essential building block for modern theoretical physics, chemistry, and engineering, especially those concerning electronic properties. Through decades of development, various program packages for…

Materials Science · Physics 2022-11-21 Yusuke Nomura , Ryosuke Akashi

The development of kinetic energy functional (KEF) is known as one of the most difficult subjects in the electronic density functional theory (DFT). In particular, the sound description of chemical bonds using a KEF is a matter of great…

Chemical Physics · Physics 2025-03-03 Hideaki Takahashi

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

Quantum information theorems state that it is possible to exploit collective quantum resources to greatly enhance the charging power of quantum batteries (QBs) made of many identical elementary units. We here present and solve a model of a…

Mesoscale and Nanoscale Physics · Physics 2018-03-19 Dario Ferraro , Michele Campisi , Gian Marcello Andolina , Vittorio Pellegrini , Marco Polini

Quantum computers (QC) could harbor the potential to significantly advance materials simulations, particularly at the atomistic scale involving strongly correlated fermionic systems where an accurate description of quantum many-body effects…