Related papers: Dissociative Recombination of Rotationally Cold OH…
Observations of CH$^+$ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH$^+$ chemistry. Until this work, the most uncertain reaction in that chemistry was…
Cross sections and rate coefficients for the Dissociative Recombination (DR) of the NS+ ion induced by collisions with low-energy electrons are reported for temperatures between 10 and 1000 K, relevant to a large range of interstellar cloud…
We have investigated dissociative recombination (DR) of NH$^+$ with electrons using a merged beams configuration at the TSR heavy-ion storage ring located at the Max Planck Institute for Nuclear Physics in Heidelberg, Germany. We present…
We have experimentally studied dissociative recombination (DR) of electronically and vibrationally relaxed ArH$^+$ in its lowest rotational levels, using an electron--ion merged-beams setup at the Cryogenic Storage Ring. We report…
Diffuse interstellar clouds show large abundances of H_3^+ which can be maintained only by a high ionization rate of H_2. Cosmic rays are the dominant ionization mechanism in this environment, so the large ionization rate implies a high…
Dielectronic recombination (DR) is the dominant recombination process for most heavy elements in photoionized clouds. Accurate DR rates for a species can be predicted when the positions of autoionizing states are known. Unfortunately such…
New high-resolution dissociative recombination rate coefficients of rotationally cool and hot H3+ in the vibrational ground state have been measured with a 22-pole trap setup and a Penning ion source, respectively, at the ion storage ring…
Chemistry in diffuse molecular clouds relies primarily on rapid ion-molecule reactions. Formation of the initial ions, H$^+$ and H$_2^+$, is dominated by cosmic-ray ionization of H and H$_2$, making the cosmic-ray ionization rate (denoted…
We present a new method for the simultaneous calculation of the cosmic ray ionization rate, zeta(H2), and the ionization fraction, chi(e), in dense molecular clouds. A simple network of chemical reactions dominant in the creation and…
We have obtained estimates for the cosmic-ray ionization rate (CRIR) in the Galactic disk, using a detailed model for the physics and chemistry of diffuse interstellar gas clouds to interpret previously-published measurements of the…
This work presents our theoretical study of the dissociative recombination (DR) of the closed-shell diatomic system CF$^+$ based on an approach recently applied to the CH$^+$ molecule. Our extended treatment uses the UK R-matrix theory and…
In the interstellar medium, cosmic rays (CRs) generate a field of ultraviolet (UV) photons via the excitation and subsequent radiative decay of $\rm H_2$ molecules. This UV field is a major agent of ionization and dissociation in the inner…
The theoretical approach developed here treats uniformly the direct and indirect mechanisms of dissociative recombination (DR) in a diatomic ion. The present theory is based on electron scattering calculations performed at several…
The cosmic-ray ionization rate (CRIR, $\zeta_2$) is one of the key parameters controlling the formation and destruction of various molecules in molecular clouds. However, the current most commonly used CRIR tracers, such as H$_3^+$, OH$^+$,…
The HeH$^+$ cation is the simplest molecular prototype of the indirect dissociative recombination (DR) process that proceeds through electron capture into Rydberg states of the corresponding neutral molecule. This Letter develops the first…
Cross sections are presented for dissociative recombination and electron-impact vibrational excitation of the ArH+ molecular ion at electron energies appropriate for the interstellar environment. The R-matrix method is employed to determine…
The ionization fraction is an important factor in determining the chemical and physical evolution of star forming regions. In the dense, dark starless cores of such objects, the ionization rate is dominated by cosmic rays; it is therefore…
Absorption lines from the molecules OH+, H2O+, and H3+ have been observed in a diffuse molecular cloud along a line of sight near W51 IRS2. We present the first chemical analysis that combines the information provided by all three of these…
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code…
Observations of H3+ in the Galactic diffuse interstellar medium (ISM) have led to various surprising results, including the conclusion that the cosmic-ray ionization rate (zeta_2) is about 1 order of magnitude larger than previously…