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Transient opto-electrical measurements of methylammonium lead iodide (MALI) perovskite solar cells (PSCs) are performed and analyzed in order to elucidate the operating mechanisms. The current response to a light pulse or voltage pulse…

Materials Science · Physics 2016-11-22 Martin Thomas Neukom

Traditional inorganic semiconductors can be electronically doped with high precision. Conversely, there is still conjecture regarding the assessment of the electronic doping density in metal-halide perovskites, not to mention of a control…

Halide perovskites make efficient solar cells due to their exceptional optoelectronic properties, but suffer from several stability issues. The characterization of the degradation processes is challenging because of the limitations in the…

Materials Science · Physics 2022-05-25 Mike Pols , José Manuel Vicent-Luna , Ivo Filot , Adri C. T. van Duin , Shuxia Tao

Defect-assisted recombination processes are critical to understand, as they frequently limit photovoltaic (PV) device performance. However, the physical parameters governing these processes can be extremely challenging to measure, requiring…

Organic-inorganic hybrid perovskite solar cells (PSC) have demonstrated impressive performance improvement. Among the various characteristics, the time-dependent current-voltage (J-V) hysteresis allows a direct exploration of various…

Materials Science · Physics 2024-12-23 Abhimanyu Singareddy , Pradeep R. Nair

Halide perovskite optoelectronic devices suffer from chemical degradation and current-voltage hysteresis induced by migration of highly mobile charged defects. Atomic scale molecular dynamics simulations can capture the motion of these…

Materials Science · Physics 2025-05-20 Viren Tyagi , Mike Pols , Geert Brocks , Shuxia Tao

Pinpointing the origin of inefficiency can expedite the process of optimizing the efficiency of perovskite photovoltaics. However, it is challenging to discern and quantify the different loss pathways in a complete perovskite photovoltaic…

Applied Physics · Physics 2023-12-01 Minshen Lin , Xuehui Xu , Hong Tian , Yang Michael Yang , Wei E. I. Sha , Wenxing Zhong

Hysteresis in the current-voltage characteristics of hybrid organic-inorganic perovskite-based solar cells is one of the fundamental aspects of these cells that we do not understand well. One possible cause, suggested for the hysteresis, is…

Efficient parameter identification of electrochemical models is crucial for accurate monitoring and control of lithium-ion cells. This process becomes challenging when applied to complex models that rely on a considerable number of…

Systems and Control · Electrical Eng. & Systems 2024-05-20 Jianzong Pi , Samuel Filgueira da Silva , Mehmet Fatih Ozkan , Abhishek Gupta , Marcello Canova

Perovskite solar cells (PSCs) continue to be the front runner technology among emerging photovoltaic devices in terms of power conversion efficiency and application versatility. However, not only the stability but also the understanding of…

Halide perovskites have emerged as promising candidates for high-performance solar cells. This study investigates the temperature-dependent optoelectronic properties of mixed-cation mixed-halide perovskite solar cells using…

Lead iodide perovskites have attracted considerable interest in the upcoming photovoltaic technologies and optoelectronic devices. Therefore, an accurate theoretical description of the electronic and optical properties especially to…

Materials Science · Physics 2022-01-20 Pooja Basera , Arunima Singh , Deepika Gill , Saswata Bhattacharya

With the rapid evolution of lead halide perovskite solar cells, there are considerable evidences that the mobile ions strongly impact their properties. However, except the activation energy, the other properties of ionic migration are…

Materials Science · Physics 2018-06-21 Ningbo Yi , Gang Li , Yuhan Wang , Shuai Wang , Kaiyang Wang , Qinghai Song , Shumin Xiao

Understanding and quantifying the main loss factors affecting the power conversion efficiency of perovskite solar cells are urgently needed. In this work, based on semiconductor physics, the expressions of bulk and surface recombination…

Mesoscale and Nanoscale Physics · Physics 2021-03-23 Ting Xu , Zi-Shuai Wang , Xuan-Hua Li , Wei E. I. Sha

The current density-voltage characteristic (JV) is a critical tool for understanding the behaviour of solar cells. In this article, we present an overview of the key aspects of JV analysis and introduce a user-friendly flowchart that…

Materials Science · Physics 2024-04-17 Albert These , L. Jan Anton Koster , Christoph J. Brabec , Vincent M. Le Corre

Impedance spectroscopy (IS) is a relatively straightforward experimental technique that is commonly used to obtain information about the physical and chemical characteristics of photovoltaic devices. However, the non-standard physical…

Perovskite-based solar cells are promising due to their rapidly improving efficiencies, but suffer from instability issues. Recently it has been claimed that one of the key contributors to the instability of perovskite solar cells is ion…

Applied Physics · Physics 2019-04-29 Boris Rivkin , Paul Fassl , Qing Sun , Alexander D. Taylor , Zhuoying Chen , Yana Vaynzof

This paper presents a first step toward a pragmatic phenomenological multiscale approach to evaluate perovskite solar cell performance which determines material properties at the atomistic scale with first-principles calculations, and…

Materials Science · Physics 2026-01-08 Ph Baranek , J P Connolly , A Gissler , Ph Schulz , M Rérat , R Dovesi

In this work, perovskite solar cells (PSCs) with different transport layers were fabricated to understand the hysteresis phenomenon under a series of scan rates. The experimental results show that the hysteresis phenomenon would be affected…

Materials Science · Physics 2022-05-24 Jun-Yu Huang , You-Wei Yang , Wei-Hsuan Hsu , En-Wen Chang , Mei-Hsin Chen , Yuh-Renn Wu

Metal halide perovskites (MHPs) are nowadays one of the most studied semiconductors due to their exceptional performance as active layers in solar cells. Although MHPs are excellent solid-state semiconductors, they are also ionic compounds,…