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We propose a computationally lean, two-stage approach that reliably predicts self-assembly behavior of complex charged molecules on a metallic surfaces under electrochemical conditions. Stage one uses ab initio simulations to provide…

Computational Physics · Physics 2020-07-15 Benedikt Hartl , Shubham Sharma , Oliver Brügner , Stijn F. L. Mertens , Michael Walter , Gerhard Kahl

Triply periodic continuous morphologies arising a result of the microphase separation in block copolymer melts have so far never been observed self-assembled in systems of particles with spherically symmetric interaction. We report a…

Soft Condensed Matter · Physics 2019-05-10 Lorenzo Agosta , Alfredo Metere , Peter Oleynikov , Mikhail Dzugutov

If particles interact according to isotropic pair potentials that favor multiple length scales, in principle a large variety of different complex structures can be achieved by self-assembly. We present, motivate, and discuss a conjecture…

Soft Condensed Matter · Physics 2018-11-07 Erdal C. Oğuz , Aleksandar Mijailović , Michael Schmiedeberg

We use thermodynamic perturbation theory to calculate the free energies and resulting phase diagrams of binary systems of spherical colloidal particles and interacting polymer coils in good solvent within an effective one-component…

Soft Condensed Matter · Physics 2009-11-10 B. Rotenberg , J. Dzubiella , J. -P. Hansen , A. A. Louis

Motivated by observations of heterogeneous domain structure on the surface of cells, we consider a minimal model to describe the dynamics of phase separation on the surface of a spherical particle. Finite-size effects on the curved particle…

Soft Condensed Matter · Physics 2016-07-13 Matthias C. Bott , Joseph M. Brader

The fluid phase diagram of trimer particles composed of one central attractive bead and two repulsive beads was determined as a function of simple geometric parameters using flat-histogram Monte Carlo methods. A variety of self-assembled…

Soft Condensed Matter · Physics 2015-05-20 Harold W. Hatch , Jeetain Mittal , Vincent K. Shen

Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar)…

Soft Condensed Matter · Physics 2015-05-13 Ezequiel R. Soule , Nasser Mohieddin Abukhdeir , Alejandro D. Rey

Herein, we describe new methods to produce colloidal particle chains of three stiffness regimes that can be observed on a single-particle level, that is, on the level of the monomers that make up the chain; the chains can even be observed…

Colloidal particles can spontaneously self-assemble into ordered structures, which not only can manipulate the propagation of light, but also vibration or phonons. Using Monte Carlo simulation, we study the self-assembly of perfectly…

Soft Condensed Matter · Physics 2024-03-11 Ji-Dong Hu , Ting Wang , Qun-Li Lei , Yu-qiang Ma

We study the phase behavior of bowl-shaped particles using computer simulations. These particles were found experimentally to form a meta-stable worm-like fluid phase in which the bowl-shaped particles have a strong tendency to stack on top…

Soft Condensed Matter · Physics 2011-12-07 Matthieu Marechal , Marjolein Dijkstra

Using Langevin dynamics complemented by Wang-Landau Monte Carlo simulations, we study the phase behavior of single and multiple semiflexible polymer chains in solution under poor-solvent conditions. In the case of a single chain, we obtain…

We study the phase ordering colloids suspended in a thermotropic nematic liquid crystal below the clearing point Tni and the resulting aggregated structure. Small (150nm) PMMA particles are dispersed in a classical liquid crystal matrix,…

Soft Condensed Matter · Physics 2007-05-23 V. J. Anderson , E. M. Terentjev , S. P. Meeker , J. Crain , W. C. K. Poon

The self-assembly of polyhedral shells, each constructed from 60 trapezoidal particles, is simulated using molecular dynamics. The spatial organization of the component particles in this shell is similar to the capsomer proteins forming the…

Soft Condensed Matter · Physics 2012-12-05 D. C. Rapaport

The lattice cluster theory (LCT) for strongly interacting, self-assembling telechelic polymers provides a theoretical tool that enables establishing the connections between important microscopic molecular details of self-assembling polymers…

Soft Condensed Matter · Physics 2016-05-31 Wen-Sheng Xu , Karl F. Freed

Two-dimensional colloidal suspensions exposed to periodic external fields exhibit a variety of molecular crystalline phases. There two or more colloids assemble at lattice sites of potential minima to build new structural entities, referred…

Soft Condensed Matter · Physics 2009-11-11 Andreja Sarlah , Erwin Frey , Thomas Franosch

We investigate - with Monte Carlo computer simulations - the phase behaviour of dimeric colloidal molecules on periodic substrates with square symmetry. The molecules are formed in a two-dimensional suspension of like charged colloids…

Soft Condensed Matter · Physics 2015-06-04 Samir El Shawish , Emmanuel Trizac , Jure Dobnikar

When liquid-crystal elastomers are prepared without any alignment, disordered polydomain structures emerge as the materials are cooled into the nematic phase. These polydomain structures have been attributed to quenched disorder in the…

Soft Condensed Matter · Physics 2015-11-04 Ayhan Duzgun , Jonathan V. Selinger

A modified phase field crystal model in which the free energy may be minimised by an order parameter profile having isolated bumps is investigated. The phase diagram is calculated in one and two dimensions and we locate the regions where…

Soft Condensed Matter · Physics 2012-08-31 Mark J. Robbins , Andrew J. Archer , Uwe Thiele , Edgar Knobloch

We study avenues to shape multistability and shape-morphing in flexible crystalline membranes of cylindrical topology, enabled by glide mobility of dislocations. Using computational modeling, we obtain states of mechanical equilibrium…

Soft Condensed Matter · Physics 2022-03-23 Andrei Zakharov , Daniel A. Beller

A recently introduced active phase field crystal model describes the formation of ordered resting and traveling crystals in systems of self-propelled particles. Increasing the active drive, a resting crystal can be forced to perform…

Soft Condensed Matter · Physics 2014-02-18 Andreas M. Menzel , Takao Ohta , Hartmut Löwen