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Related papers: Engineering ferroelectricity in monoclinic hafnia

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In hafnia-based thin-film ferroelectric devices, chemical phenomena during growth and processing such as oxygen vacancy formation and interfacial reactions appear to strongly affect device performance. However, the nanoscale structure,…

Ferroelectricity in hafnia is often regarded as a breakthrough discovery in ferroelectrics, potentially able to revolutionize the whole field. Despite increasing interests, a comprehensive understanding of the many factors driving the…

Materials Science · Physics 2021-06-16 Francesco Delodovici , Paolo Barone , Silvia Picozzi

Remarkable exploitation of valence and lattice mismatch in epitaxial ferroelectric heterostructures generates physical effects not classically expected for perovskite oxides, such as 2D electron gas and polar skyrmions. However the…

The binary fluorite oxide Hf0.5Zr0.5O2 tends to grab a significant amount of notice due to the distinct and superior ferroelectricity found in its metastable phase. Stabilizing the metastable ferroelectric phase and delineating the…

Materials Science · Physics 2023-07-12 Yufan Shen , Mitsutaka Haruta , I-Ching Lin , Lingling Xie , Daisuke Kan , Yuichi Shimakawa

Binary oxide ferroelectrics like doped HfO2, compatible with complementary metal-oxide-semiconductor (CMOS) platforms, have gained significant interest for energy efficient, scalable, high-performance non-volatile memory and neuromorphic…

Materials Science · Physics 2024-10-15 Ella Paasio , Rikhard Ranta , Sayani Majumdar

Ferroelectric HfO$_2$ is a promising material for new memory devices, but significant improvement of important properties is necessary to reach applications. However, precedent literature shows that a dilemma between polarization, endurance…

Applied Physics · Physics 2020-06-30 Jike Lyu , Tingfeng Song , Ignasi Fina , Florencio Sánchez

The unconventional Si-compatible ferroelectricity in hafnia-based systems, which becomes robust only at nanoscopic sizes, has attracted a lot of interest. While a metastable polar orthorhombic (o-) phase (Pca21) is widely regarded as the…

Materials Science · Physics 2021-01-05 Pavan Nukala , Yingfen Wei , Vincent de Haas , Qikai Guo , Jordi Antoja-Lleonart , Beatriz Noheda

Ferroelectricity is intriguing for its spontaneous electric polarization, which is switchable by an external electric field. Expanding ferroelectric materials to two-dimensional limit will provide versatile applications for the development…

Mesoscale and Nanoscale Physics · Physics 2024-04-05 Le Zhang , Jing Ding , Hanxiao Xiang , Naitian Liu , Wenqiang Zhou , Linfeng Wu , Na Xin , Kenji Watanabe , Takashi Taniguchi , Shuigang Xu

Hafnia ferroelectrics combine technological promise and unprecedented behaviors. Their peculiarity stems from the many active extrinsic mechanisms that contribute to their properties and from a continuously growing number of novel intrinsic…

Materials Science · Physics 2023-11-15 Hugo Aramberri , Jorge Íñiguez

For spintronics applications, it is highly desirable to realize highly-spin-polarized two-dimensional (2D) electron systems in electrically-controllable epitaxial ultrathin films on semiconductor substrates. Through systematic…

Mesoscale and Nanoscale Physics · Physics 2019-06-12 Xiang-Bo Xiao , Bang-Gui Liu

The epitaxial growth of multifunctional oxides on semiconductors has opened a pathway to introduce new functionalities to semiconductor device technologies. In particular, ferroelectric materials integrated on semiconductors could lead to…

Although technologically challenging, the integration of ferroelectric thin films with graphene spintronics potentially allows the realization of highly efficient, electrically tuneable, non-volatile memories. Here, the atomic layer…

Nanosized hafnia-zirconia HfxZr1-xO2 in the form of thin films, multilayers and heterostructures are indispensable silicon-compatible ferroelectric materials for advanced electronic memories and logic devices. The distinctive feature of…

Materials Science · Physics 2026-05-05 Anna N. Morozovska , Eugene A. Eliseev , Sergei V. Kalinin , Maksym V. Strikha

Fluorite structure ferroelectrics, especially hafnium oxide, are widely investigated for their application in non-volatile memories, sensors, actuators, RF devices and energy harvesters. Due to the metastable nature of the ferroelectric…

The discovery of ferroelectric polarization in HfO2-based ultrathin films has spawned a lot of interest due to their potential applications in data storage. Recently, a new R3m rhombohedral phase was proposed to be responsible for the…

Materials Science · Physics 2020-07-29 Yuke Zhang , Qiong Yang , Lingling Tao , Evgeny Y. Tsymbal , Vitaly Alexandrov

After the discovery of ferroelectricity in HfO$_2$ based thin films a decade ago, ferroelectric Hf$_{0.5}$Zr$_{0.5}$O$_2$ (HZO) thin films are frequently being utilized in the CMOS (Complementary Metal- Oxide Semiconductor) and logic…

Materials Science · Physics 2024-09-11 Deepak Kumar

Flexoelectricity is universal in all dielectrics, effective at high temperatures, and a promising transduction technique for nanoelectromechanical systems (NEMS). However, as flexoelectricity is still in its early stages, many aspects…

Materials Science · Physics 2024-10-03 Daniel Moreno-Garcia , Luis Guillermo Villanueva

Structural softness - often characterized by unstable phonon modes and large electromechanical responses - is a hallmark of ferroelectric perovskites like BaTiO3 or Pb(Ti,Zr)O3. Whether HfO2 ferroelectrics present any such structural…

Materials Science · Physics 2024-12-30 Binayak Mukherjee , Natalya S. Fedorova , Jorge Íñiguez-González

Ferroelectric field-effect transistors integrated on 2D semiconducting platforms are extremely relevant for low power electronics. Here, we propose and demonstrate a novel phase-change ferroelectric field effect transistor (PCFE-FET) for…

Applied Physics · Physics 2024-11-05 Sooraj Sanjay , Jalaja M. A , Navakanta Bhat , Pavan Nukala

Wurtzite ferroelectrics are rapidly emerging as a promising material class for next-generation non-volatile memory technologies, owing to their large remanent polarization, intrinsically ordered three-dimensional crystal structure, and full…