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An exchange energy functional is proposed and tested for obtaining a class of excited-state energies using density-functional formalism. The functional is the excited-state counterpart of the local-density approximation functional for the…

Other Condensed Matter · Physics 2007-05-23 Prasanjit Samal , Manoj K. Harbola

A set of curves or images of similar shape is an increasingly common functional data set collected in the sciences. Principal Component Analysis (PCA) is the most widely used technique to decompose variation in functional data. However, the…

Methodology · Statistics 2009-09-29 Rima Izem , J. S. Marron

Empirical scoring functions based on either molecular force fields or cheminformatics descriptors are widely used, in conjunction with molecular docking, during the early stages of drug discovery to predict potency and binding affinity of a…

Machine Learning · Computer Science 2017-03-31 Joseph Gomes , Bharath Ramsundar , Evan N. Feinberg , Vijay S. Pande

Classification of human emotions can play an essential role in the design and improvement of human-machine systems. While individual biological signals such as Electrocardiogram (ECG) and Electrodermal Activity (EDA) have been widely used…

Machine Learning · Computer Science 2021-08-06 Anubhav Bhatti , Behnam Behinaein , Dirk Rodenburg , Paul Hungler , Ali Etemad

Accurately modeling chemical reactions at the atomistic level requires high-level electronic structure theory due to the presence of unpaired electrons and the need to properly describe bond breaking and making energetics. Commonly used…

While in principle exact, Kohn-Sham density functional theory -- the workhorse of computational chemistry -- must rely on approximations for the exchange-correlation functional. Despite staggering successes, present-day approximations still…

The spatial distribution of the internal pressure of an electron fluid, which spontaneously arises at the formation of a molecule or a crystal, is linked to the main features of chemical bonding in molecular crystals. The local pressure is…

Chemical Physics · Physics 2016-05-04 Vladimir G. Tsirelson , Adam I. Stash , Ilya V. Tokatly

Tensor decomposition is an important tool for multiway data analysis. In practice, the data is often sparse yet associated with rich temporal information. Existing methods, however, often under-use the time information and ignore the…

Machine Learning · Computer Science 2023-10-31 Zheng Wang , Shikai Fang , Shibo Li , Shandian Zhe

Faithful representations of atomic environments and general models for regression can be harnessed to learn electron densities that are close to the ground state. One of the applications of data-derived electron densities is to orbital-free…

Materials Science · Physics 2019-03-01 Andrew T. Fowler , Chris J. Pickard , James A. Elliott

The energy-energy correlation function of the two-dimensional Ising model with weakly fluctuating random bonds is evaluated in the large scale limit. Two correlation lengths exist in contrast to one correlation length in the pure 2D Ising…

Condensed Matter · Physics 2007-05-23 K. Ziegler

The modal decomposition techniques of proper orthogonal decomposition (POD) and dynamic mode decomposition (DMD) have become a common method for analysing the spatio-temporal coherence of dynamical systems. In particular, these techniques…

Fluid Dynamics · Physics 2019-09-18 Scott B. Leask , Vincent G. McDonell

Interpolating the exchange-correlation energy along the density-fixed adiabatic connection of density functional theory is a promising way to build approximations that are not biased towards the weakly correlated regime. These…

Strongly Correlated Electrons · Physics 2020-12-10 Derk P. Kooi , Paola Gori-Giorgi

We present a review of the basic ideas and techniques of the spectral density functional theory which are currently used in electronic structure calculations of strongly-correlated materials where the one-electron description breaks down.…

Strongly Correlated Electrons · Physics 2009-11-11 G. Kotliar , S. Y. Savrasov , K. Haule , V. S. Oudovenko , O. Parcollet , C. A. Marianetti

We explore the deformation properties of the newly postulated BCP energy density functional (EDF). The results obtained for three isotope chains of Mg, Dy and Ra are compared to the available experimental data as well as to the results of…

Nuclear Theory · Physics 2009-11-13 L. M. Robledo , M. Baldo , P. Schuck , X. Viñas

We show an $\textit{ab initio}$ construction of the energy density functional (EDF) for electron systems using the functional renormalization group. The correlation energies of the homogeneous electron gas given in our framework reproduce…

Strongly Correlated Electrons · Physics 2021-08-03 Takeru Yokota , Tomoya Naito

Machine-learning models have recently encountered enormous success for predicting the properties of materials. These are often trained based on data that present various levels of accuracy, with typically much less high- than low-fidelity…

Materials Science · Physics 2022-04-25 Xiaotong Liu , Pierre-Paul De Breuck , Linghui Wang , Gian-Marco Rignanese

Electrophoretic separations of proteins are widely used in proteomic analyses, and rely heavily on SDS electrophoresis. This mode of separation is almost exclusively used when a single dimension separation is performed, and generally…

Genomics · Quantitative Biology 2010-05-07 Thierry Rabilloud

In this perspective, the various measures of electron correlation used in wavefunction theory, density functional theory and quantum information theory are briefly reviewed. We then focus on a more traditional metric based on dominant…

Chemical Physics · Physics 2023-04-07 Róbert Izsák , Aleksei V Ivanov , Nick S. Blunt , Nicole Holzmann , Frank Neese

We investigate an extension of excited state mean-field theory in which the energy expression is augmented with density functional components in an effort to include the effects of weak electron correlations. The approach remains…

Chemical Physics · Physics 2020-02-05 Luning Zhao , Eric Neuscamman

The power loss and electromagnetic energy density of a metamaterial consisting of arrays of wires and split-ring resonators (SRRs) are investigated. We show that a field energy density formula can be derived consistently from both the…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Pi-Gang Luan