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The 5d pyrochlore oxide Cd2Re2O7 exhibits successive phase transitions from a cubic pyrochlore structure (phase I) to a tetragonal structure without inversion symmetry below Ts1 of ~200 K (phase II) and further to another noncentrosymmetric…

A rare combination of strong spin-orbit coupling and electron-electron correlations makes the iridate Mott insulator Sr$_2$IrO$_4$ a promising host for novel electronic phases of matter. The resemblance of its crystallographic, magnetic and…

Strongly Correlated Electrons · Physics 2016-01-11 L. Zhao , D. H. Torchinsky , H. Chu , V. Ivanov , R. Lifshitz , R. Flint , T. Qi , G. Cao , D. Hsieh

The 3d electronic structure and phase transition in pure and Cr doped V2O3 are theoretically investigated in relation to the 3d spin-orbit interaction and lattice distortion. A model consisting of the nearest-neighbor V ion pair with full…

Strongly Correlated Electrons · Physics 2016-08-31 Arata Tanaka

The (SrTiO$_3$)$_m$/(SrVO$_3$)$_n$ $d^0-d^1$ multilayer system is studied with first principles methods through the observed insulator-to-metal transition with increasing thickness of the SrVO$_3$ layer. When correlation effects with…

Strongly Correlated Electrons · Physics 2015-05-19 Victor Pardo , Warren E. Pickett

Previous theoretical studies [W. Cho, C. Platt, R. H. McKenzie, and S. Raghu, Phys. Rev. B 92, 134514 (2015); N. Lera and J. V. Alvarez, Phys. Rev. B 92, 174523 (2015)] have suggested that Li$_{0.9}$Mo$_6$O$_{17}$, a quasi-one dimensional…

Superconductivity · Physics 2016-06-29 Christian Platt , Weejee Cho , Ross H. McKenzie , Ronny Thomale , Sri Raghu

In contrast to the previous reports that the divalent perovskite SrCrO$_3$ was believed to be cubic structure and nonmagnetic metal, recent measurements suggest coexistence of majority tetragonally distorted weak antiferromagnetic phase and…

Strongly Correlated Electrons · Physics 2009-10-01 K. -W. Lee , W. E. Pickett

Odd-parity superconductivity is a fundamentally interesting but rare state of matter with a potential for applications in topological quantum computing. Crystals with staggered locally noncentrosymmetric structures have been proposed as…

Spin-orbit coupling (SOC) is central to many physical phenomena, including fine structures of atomic spectra and quantum topological matters. Whereas SOC is in general fixed in a physical system, atom-laser interaction provides physicists a…

Spin orbit coupling provides a mechanism to lock the momentum of electron to its spin degree, recent years was revealed to be essential in arousing many novel physical behaviors. SrIrO3 is a typical metallic member of the strong spin orbit…

Materials Science · Physics 2018-08-10 Lunyong Zhang , Bin Pang , Y. B. Chen , Yanfeng Chen

The realization of spin-orbit coupling (SOC) in ultracold atoms has triggered an intensive exploring of topological superfluids in the degenerate Fermi gases based on mean-field theory, which has not yet been reported in experiments. Here,…

Polar distortions in solids give rise to the well-known functionality of switchable macroscopic polarisation in ferroelectrics and, when combined with strong spin-orbit coupling, can mediate giant spin splittings of electronic states. While…

It is generally believed that spin-orbit coupling (SOC) follows Z4 (atomic number) dependence and becomes significant only in heavy elements. Consequently, SOC in 3d transition metals should be negligible given their small Z. Using dynamic…

Materials Science · Physics 2014-10-08 Chunhui Du , Hailong Wang , Fengyuan Yang , P. Chris Hammel

By using the arc-melting method, we successfully synthesized the compound Sc$_{0.5}$Zr$_{0.5}$Co with the space group of $Pm$-$3m$. Both the resistivity and magnetic susceptibility measurements reveal a phase transition at about 86 K. This…

Materials Science · Physics 2020-07-06 Jin Si , Xinwei Fan , Enyu Wang , Xiyu Zhu , Qing Li , Hai-Hu Wen

It is shown that both structural phase transitions in Cd2Re2O7, which occur at T_{s1}=200 K and T_{s2}=120 K, are due to an instability of the Re tetrahedral network with respect to the same doubly degenerate long-wavelength phonon mode.…

Superconductivity · Physics 2009-11-10 I. A. Sergienko , S. H. Curnoe

At room temperature, the normal oxide spinels NiCr_2O_4 and CuCr_2O_4 are tetragonally distorted and crystallize in the I4_1/amd space group due to cooperative Jahn-Teller ordering driven by the orbital degeneracy of tetrahedral Ni$^{2+}$…

Materials Science · Physics 2012-09-11 Matthew R. Suchomel , Daniel P. Shoemaker , Lynn Ribaud , Moureen C. Kemei , Ram Seshadri

The kagome lattice, with its inherent frustration, hosts a plethora of exotic phenomena, including the emergence of $3\mathbf{q}$ charge density wave order. The high rotational symmetry, required to realize such an unconventional charge…

Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance,…

Strongly Correlated Electrons · Physics 2009-11-07 Zenji Hiroi , Jun-Ichi Yamaura , Yuji Muraoka , Masafumi Hanawa

Complex oxides with $4d$ and $5d$ transition-metal ions recently emerged as a new paradigm in correlated electron physics, due to the interplay between spin-orbit coupling and electron interactions. For $4d$ and $5d$ ions, the spin-orbit…

Strongly Correlated Electrons · Physics 2021-05-19 Tomohiro Takayama , Jiri Chaloupka , Andrew Smerald , Giniyat Khaliullin , Hidenori Takagi

Identifying ordered phases and their underlying symmetries is the first and most important step toward understanding the mechanism of high-temperature superconductivity; critical behaviors of ordered phases are expected to be correlated…

Structural phase transitions often couple to magnetic and electronic degrees of freedom, enabling emergent phenomena in solids. In high-entropy oxides (HEOs), which typically stabilize in highly symmetric cubic phases, such transitions are…