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Maximally localized Wannier functions are the key tool for a variety of physical applications of Bloch states. Here we develop a simple and exact procedure to construct maximally localized Wannier functions for one dimensional periodic…

Strongly Correlated Electrons · Physics 2014-12-12 Yuri Lensky , Colin Kennedy

We derive a multi-band formulation of the orbital magnetization in a normal periodic insulator (i.e., one in which the Chern invariant, or in 2d the Chern number, vanishes). Following the approach used recently to develop the single-band…

Materials Science · Physics 2009-11-11 Davide Ceresoli , T. Thonhauser , David Vanderbilt , R. Resta

The modern theory of polarization does not apply in its original form to systems with non-trivial band topology. Chern insulators are one such example. Defining polarization for them is complicated because they are insulating in the bulk…

Strongly Correlated Electrons · Physics 2026-02-04 Thivan M. Gunawardana , Frank Schindler , Ari M. Turner , Ryan Barnett

We present a rapidly convergent scheme for computing globally optimal Wannier functions of isolated single bands for matrix models in two dimensions. The scheme proceeds first by constructing provably exponentially localized Wannier…

Mathematical Physics · Physics 2025-04-24 Hanwen Zhang

We present an alternative formalism for calculating the maximally localized Wannier functions in crystalline solids, obtaining an expression which is extremely simple and general. In particular, our scheme is exactly invariant under…

Materials Science · Physics 2011-03-03 Massimiliano Stengel , Nicola A. Spaldin

We present a first-principles calculation of the electronic properties of crystalline silicon and gallium arsenide in a uniform electric field. Polarized Wannier-like functions which are confined in a finite region are obtained by…

Materials Science · Physics 2007-05-23 Pablo Fernández , Andrea Dal Corso , Alfonso Baldereschi

We present a method for obtaining well-localized Wannier-like functions (WFs) for energy bands that are attached to or mixed with other bands. The present scheme removes the limitation of the usual maximally-localized WFs method (N. Marzari…

Materials Science · Physics 2009-11-07 Ivo Souza , Nicola Marzari , David Vanderbilt

We use the maximally-localized Wannier function method to study bonding properties in amorphous silicon. This study represents, to our knowledge, the first application of the Wannier-function analysis to a disordered system. Our results…

Materials Science · Physics 2009-10-31 Pier Luigi Silvestrelli , Nicola Marzari , David Vanderbilt , Michele Parrinello

Accurate prediction of fundamental band gaps of crystalline solid state systems entirely within density functional theory is a long standing challenge. Here, we present a simple and inexpensive method that achieves this by means of…

We investigate the interplay of band structure topology and localization properties of Wannier functions. To this end, we extend a recently proposed compressed sensing based paradigm for the search for maximally localized Wannier functions…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 J. C. Budich , J. Eisert , E. J. Bergholtz , S. Diehl , P. Zoller

The existence and construction of exponentially localised Wannier functions for insulators is a well-studied problem. In comparison, the case of metallic systems has been much less explored, even though localised Wannier functions…

Mathematical Physics · Physics 2019-02-04 Horia Cornean , David Gontier , Antoine Levitt , Domenico Monaco

In insulators, the method of Marzari and Vanderbilt [Phys. Rev. B {\bf 56}, 12847 (1997)] can be used to generate maximally localized Wannier functions whose centers are related to the electronic polarization. In the case of layered…

Materials Science · Physics 2009-12-17 Xifan Wu , Oswaldo Diéguez , Karin M. Rabe , David Vanderbilt

Optimal tuning of functional parameters in density functional theory approximations, based on enforcing the ionization potential theorem, has emerged as the method of choice for the non-empirical prediction of the electronic structure of…

A non-iterative method is presented to calculate the closest Wannier functions (CWFs) to a given set of localized guiding functions, such as atomic orbitals, hybrid atomic orbitals, and molecular orbitals, based on minimization of a…

Materials Science · Physics 2023-07-03 Taisuke Ozaki

We propose a numerical method using the discrete variable representation (DVR) for constructing real-valued Wannier functions localized in a unit cell for both symmetric and asymmetric periodic potentials. We apply these results to finding…

Quantum Gases · Physics 2016-09-14 Saurabh Paul , Eite Tiesinga

We propose a general method of constructing Wannier functions in disordered systems directly out of energy eigenstates. This method consists of two successive operations: (i) a phase transformation setting the proper localization center;…

Disordered Systems and Neural Networks · Physics 2015-12-24 Junbo Zhu , Zhu Chen , Biao Wu

Non-trivial Chern classes pose an obstruction to the existence of exponentially decaying Wannier functions which provide natural bases for spectral subspaces. For non-trivial Bloch bundles, we obtain decay rates of Wannier functions in…

Mathematical Physics · Physics 2025-05-06 Simon Becker , Zhongkai Tao , Mengxuan Yang

We consider a real periodic Schr\"odinger operator and a physically relevant family of $m \geq 1$ Bloch bands, separated by a gap from the rest of the spectrum, and we investigate the localization properties of the corresponding composite…

Mathematical Physics · Physics 2016-01-13 Domenico Fiorenza , Domenico Monaco , Gianluca Panati

Wannier function expansions are well suited for the description of photonic- crystal-based defect structures, but constructing maximally localized Wannier functions by optimizing the phase degree of freedom of the Bloch modes is crucial for…

Optics · Physics 2015-05-27 Tobias Stollenwerk , Dmitry N. Chigrin , Johann Kroha

We consider the problem of constructing Wannier functions for Z_2 topological insulators in two dimensions. It is well known that there is a topological obstruction to the construction of Wannier functions for Chern insulators, but it has…

Mesoscale and Nanoscale Physics · Physics 2011-02-23 Alexey A. Soluyanov , David Vanderbilt