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Two coarse-grained models for polymer chains in dense glass-forming polymer melts are studied by computer simulation: the bond-fluctuation model on a simple cubic lattice, where a bond-length potential favors long bonds, is treated by…

Soft Condensed Matter · Physics 2007-05-23 K. Binder , J. Baschnagel , C. Bennemann , W. Paul

We use X-Ray Photon Correlation Spectroscopy to investigate the structural relaxation process in a metallic glass on the atomic length scale. We report evidence for a dynamical crossover between the supercooled liquid phase and the…

Soft Condensed Matter · Physics 2015-06-11 B. Ruta , Y. Chushkin , G. Monaco , L. Cipelletti , E. Pineda , P. Bruna , V. M. Giordano , M. Gonzalez-Silveira

We carried out molecular dynamics simulations (MD) using realistic empirical potentials for the vapor deposition (VD) of CuZrAl glasses. VD glasses have higher densities and lower potential and inherent structure energies than the…

Computational Physics · Physics 2017-09-15 G. B. Bokas , L. Zhao , D. Morgan , I. Szlufarska

We applied an efficient methodology to separate vibrational and configurational entropies in bulk metallic glasses by means of molecular dynamics simulation based on a combination of non-equilibrium adiabatic switching and reversible…

Soft Condensed Matter · Physics 2020-07-03 René Alvarez-Donado , Alex Antonelli

We use coherent X-rays to probe the aging dynamics of a metallic glass directly on the atomic level. Contrary to the common assumption of a steady slowing down of the dynamics usually observed in macroscopic studies, we show that the…

Materials Science · Physics 2015-10-23 Zach Evenson , Beatrice Ruta , Simon Hechler , Moritz Stolpe , Eloi Pineda , Isabella Gallino , Ralf Busch

A fundamental objective of materials modeling is identifying atomic structures that align with experimental observables. Conventional approaches for disordered materials involve sampling from thermodynamic ensembles and hoping for an…

Materials Science · Physics 2025-09-30 Tigany Zarrouk , Miguel A. Caro

The crystal nucleation from liquid in most cases is too rare to be accessed within the limited timescales of the conventional molecular dynamics (MD) simulation. Here, we developed a "persistent embryo" method to facilitate crystal…

Materials Science · Physics 2018-02-27 Yang Sun , Huajing Song , Feng Zhang , Lin Yang , Zhuo Ye , Mikhail I. Mendelev , Cai-Zhuang Wang , Kai-Ming Ho

The low-temperature quasi-universal behavior of amorphous solids has been attributed to the existence of spatially-localized tunneling defects found in the low-energy regions of the potential energy landscape. Computational models of…

Disordered Systems and Neural Networks · Physics 2023-01-05 Felix C. Mocanu , Ludovic Berthier , Simone Ciarella , Dmytro Khomenko , David R. Reichman , Camille Scalliet , Francesco Zamponi

This review deals with the kinetic and thermodynamic fragility of bulk metallic glass forming liquids. The experimental methods to determine the kinetic fragility, relaxation behavior and thermodynamic functions of undercooled metallic…

Materials Science · Physics 2014-05-12 Ralf Busch , Zach Evenson , Isabella Gallino , Shuai Wei

Multicanonical molecular dynamics (MD) is a powerful technique for sampling conformations on rugged potential surfaces such as protein. However, it is notoriously difficult to estimate the multicanonical temperature effectively. Wang and…

Computational Physics · Physics 2007-11-01 Takehiro Nagasima , Akira R. Kinjo , Takashi Mitsui , Ken Nishikawa

Thermodynamic multi-component solution solidification approach to liquid-to-glass transition is proposed and actual mechanisms underlying vitrification, other than viscous slowdown, are identified. Due to polydisperse aggregation in liquid…

Materials Science · Physics 2022-09-14 Vladimir Belostotsky

Decades of hardware, methodological, and algorithmic development have propelled molecular dynamics (MD) simulations to the forefront of materials-modeling techniques, bridging the gap between electronic-structure theory and continuum…

Soft Condensed Matter · Physics 2020-11-11 Tristan Bereau

Molecular Dynamics studies of chemical processes in solution are of great value in a wide spectrum of applications, which range from nano-technology to pharmaceutical chemistry. However, these calculations are affected by severe finite-size…

Chemical Physics · Physics 2015-04-20 Claudio Perego , Matteo Salvalaglio , Michele Parrinello

We propose a hybrid deterministic and stochastic approach to achieve extended time scales in atomistic simulations that combines the strengths of molecular dynamics (MD) and Monte Carlo (MC) simulations in an easy-to-implement way. The…

Materials Science · Physics 2011-10-18 Pratyush Tiwary , Axel van de Walle

Accelerated molecular dynamics (MD) simulations are implemented to model the sliding process of AFM experiments at speeds close to those found in experiment. In this study the hyperdynamics method, originally devised to extend MD time…

Materials Science · Physics 2015-05-14 Woo Kyun Kim , Michael L. Falk

Classical Molecular Dynamics (MD) simulations are employed as a tool to investigate structural properties of ice crystals under several temperature and pressure conditions. All ice crystal phases are analyzed by means of a computational…

Materials Science · Physics 2015-05-28 M. Cogoni , B. D'Aguanno , L. N. Kuleshova , D. W. M. Hofmann

Monte Carlo simulations are widely employed to measure the physical properties of glass-forming liquids in thermal equilibrium. Combined with local Monte Carlo moves, the Metropolis algorithm can also be used to simulate the relaxation…

Statistical Mechanics · Physics 2024-09-23 Ludovic Berthier , Federico Ghimenti Frédéric van Wijland

We applied a multicanonical algorithm (entropic sampling) to a two-dimensional and a three-dimensional Lennard-Jones system with quasicrystalline and glassy ground states. Focusing on the ability of the algorithm to locate low lying energy…

Statistical Mechanics · Physics 2009-10-30 Kamal K. Bhattacharya , James P. Sethna

The simulation of rare events is one of the key problems in atomistic simulations. Towards its solution a plethora of methods have been proposed. Here we combine two such methods metadynamics and inte-grated tempering sampling. In…

Chemical Physics · Physics 2018-10-29 Yi Isaac Yang , Haiyang Niu , Michele Parrinello

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi