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The Raman effect -- inelastic scattering of light by lattice vibrations (phonons) -- produces an optical response closely tied to a material's crystal structure. Here we show that resonant optical excitation of IR and Raman phonons gives…

Materials Science · Physics 2021-07-07 Guru Khalsa , Nicole A. Benedek , Jeffrey Moses

Calculation of Raman scattering from molecular dynamics (MD) simulations requires accurate modeling of the evolution of the electronic polarizability of the system along its MD trajectory. For large systems, this necessitates the use of…

Materials Science · Physics 2024-06-12 Atanu Paul , Maya Rubenstein , Anthony Ruffino , Stefan Masiuk , Jonathan Spanier , Ilya Grinberg

We propose and demonstrate a novel technique that combines Raman scattering and optical cycling in molecules with diagonal Franck-Condon factors. This resonance Raman optical cycling manipulates molecules to behave like efficient…

Atomic Physics · Physics 2021-08-26 J. C. Shaw , J. C. Schnaubelt , D. J. McCarron

Random Matrix Theory (RMT) is capable of making predictions for the spectral fluctuations of a physical system only after removing the influence of the level density by unfolding the spectra. When the level density is known, unfolding is…

Statistical Mechanics · Physics 2013-12-16 Ashraf A. Abul-Magd , Adel Y. Abul-Magd

Two-magnon Raman scattering provides important information about electronic correlations in the insulating parent compounds of high-$T_c$ materials. Recent experiments have shown a strong dependence of the Raman signal in $B_{1g}$ geometry…

Strongly Correlated Electrons · Physics 2009-10-30 Dirk K. Morr , Andrey V. Chubukov

Infrared and Raman spectroscopies are ubiquitous techniques employed in many experimental laboratories, thanks to their fast and non-destructive nature able to capture materials' features as spectroscopic fingerprints. Nevertheless, these…

Materials Science · Physics 2024-05-08 Lorenzo Bastonero , Nicola Marzari

We report the observation of a novel nonlinear effect in the hard x-ray range. Upon illuminating Fe and Cu metal foils with intense x-ray pulses tuned near their respective K edges, photons at nearly twice the incoming photon energy are…

In this paper, we consider the problem of unmixing a time series of hyperspectral images. We propose a dynamical model based on linear mixing processes at each time instant. The spectral signatures and fractional abundances of the pure…

Computer Vision and Pattern Recognition · Computer Science 2016-06-29 Simon Henrot , Jocelyn Chanussot , Christian Jutten

We analyze how to obtain non-resonant and resonant Raman spectra within the Placzek as well as the Albrecht approximation. Both approximations are derived from the matrix element for light scattering by application of the Kramers,…

Chemical Physics · Physics 2019-12-30 Michael Walter , Michael Moseler

All signals obtained as instrumental response of analytical apparatus are affected by noise, as in Raman spectroscopy. Whereas Raman scattering is an inherently weak process, the noise background can lead to misinterpretations. Although…

We develop a generic theory for the resonant inelastic light (Raman) scattering by a conduction band quantum plasma taking into account the presence of the filled valence band in doped semiconductor nanostructures within a generalized…

Strongly Correlated Electrons · Physics 2009-11-07 Daw-Wei Wang , S. Das Sarma

The real-time dynamics of interacting electrons out of equilibrium contains detailed microscopic information about electronically correlated materials, which can be read out with time-resolved optical spectroscopy. The reflectivity that is…

Strongly Correlated Electrons · Physics 2008-12-08 Martin Eckstein , Marcus Kollar

In a retroreflective scheme atomic Raman diffraction adopts some of the properties of Bragg diffraction due to additional couplings to off-resonant momenta. As a consequence, double Raman diffraction has to be performed in a Bragg-type…

Quantum Physics · Physics 2022-09-08 Sabrina Hartmann , Jens Jenewein , Sven Abend , Albert Roura , Enno Giese

Inelastic light scattering is an intensively used tool in the study of electronic properties of solids. Triggered by the discovery of high temperature superconductivity in the cuprates and by new developments in instrumentation, light…

Strongly Correlated Electrons · Physics 2009-11-11 T. P. Devereaux , R. Hackl

Low-frequency Raman scattering experiments have been performed on thin films consisting of nickel-silver composite nanoparticles embedded in alumina matrix. It is observed that the Raman scattering by the quadrupolar modes, strongly…

Condensed Matter · Physics 2007-05-23 H. Portales , L. Saviot , E. Duval , M. Gaudry , E. Cottancin , M. Pellarin , J. Lerme , M. Broyer

A theory of resonant Raman scattering spectroscopy of one dimensional electronic systems is developed on the assumptions that (i) the excitations of the one dimensional electronic system are described by the Luttinger Liquid model, (ii)…

Strongly Correlated Electrons · Physics 2016-08-31 D. -W. Wang , A. J. Millis , S. Das Sarma

Light-matter interaction is exploited in spectroscopic techniques to access information about molecular, atomic or nuclear constituents of the sample of interest. While scattered light carries both amplitude and phase information of the…

Multidimensional coherent optical spectroscopy is one of the most powerful tools for investigating complex quantum mechanical systems. While it was conceived decades ago in magnetic resonance spectroscopy using micro- and radio-waves, it…

Raman spectroscopy is a powerful tool for material characterization. However, careful preprocessing is required for the identification and handling of noise, baseline drift, and random spikes. This paper presents a comprehensive approach to…

In the last two decades, non-equilibrium spectroscopies have evolved from avant-garde studies to crucial tools for expanding our understanding of the physics of strongly correlated materials. The possibility of obtaining simultaneously…