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The selection of a balanced active space is a critical step in multi-reference quantum chemistry calculations, particularly for systems with strong electron correlation. Likewise, active space selection is a key to unlock the potential of…

We propose a practical method for accurately evaluating molecular energies using a hybrid approach that integrates fault-tolerant quantum computers with classical computing. Our scheme comprises two complementary methods: quantum dominant…

Quantum Physics · Physics 2026-03-04 Nobuki Inoue , Hisao Nakamura

We present our implementation autoCAS for fully automated multi-configurational calculations, which we also make available free of charge on our webpages. The graphical user interface of autoCAS connects a general electronic structure…

Chemical Physics · Physics 2019-12-03 Christopher J. Stein , Markus Reiher

Optimizing Reconfigurable Intelligent Surfaces (RIS) is a high-dimensional combinatorial challenge. Current quantum algorithms often simplify this problem by ignoring physical constraints like mutual coupling, which significantly degrades…

Computational Engineering, Finance, and Science · Computer Science 2026-05-08 Marco Pasquale , Erik M. Åsgrim , Stefano Markidis , Oscar Quevedo-Teruel

The complete active space self-consistent field (CASSCF) method is the principal approach employed for studying strongly correlated systems. However, exact CASSCF can only be performed on small active spaces of ~20 electrons in ~20 orbitals…

Computational Physics · Physics 2021-12-22 Daniel S. Levine , Diptarka Hait , Norm M. Tubman , Susi Lehtola , K. Birgitta Whaley , Martin Head-Gordon

In this work, we investigate the possibility of improving multireference-driven coupled cluster (CC) approaches with an algorithm that iteratively combines complete active space (CAS) calculations with tailored CC and externally corrected…

Chemical Physics · Physics 2025-03-06 Robin Feldmann , Max Mörchen , Jakub Lang , Michał Lesiuk , Markus Reiher

Computation of electronic spectra is one of the most important applications of methods capturing static electron correlation, including complete-active-space self-consistent field (CASSCF) and post-CASSCF theories. Performance of these…

Chemical Physics · Physics 2025-11-19 Reza G. Shirazi , Alexander Zech , Peter Pinski , Vladimir V. Rybkin

An iterative configuration interaction (iCI)-based multiconfigurational self-consistent field (SCF) theory, iCISCF, is proposed to handle systems that require large complete active spaces (CAS). The success of iCISCF stems from three…

Chemical Physics · Physics 2021-06-21 Yang Guo , Ning Zhang , Yibo Lei , Wenjian Liu

We use the recently-developed Heat-bath Configuration Interaction (HCI) algorithm as an efficient active-space solver to perform multi-configuration self-consistent field calculations (HCISCF) with large active spaces. We give a detailed…

Chemical Physics · Physics 2018-11-08 James E. T. Smith , Adam A. Holmes , Bastien Mussard , Sandeep Sharma

Quantum architecture search (QAS) is desired to construct a powerful and general QAS platform which can significantly accelerate quantum advantages in error-prone and depth limited quantum circuits in today Noisy Intermediate-Scale Quantum…

Quantum Physics · Physics 2022-12-02 Anqi Zhang , Shengmei Zhao

With the rapid development of quantum computers, quantum algorithms have been studied extensively. However, quantum algorithms tackling statistical problems are still lacking. In this paper, we propose a novel non-oracular quantum adaptive…

Methodology · Statistics 2021-07-20 Wenxuan Zhong , Yuan Ke , Ye Wang , Yongkai Chen , Jinyang Chen , Ping Ma

Quantum Interior Point Methods (QIPMs) have been attracting significant interests recently due to their potential of solving optimization problems substantially faster than state-of-the-art conventional algorithms. In general, QIPMs use…

Optimization and Control · Mathematics 2024-12-17 Zeguan Wu , Xiu Yang , Tamás Terlaky

We introduce QICS (Quantum Information Conic Solver), an open-source primal-dual interior point solver fully implemented in Python, which is focused on solving optimization problems arising in quantum information theory. QICS has the…

Optimization and Control · Mathematics 2025-07-08 Kerry He , James Saunderson , Hamza Fawzi

Quantum optimal control includes the family of pulse-shaping algorithms that aim to unlock the full potential of a variety of quantum technologies. Our Quantum Optimal Control Suite (QuOCS) unites experimental focus and model-based…

Accurate computation of non-covalent, intermolecular interaction energies is important to understand various chemical phenomena, and quantum computers are anticipated to accelerate it. Although the state-of-the-art quantum computers are…

Quantum Physics · Physics 2025-12-29 Yuhei Tachi , Akihiko Arakawa , Taisei Osawa , Masayoshi Terabe , Kenji Sugisaki

Quantum correlations in an entangled many-body system are capable of storing information. Even when the information is injected by a local unitary operation to the system, the entanglement delocalizes it. In a recent study on multiple-qubit…

Quantum Physics · Physics 2020-06-04 Koji Yamaguchi , Masahiro Hotta

Task scheduling with constrained time intervals and limited resources remains a fundamental challenge across domains such as manufacturing, logistics, cloud computing, and healthcare. This study presents a novel variant of the Quantum…

Quantum Physics · Physics 2026-05-26 José A. Tirado-Domínguez , Eladio Gutiérrez , Oscar Plata

The accuracy of reaction energy profiles calculated with multi-configurational electronic structure methods and corrected by multi-reference perturbation theory depends crucially on consistent active orbital spaces selected along the…

Chemical Physics · Physics 2023-04-14 Moritz Bensberg , Markus Reiher

A recent direction in quantum computing for molecular electronic structure sees the use of quantum devices as configuration sampling machines integrated within high-performance computing (HPC) platforms. This appeals to the strengths of…

Quantum Physics · Physics 2026-05-18 Tim Weaving , Angus Mingare , Alexis Ralli , Peter V. Coveney

Active reconfigurable intelligent surface (A-RIS) aided integrated sensing and communications (ISAC) system has been considered as a promising paradigm to improve spectrum efficiency. However, massive energy-hungry radio frequency (RF)…

Information Theory · Computer Science 2025-01-17 Wei Ma , Peichang Zhang , Junjie Ye , Rouyang Guan , Xiao-Peng Li , Lei Huang
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