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We present an experimentally guided, multi-phase, multi-species polyelectrolyte gel model to make quantitative predictions on the electro-chemical properties of articular cartilage. The mixture theory consists of two different types of…

Tissues and Organs · Quantitative Biology 2013-08-22 Sarthok Sircar , Elizabeth Aisenbrey , Stephanie J. Bryant , David M. Bortz

From a fundamental and application point of view it is of importance to understand how charge carrier generation and transport in a conjugated polymer (CP):fullerene blend are affected by the blend morphology. In this work light-induced…

Soft Condensed Matter · Physics 2017-09-13 Tom J. Savenije , Andreas Sperlich , Hannes Kraus , Oleg G. Poluektov , Martin Heeney , Vladimir Dyakonov

We use state-of-the-art molecular dynamics simulations to study the effects of annealed disorder on the phase separating kinetics and aging phenomena of a segregating binary fluid mixture. In the presence of disorder, we observe a dramatic…

Soft Condensed Matter · Physics 2021-12-01 Rounak Bhattacharyya , Bhaskar Sen Gupta

We present a theory for phase-separated liquid coacervates with salt, taking into account spatial heterogeneities and interfacial profiles. We find that charged layers of alternating sign can form around the interface while the bulk phases…

Soft Condensed Matter · Physics 2024-08-07 Arghya Majee , Christoph A. Weber , Frank Jülicher

Binary mixtures of semiflexible polymers with the same chain length but different persistence lengths separate into two coexisting different nematic phases when the osmotic pressure of the lyotropic solution is varied. Molecular Dynamics…

Soft Condensed Matter · Physics 2020-09-15 Andrey Milchev , Sergei A. Egorov , Jiarul Midya , Kurt Binder , Arash Nikoubashman

We report the formation of colloidal complexes resulting from the electrostatic co-assembly between anionic surfactants and cationic polyelectrolytes or block copolymers. Combining light and x-ray scattering experiments with cryogenic…

Soft Condensed Matter · Physics 2009-04-01 J. -F. Berret

We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…

Soft Condensed Matter · Physics 2013-04-22 Vincent Démery , David S. Dean , Rudolf Podgornik

The cavitation flow of linear-polymer solutions around a cylinder is studied by performing a large-scale molecular dynamics simulation. The addition of polymer chains remarkably suppresses the cavitation. The polymers are stretched into a…

Fluid Dynamics · Physics 2021-07-28 Yuta Asano , Hiroshi Watanabe , Hiroshi Noguchi

Polymer electrolytes are intensely investigated for use as solid electrolytes in next generation lithium-ion and lithium-metal batteries. However, little is known about the structural and dynamical properties of polymer electrolytes close…

Soft Condensed Matter · Physics 2021-12-02 Andreas Thum , Diddo Diddens , Andreas Heuer

The collapse kinetics of strongly charged polyelectrolytes in poor solvents is investigated by Langevin simulations and scaling arguments. The rate of collapse increases sharply as the valence of counterions, z, increases from one to four.…

Soft Condensed Matter · Physics 2007-05-23 Namkyung Lee , D. Thirumalai

The interaction between charged objects in solution is generally expected to recapitulate two central principles of electromagnetics: (i) like-charged objects repel, and (ii) they do so regardless of the sign of their electrical charge.…

Soft Condensed Matter · Physics 2022-12-27 Sida Wang , Rowan Walker-Gibbons , Bethany Watkins , Melissa Flynn , Madhavi Krishnan

Polymer chains adsorbed onto oppositely charged spherical colloidal particles can significantly modify the particle-particle interactions. For sufficient amounts of added polymers, the original electrostatic repulsion can even turn into an…

Soft Condensed Matter · Physics 2015-05-13 D. Truzzolillo , F. Bordi , F. Sciortino , C. Cametti

Polymer brushes normally swell in a good solvent and collapse in a poor solvent. An abnormal response of polymer brushes, so-called co-nonsolvency, is the phenomenon where the brush counter-intuitively collapses in a good solvent mixture.…

Soft Condensed Matter · Physics 2019-08-26 Gyehyun Park , YounJoon Jung

Interfacial energy dissipation during stick-slip motion of a liquid drop on a non-conductive polymer substrate is shown to lead to an irreversible increase in electrical charge. This previously unobserved phenomenon occurs during surface…

When two bubbles submerged in a liquid are brought closely together, the intermediate liquid film separating the bubbles begins to drain. Once the film ruptures, the bubbles coalesce and form a neck that expands with time. The dynamics of…

Fluid Dynamics · Physics 2023-05-03 Alexandros T. Oratis , Vincent Bertin , Jacco H. Snoeijer

Pressure-driven coarsening triggers bubble rearrangements in liquid foams. Our experiments show that changing the continuous phase rheology can alter these internal bubble dynamics without influencing the coarsening kinetics. Through bubble…

Soft Condensed Matter · Physics 2024-05-16 Chiara Guidolin , Emmanuelle Rio , Roberto Cerbino , Fabio Giavazzi , Anniina Salonen

Intermolecular interactions are pivotal for aggregation, solvation, and crystallization. We demonstrate that the collective strong coupling of several molecules to a single optical mode results in notable changes in the molecular…

Quantum Physics · Physics 2024-02-19 Matteo Castagnola , Tor S. Haugland , Enrico Ronca , Henrik Koch , Christian Schäfer

The ability to precisely control surface charge using charged polymers is fundamental to many nanotechnology applications, enabling the design and fabrication of materials with tailored properties and functionalities. Here, we study the…

Soft Condensed Matter · Physics 2025-12-09 Vijay Yadav , Prabhat Kumar Jaiswal , Rudolf Podgornik , Sunita Kumari

We explore theoretically the modifications to the interactions between charged surfaces across an ionic solution caused by the presence of dielectric polymers. Although the chains are neutral, the polymer physics and the electrostatics are…

Soft Condensed Matter · Physics 2007-05-23 O. A. Croze , M. E. Cates

This work aims to identify some inhomogeneity factors for plane symmetric topology with anisotropic and dissipative fluid under the effects of both electromagnetic field as well as Palatini $f(R)$ gravity. We construct the modified field…

General Relativity and Quantum Cosmology · Physics 2016-05-12 M. Zaeem Ul Haq Bhatti , Z. Yousaf