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Based on ab initio evolutionary crystal structure search computation, we report a new phase of phosphorus called green phosphorus ({\lambda}-P), which exhibits the direct band gaps ranging from 0.7 to 2.4 eV and the strong anisotropy in…

Materials Science · Physics 2017-09-15 W. H. Han , Sunghyun Kim , In-Ho Lee , K. J. Chang

By means of the first-principles density functional theory (DFT), I2-II-IV-VI4 type Cu-based quaternary chalcogenides Cu 2 XSiS 4 (X = Ge, Sn, and Pb) have been thoroughly investigated. We report the study of Ge and Sn substitution in the…

Materials Science · Physics 2025-09-26 H. Laltlanmawii , L. Celestine , R. Zosiamliana , B. Chettri , S. Bhattarai , K. C. Bhamu , D. P. Rai

The production of high-quality hexagonal boron nitride (h-BN) is essential for the ultimate performance of two-dimensional (2D) materials-based devices, since it is the key 2D encapsulation material. Here, a decisive guideline is reported…

Materials Science · Physics 2022-10-14 Adrian Hemmi , Ari Paavo Seitsonen , Thomas Greber , Huanyao Cun

Boron nitride (BN) is a material with outstanding technological promise because of its exceptional thermochemical stability, structural, electronic and thermal conductivity properties, and extreme hardness. Yet, the relative thermodynamic…

Materials Science · Physics 2018-12-13 Claudio Cazorla , Tim Gould

Graphene-based materials (GBMs) constitute a large family of materials which has attracted great interest for potential applications. In this work, we apply first-principles calculations based on density functional theory (DFT) and fully…

Materials Science · Physics 2021-05-05 Enesio Marinho , Pedro A. S. Autreto

Graphene nanoribbons (GNRs) with atomically precise width and edge structures are a promising class of nanomaterials for optoelectronics, thanks to their semiconducting nature and high mobility of charge carriers. Understanding the…

Mesoscale and Nanoscale Physics · Physics 2020-04-15 Alexander Tries , Silvio Osella , Pengfei Zhang , Fugui Xu , Mathias Kläui , Yiyong Mai , David Beljonne , Hai I. Wang

The recent discovery of methods to isolate graphene, a one-atom-thick layer of crystalline carbon, has raised the possibility of a new class of nano-electronics devices based on the extraordinary electrical transport and unusual physical…

Mesoscale and Nanoscale Physics · Physics 2008-10-02 Xu Du , Ivan Skachko , Anthony Barker , Eva Y. Andrei

Both theoretical and experimental analysis are carried out to understand the physical properties of the fascinating electronic and optical properties of antimony tungstate (Sb$_2$WO$_6$). The nanosized ($\sim 40-80~nm$) material is produced…

Materials Science · Physics 2021-08-11 Devdas Karmakar , Sujoy Datta , Debnarayan Jana

Phosphorene, a 2D allotrope of phosphorus, is technologically very appealing because of its semiconducting properties and narrow band gap. Further reduction of the phosphorene dimensionality may spawn exotic properties of its electronic…

The growing demand for efficient energy storage has driven the search for advanced anode materials for lithium- and sodium-ion batteries (LIBs and SIBs). In this context, we report the application of HOP-graphene (a 5-6-8-membered 2D carbon…

Penta-graphene is a quasi-two-dimensional carbon allotrope consisting of a pentagonal lattice in which both sp2 and sp3-like carbons are present. Unlike graphene, penta-graphene exhibits a non-zero bandgap, which opens the possibility of…

The class of 2D carbon allotropes has garnered significant attention due to its exceptional optoelectronic and mechanical properties, crucial for diverse device applications, such as energy storage. This study employs density functional…

Materials Science · Physics 2023-11-20 E. J. A. Santos , K. A. L. Lima , L. A. Ribeiro Junior

In this Letter, we derive an effective theory of graphene on a hexagonal Boron Nitride (h-BN) substrate. We show that the h-BN substrate generically opens a spectral gap in graphene despite the lattice mismatch. The origin of that gap is…

Mesoscale and Nanoscale Physics · Physics 2012-11-12 M. Kindermann , Bruno Uchoa , D. L. Miller

An overview is given of recent advances in experimental and theoretical understanding of optical properties of ultra-thin crystal structures (graphene, phosphorene, silicene, MoS2, MoSe2 , WS2 , WSe2 , h-AlN, h-BN, fluorographene,…

Mesoscale and Nanoscale Physics · Physics 2016-03-02 H. Sahin , E. Torun , C. Bacaksiz , S. Horzum , J. Kang , R. T. Senger , F. M. Peeters

Recently a stable monolayer of antimony in buckled honeycomb structure called antimonene was successfully grown on 3D topological insulator Bi$_2$Te$_3$ and Sb$_2$Te$_3$, which displays semiconducting properties. By first principle…

Materials Science · Physics 2017-03-22 Yuanfeng Xu , Bo Peng , Hao Zhang , Hezhu Shao , Rongjun Zhang , Hongliang Lu , David Wei Zhang , Heyuan Zhu

The adsorption of boron and oxygen atoms onto mono- and multi-layer graphene leads to the formation of a buckled graphene layer (BO-graphane) and a 2D diamond-like structure (BO-diamane) sandwiched between boron monoxide layers per DFT…

Materials Science · Physics 2025-06-09 Babu Ram , Rohit Anand , Arun S. Nissimagoudar , Geunsik Lee , Rodney S Ruoff

Since the advent of graphene, two-dimensional (2D) materials become very attractive and there is growing interest to explore new 2D beyond graphene. Here, through density functional theory (DFT) calculations, we predict 2D wide-band-gap…

Mesoscale and Nanoscale Physics · Physics 2016-10-31 Xue-Jing Zhang , Bang-Gui Liu

A new dislocation structure-square-octagon pair (4|8) is discovered in two-dimensional boron nitride (h-BN), via first-principles calculations. It has lower energy than corresponding pentagon-heptagon pairs (5|7), which contain unfavorable…

Materials Science · Physics 2012-08-02 Yuanyue Liu , Xiaolong Zou , Boris I. Yakobson

The electronic and magnetic properties of varying width, oxygen-functionalized armchair graphene nanoribbons (AGNRs) are investigated using first-principles density functional theory (DFT). Our study shows that O-passivation results in a…

Recently hybridized monolayers consisting of hexagonal boron nitride (h-BN) phases inside graphene layer have been synthesized and shown to be an effective way of opening band gap in graphene monolayers [1]. In this letter, we report an ab…

Materials Science · Physics 2012-04-27 Qing Peng , Amir R. Zamiri , Wei Ji , Suvranu De
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