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Thermal conductance of single molecular junctions at room temperature has been measured recently using picowatt-resolution scanning probes. However, fully understanding thermal transport in a much wider temperature range is needed for the…

Mesoscale and Nanoscale Physics · Physics 2022-02-15 Gen Li , Bing-Zhong Hu , Nuo Yang , Jing-Tao Lü

A model for the thermodynamics of a quantum heat bath is introduced. Under the assumption that the bath molecules have finitely many degrees of freedom and are weakly interacting, we present a general derivation of the equation of state of…

Quantum Physics · Physics 2016-12-12 Dorje C. Brody , Lane P. Hughston

We present a scattering approach for the study of the transport and thermodynamics of quantum systems strongly coupled to their thermal environment(s). This formalism recovers the standard non-equilibrium Green's function expressions for…

Statistical Mechanics · Physics 2020-07-15 Alexander Semenov , Abraham Nitzan

We study the nonequilibrium steady-state of a fully-coupled network of $N$ quantum harmonic oscillators, interacting with two thermal reservoirs. Given the long-range nature of the couplings, we consider two setups: one in which the number…

Statistical Mechanics · Physics 2022-09-27 Francesco Andreucci , Stefano Lepri , Stefano Ruffo , Andrea Trombettoni

Molecular or condensed matter systems are often well approximated by hybrid quantum-classical models: the electrons retain their quantum character, whereas the ions are considered to be classical particles. We discuss various alternative…

Chemical Physics · Physics 2021-05-07 J. L. Alonso , C. Bouthelier , A. Castro , J. Clemente-Gallardo , J. A. Jover-Galtier

The treatment of quantum thermodynamic systems beyond weak coupling is of increasing relevance, yet extremely challenging. The evaluation of thermodynamic quantities in strong-coupling regimes requires a nonperturbative knowledge of the…

Quantum Physics · Physics 2025-01-16 Francesco Albarelli , Bassano Vacchini , Andrea Smirne

Quasicentroid molecular dynamics (QCMD) is a path-integral method for approximating nuclear quantum effects in dynamics simulations, which has given promising results for gas- and condensed-phase water. Here, by simulating the infrared…

Chemical Physics · Physics 2021-11-29 Christopher Haggard , Vijay Ganesh Sadhasivam , George Trenins , Stuart C. Althorpe

We construct a finite bath with variable temperature for quantum thermodynamic simulations in which heat flows between a system $\mathcal{S}$ and the bath environment $\mathcal{E}$ in time evolution of an initial $\mathcal{SE}$ pure state.…

Statistical Mechanics · Physics 2019-10-09 Phillip C. Lotshaw , Michael E. Kellman

With the objective to understand microscopic principles governing thermal energy flow in nanojunctions, we study phononic heat transport through metal-molecule-metal junctions using classical molecular dynamics (MD) simulations. Considering…

Mesoscale and Nanoscale Physics · Physics 2022-11-23 Jonathan J. Wang , Jie Gong , Alan J. H. McGaughey , Dvira Segal

Conventional continuous quantum heat engines with incoherent heat transfer perform poorly as they exploit two-body interactions between the system and hot or cold baths, thus having limited capability to outperform their classical…

In this review the debated rapport between thermodynamics and quantum mechanics is addressed in the framework of the theory of periodically-driven/controlled quantum-thermodynamic machines. The basic model studied here is that of a…

Quantum Physics · Physics 2015-09-15 D. Gelbwaser-Klimovsky , Wolfgang Niedenzu , Gershon Kurizki

The powerful molecular dynamics (MD) simulation is basically based on a picture that the atoms experience classical-like trajectories under the exertion of classical force field determined by the quantum mechanically solved electronic…

Chemical Physics · Physics 2013-12-16 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang

We perform benchmark simulations using the time-dependent variational approach with the multiple Davydov Ansatz (mDA) to study realtime nonequilibrium dynamics in a single qubit model coupled to two thermal baths with distinct temperatures.…

Quantum Physics · Physics 2025-10-13 Chenlin Ma , Fulu Zheng , Kewei Sun , Lu Wang , Yang Zhao

We present an approach for carrying out non-adiabatic molecular dynamics simulations of systems in which non-adiabatic transitions arise from the coupling between the classical atomic motions and a quasi-continuum of electronic quantum…

Computational Physics · Physics 2018-11-21 Jerome Daligault , Dmitry Mozyrsky

The performance characteristics of a heat rectifier and a heat pump are studied in a non Markovian framework. The device is constructed from a molecule connected to a hot and cold reservoir. The heat baths are modelled using the stochastic…

Quantum Physics · Physics 2016-06-09 Gil Katz , Ronnie Kosloff

A generalized Langevin equation with quantum baths (QMD) for thermal transport is derived with the help of nonequilibrium Green's function (NEGF) formulation. The exact relationship of the quasi-classical approximation to NEGF is…

Mesoscale and Nanoscale Physics · Physics 2009-12-23 Jian-Sheng Wang , Xiaoxi Ni , Jin-Wu Jiang

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to a harmonic quantum thermal bath is exactly solvable. It is shown that at low enough temperatures the stationary state is non-Gibbsian due to an…

Statistical Mechanics · Physics 2007-05-23 Th. M. Nieuwenhuizen , A. E. Allahverdyan

Nonequilibrium molecular dynamics (NEMD) has been extensively used to study thermal transport at various length scales in many materials. In this method, two local thermostats at different temperatures are used to generate a nonequilibrium…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Zhen Li , Shiyun Xiong , Charles Sievers , Yue Hu , Zheyong Fan , Ning Wei , Hua Bao , Shunda Chen , Davide Donadio , Tapio Ala-Nissila

First-principles molecular dynamics simulation based on a plane wave/pseudopotential implementation of density functional theory is adopted to investigate atomic scale energy transport for semiconductors (silicon and germanium). By imposing…

Computational Physics · Physics 2016-02-02 Pengfei Ji , Yuwen Zhang

In this article we review aspects of charge and heat transport in interacting quantum dots and molecular junctions under stationary and time-dependent non-equilibrium conditions due to finite electrical and thermal bias. In particular, we…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 F. Haupt , M. Leijnse , H. L. Calvo , L. Classen , J. Splettstoesser , M. R. Wegewijs