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We apply the Born--Oppenheimer approximation to a harmonic diatomic molecule with one electron. We compare the exact and approximate results not only for the internal degrees of freedom but also for the motion of the center of mass. We…

Mathematical Physics · Physics 2017-07-18 Francisco M. Fernández

There exists a growing interest in the properties of the light generated by hybrid systems involving a mesoscopic number of emitters as a means of providing macroscopic quantum light sources. In this work, the quantum correlations of the…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 R. Sáez-Blázquez , J. Feist , F. J. García-Vidal , A. I. Fernández-Domínguez

We discuss a simple singular system in one dimension, two heavy particles interacting with a light particle via an attractive contact interaction. It is natural to apply Born-Oppenheimer approximation to this problem. We present a detailed…

Mathematical Physics · Physics 2016-03-30 Haci Akbas , O. Teoman Turgut

Electron-photon quantum entanglement in an electron microscope paves the way for a new quantum platform, enabling the integration of quantum functionalities into electron microscopy and opening opportunities for quantum imaging and quantum…

Quantum Physics · Physics 2026-05-25 Tatsuro Yuge , Ryo Okamoto , Takumi Sannomiya , Keiichirou Akiba

Under appropriate conditions, superconducting electronic circuits behave quantum mechanically, with properties that can be designed and controlled at will. We have realized an experiment in which a superconducting two-level system, playing…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Wallraff , D. I. Schuster , A. Blais , L. Frunzio , R. -S. Huang , J. Majer , S. Kumar , S. M. Girvin , R. J. Schoelkopf

We analyze the entanglement between electronic and nuclear motions in molecular wave functions, by using different widely used ansatzes in molecular Hamiltonian models (H$^+_2$ in 1D and the Shin-Metiu model); namely, i) Born-Oppenheimer…

Quantum Physics · Physics 2025-11-13 Juan F. P. Mosquera , Jose Luis Sanz-Vicario

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

We introduce a simple scheme to efficiently compute photon exchange-correlation contributions due to the coupling to transversal photons as formulated in the newly developed quantum-electrodynamical density functional theory (QEDFT). Our…

Quantum Physics · Physics 2018-04-16 Johannes Flick , Christian Schäfer , Michael Ruggenthaler , Heiko Appel , Angel Rubio

We develop a formalism to accurately account for the renormalization of electronic structure due to quantum and thermal nuclear motions within the Born-Oppenheimer approximation. We focus on the fundamental energy gap obtained from…

Materials Science · Physics 2021-02-03 Vitaly Gorelov , David M. Ceperley , Markus Holzmann , Carlo Pierleoni

In our recent paper [1], we reported observations of photon blockade by one atom strongly coupled to an optical cavity. In support of these measurements, here we provide an expanded discussion of the general phenomenology of photon blockade…

Quantum Physics · Physics 2009-11-11 K. M. Birnbaum , A. Boca , R. Miller , A. D. Boozer , T. E. Northup , H. J. Kimble

Optical non-linearities at the single-photon level are key ingredients for future photonic quantum technologies. Prime candidates for the realization of strong photon-photon interactions necessary for implementing quantum information…

Mesoscale and Nanoscale Physics · Physics 2012-02-10 Andreas Reinhard , Thomas Volz , Martin Winger , Antonio Badolato , Kevin J. Hennessy , Evelyn L. Hu , Atac Imamoglu

Cavity-polaritons in semiconductor microstructures have emerged as a promising system for exploring nonequilibrium dynamics of many-body systems. Key advances in this field, including the observation of polariton condensation,…

Mesoscale and Nanoscale Physics · Physics 2019-04-05 Aymeric Delteil , Thomas Fink , Anne Schade , Sven Höfling , Christian Schneider , Ataç Imamoğlu

Polariton chemistry exploits the strong interaction between quantized excitations in molecules and quantized photon states in optical cavities to affect chemical reactivity. Molecular polaritons have been experimentally realized by the…

Chemical Physics · Physics 2023-09-06 Jonathan J. Foley , Jonathan F. McTague , A. Eugene DePrince

Ultracold atoms coupled to optical cavities offer a powerful platform for studying strongly correlated many-body physics. Here, we propose an experimental scheme for creating biatomic molecules via cavity-enhanced photoassociation from an…

Quantum Gases · Physics 2026-04-17 Yun Chen , Yuqi Wang , Jingjun You , Yingqi Liu , Su Yi , Yuangang Deng

We present a universal expression for the electronic friction as felt by a set of classical nuclear degrees of freedom (DoF's) coupled to a manifold of quantum electronic DoF's; no assumptions are made regarding the nature of the electronic…

Materials Science · Physics 2017-08-02 Wenjie Dou , Gaohan Miao , Joseph E. Subotnik

The electron attachment variant of equation-of-motion coupled-cluster theory (EOM-EA-CC) is generalized to the case of strong light-matter coupling within the framework of cavity quantum electrodynamics (QED). The resulting EOM-EA-QED-CC…

Chemical Physics · Physics 2022-02-23 Marcus D. Liebenthal , Nam Vu , A. Eugene DePrince

We theoretically predict the interaction between polaritonic excitations arising from the coupling of a cavity photon mode with bound to continuum intersubband transitions in a doped quantum well. The resulting exciton bound by photon…

Other Condensed Matter · Physics 2025-10-29 Miguel S. Oliveira , Cristiano Ciuti

A single cavity photon mode is expected to modify the Coulomb interaction of an electron system in the cavity. Here we investigate this phenomena in a parallel double quantum dot system. We explore properties of the closed system and the…

Mesoscale and Nanoscale Physics · Physics 2016-05-17 Vidar Gudmundsson , Anna Sitek , Nzar Rauf Abdullah , Chi-Shung Tang , Andrei Manolescu

We study coherent photoassociation, phenomena analogous to coherent optical transients in few-level systems, which may take place in photoassociation of an atomic Bose-Einstein condensate but not in a nondegenerate gas. We develop a…

Atomic Physics · Physics 2016-09-08 Marijan Kostrun , Matt Mackie , Robin Cote , Juha Javanainen