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We present a plane-wave ultrasoft pseudopotential implementation of first-principle molecular dynamics, which is well suited to model large molecular systems containing transition metal centers. We describe an efficient strategy for…

Materials Science · Physics 2007-05-23 P. Giannozzi , F. De Angelis , R. Car

First-principles methods for time-resolved angular resolved photoelectron spectroscopy play a pivotal role in providing interpretation and microscopic understanding of the complex experimental data and in exploring novel observables or…

Materials Science · Physics 2021-12-28 Umberto De Giovannini , Shunsuke A. Sato , Hannes Hübener , Angel Rubio

Two- and multi-dimensional spectroscopy is used in physics and chemistry to obtain structural and dynamical information that would otherwise be invisible by the projection into a one-dimensional data set such as a single emission or…

Ab initio techniques have revolutionised the way in which theory can help practitioners to explore critical mechanisms that govern reactions or properties, and to develop new strategies for materials discovery and design. Yet, their…

Materials Science · Physics 2026-04-03 Mira Todorova , Stefan Wippermann , Jörg Neugebauer

In this manuscript we present a theoretical framework and its numerical implementation to simulate the out-of-equilibrium electron dynamics induced by the interaction of ultrashort laser pulses in condensed-matter systems. Our approach is…

Spectroscopy is a crucial laboratory technique for understanding quantum systems through their interactions with electromagnetic radiation. Particularly, spectroscopy is capable of revealing the physical structure of molecules, leading to…

Quantum Physics · Physics 2018-05-24 Ling Hu , YueChi Ma , Y. Xu , W. Wang , Y. Ma , K. Liu , M. -H. Yung , L. Sun

This work investigates two physics-based models that simulate the non-linear partial differential algebraic equations describing an electric double layer supercapacitor. In one model the linear dependence between electrolyte concentration…

Systems and Control · Computer Science 2014-12-09 Ross Drummond , David A. Howey , Stephen R. Duncan

The paper presents numerical simulations performed on dielectric properties of two-dimensional binary composites on eleven regular space filling tessellations. First, significant contributions of different parameters, which play an…

Materials Science · Physics 2007-05-23 Enis Tuncer

The increasing need to simulate the dynamics of photoexcited molecular and nanosystems in the sub-picosecond regime demands new efficient tools able to describe the quantum nature of matter at a low computational cost. By combining the…

We develop a general-purpose formulation, based on two-dimensional spectral integrals, for computing electromagnetic fields produced by arbitrarily-oriented dipoles in planar-stratified environments, where each layer may exhibit arbitrary…

Computational Physics · Physics 2014-11-27 K. Sainath , F. L. Teixeira , B. Donderici

We develop a simulation framework for electrostatic and transport modeling of 2D Topological insulator field-effect transistor (2D TIFETs), based solely on first-principles calculations using density functional theory (DFT). We find that…

Mesoscale and Nanoscale Physics · Physics 2026-03-30 Hyeonseok Choi , Yosep Park , Subeen Lim , Yeonghun Lee

As an aid to the development of hydrogen separation membranes, we predict the temperature dependent phase diagrams using first principles calculations combined with thermodynamic principles. Our method models the phase diagram without…

Materials Science · Physics 2014-08-07 William Paul Huhn , Michael Widom , Michael C. Gao

This is the first in a series of two papers investigating the effect of electron-phonon coupling in two-dimensional Fourier transformed electronic spectroscopy. We present a series of one- and two-dimensional nonlinear spectroscopic…

The fast dynamics of molecular polaritonics is scrutinized theoretically through the implementation of two-dimensional spectroscopy protocols. We derive conceptually simple and computationally efficient formulas to calculate two-dimensional…

Quantum Physics · Physics 2024-03-08 Daniela Gallego-Valencia , Lars Mewes , Johannes Feist , José Luis Sanz-Vicario

We have investigated the structure of cyclohexene-2-ethanamine molecule both theoretically and experimantally. Theoretical investigation is based on a first principle technique Density Functional Theory (DFT) using plane wave basis sets and…

Materials Science · Physics 2009-11-13 T. Izgi , E. Akturk , O. Gulseren , M. Senyel

Programmable electron-beam scanning offers new opportunities to improve dose efficiency and suppress scan-induced artifacts in scanning transmission electron microscopy. Here, we systematically benchmark the impact of non-raster…

The discovery of molecules with tailored optoelectronic properties such as specific frequency and intensity of absorption or emission is a major challenge in creating next-generation organic light-emitting diodes (OLEDs) and photovoltaics.…

Chemical Physics · Physics 2022-04-27 James David Green , Eric Gabriel Fuemmeler , Timothy J. H. Hele

This chapter provides a tutorial overview of first principles methods to describe the properties of matter at the ground state or equilibrium. It begins with a brief introduction to quantum and statistical mechanics for predicting the…

Computational Engineering, Finance, and Science · Computer Science 2020-10-14 Jianzhong Wu , Mengyang Gu

An efficient computational approach for optimal reconstruction of binary-type images suitable for models in various applications including biomedical imaging is developed and validated. The methodology includes derivative-free optimization…

Optimization and Control · Mathematics 2022-09-27 Paul R. Arbic , Vladislav Bukshtynov

Time-resolved photoemission spectroscopy is the key technique to probe the real-time non-equilibrium dynamics of electronic states. Theoretical predictions of the time dependent spectral function for realistic systems is however, a…

Computational Physics · Physics 2024-05-24 Cian Reeves , Vojtech Vlcek