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We present fluctuation theorems and moment generating function equalities for generalized thermodynamic observables and quantum dynamics described by completely positive trace preserving (CPTP) maps, with and without feedback control. Our…

Quantum Physics · Physics 2013-10-01 Tameem Albash , Daniel A. Lidar , Milad Marvian , Paolo Zanardi

Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate…

Statistical Mechanics · Physics 2008-07-11 Peter Talkner , Peter Hanggi , Manuel Morillo

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as $10^{23}$ degrees of…

Statistical Mechanics · Physics 2008-02-01 Giovanni Gallavotti

The physical significance of the stochastic processes associated to the generalized Gibbs ensembles is scrutinized here with special attention to the thermodynamic fluctuations of small systems. The contact with the environment produces an…

Statistical Mechanics · Physics 2024-09-04 Amilcare Porporato , Salvatore Calabrese , Lamberto Rondoni

In quantum information geometry, the curvature of von-Neumann entropy and relative entropy induce a natural metric on the space of mixed quantum states. Here we use this information metric to construct a random matrix ensemble for states…

Quantum Physics · Physics 2026-01-26 Harry J. D. Miller

An unified thermodynamical framework based in the use of a generalized Massieu-Planck thermodynamic potential is proposed and a new formulation of Boltzmann-Gibbs Statistical Mechanics is established. Under this philosophy a generalization…

Mathematical Physics · Physics 2007-05-23 V. Garcia-Morales , J. Pellicer

People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…

Statistical Mechanics · Physics 2025-08-05 Yu Qiao , Zhaoru Shang

For more than 100 years, one of the central concepts in statistical mechanics has been the microcanonical ensemble, which provides a way of calculating the thermodynamic entropy for a specified energy. A controversy has recently emerged…

Statistical Mechanics · Physics 2016-07-04 Michael Matty , Lachlan Lancaster , William Griffin , Robert H. Swendsen

Starting from the stochastic thermodynamics description of two coupled underdamped Brownian particles, we showcase and compare three different coarse-graining schemes leading to an effective thermodynamic description for the first of the…

Statistical Mechanics · Physics 2020-02-20 Tim Herpich , Kamran Shayanfard , Massimiliano Esposito

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

Multiscale systems are ubiquitous in science and technology, but are notoriously challenging to simulate as short spatiotemporal scales must be appropriately linked to emergent bulk physics. When expensive high-dimensional dynamical systems…

Machine Learning · Computer Science 2025-12-30 Quercus Hernandez , Max Win , Thomas C. O'Connor , Paulo E. Arratia , Nathaniel Trask

The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…

Statistical Mechanics · Physics 2016-03-23 Dragos-Victor Anghel

An analysis of the thermodynamic behavior of quantum systems can be performed from a geometrical perspective investigating the structure of the state space. We have developed such an analysis for nonextensive thermostatistical frameworks,…

Statistical Mechanics · Physics 2009-11-11 M. Portesi , A. Plastino , F. Pennini

Algorithmic approach is based on the assumption that any quantum evolution of many particle system can be simulated on a classical computer with the polynomial time and memory cost. Algorithms play the central role here but not the…

Quantum Physics · Physics 2007-05-23 Yuri Ozhigov

The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…

Statistical Mechanics · Physics 2008-11-01 Giovanni Gallavotti

On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…

Statistical Mechanics · Physics 2017-07-05 Renato Pakter , Yan Levin

In statistical mechanics, measuring the number of available states and their probabilities, and thus the system's entropy, enables the prediction of the macroscopic properties of a physical system at equilibrium. This predictive capacity…

Statistical Mechanics · Physics 2023-12-14 Mathias Casiulis , Stefano Martiniani

Fluctuation theorems and the second law of thermodynamics are powerful relations constraining the behavior of out-of-equilibrium systems. While there exist generalizations of these relations to feedback controlled quantum systems, their…

Quantum Physics · Physics 2024-10-07 Kacper Prech , Patrick P. Potts