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Astronomical mid-IR spectra show two minor PAH features at 5.25 and 5.7 $\mu$m (1905 and 1754 cm$^{\rm - 1}$) that hitherto have been little studied, but contain information about the astronomical PAH population that complements that of the…

The chemistry of astronomical hydrocarbons, responsible for the well-known infrared emission features detected in a wide variety of targets, remains enigmatic. Here we focus on the group of young intermediate-mass Herbig Ae stars. We have…

Solar and Stellar Astrophysics · Physics 2015-05-19 B. Acke , J. Bouwman , A. Juhash , Th. Henning , M. E. van den Ancker , G. Meeus , A. G. G. M. Tielens , L. B. F. M. Waters

Aims. The chemistry of, and infrared (IR) emission from, polycyclic aromatic hydrocarbons (PAHs) in disks around Herbig Ae/Be and T Tauri stars are investigated. The equilibrium distribution of the PAHs over all accessible…

The mid-infrared spectrum contains rich diagnostics to probe the physical properties of galaxies, among which the pervasive emission features from polycyclic aromatic hydrocarbons (PAHs) offer a promising means of estimating the star…

Astrophysics of Galaxies · Physics 2020-12-23 Lulu Zhang , Luis C. Ho , Yanxia Xie

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, 11.3 and 12.7 micron are ubiquitously seen in a wide variety of astrophysical regions and commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules.…

Astrophysics of Galaxies · Physics 2024-03-11 Kaijun Li , Aigen Li , Xuejuan Yang , Taotao Fang

Polycyclic Aromatic Hydrocarbon (PAH) emission features dominate the mid-infrared spectra of star-forming galaxies and can be useful to calibrate star formation rates and diagnose ionized states of grains. However, the PAH 3.3 micron…

The 11.3 $\mu$m emission feature is a prominent member of the family of unidentified infrared emission (UIE) bands and is frequently attributed to out-of-plane bending modes of polycyclic aromatic hydrocarbon (PAH) molecules. We have…

Solar and Stellar Astrophysics · Physics 2015-07-15 SeyedAbdolreza Sadjadi , Yong Zhang , Sun Kwok

The mid-infrared spectra of large PAHs ranging from C54H18 to C130H28 are determined computationally using Density Functional Theory. Trends in the band positions and intensities as a function of PAH size, charge and geometry are discussed.…

Astrophysics · Physics 2012-08-27 Charles W. Bauschlicher, , Els Peeters , Louis J. Allamandola

Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they…

Solar and Stellar Astrophysics · Physics 2026-03-18 Charlotte Smith-Perez , Aidan Hembruff , Els Peeters , Alexander G. G. M. Tielens , Alessandra Ricca

Long-slit 8-13 um spectroscopy of the nebula around NGC 1333 SVS reveals spatial variations in the strength and shape of emission features which are probably produced by polycyclic aromatic hydrocarbons (PAHs). Close to SVS 3, the 11.2 um…

Astrophysics · Physics 2009-10-31 G. C. Sloan , T. L. Hayward , L. J. Allamandola , J. D. Bregman , B. DeVito , D. M. Hudgins

This joint theoretical and experimental study establishes that the adsorption of polycyclic aromatic hydrocarbons (PAHs) onto the amorphous ice surface provokes a broadening and redshift of the "dangling" OH (dOH) ice spectral feature, the…

Chemical Physics · Physics 2020-03-05 E Michoulier , C Toubin , A Simon , J Mascetti , C Aupetit , J A Noble

We have examined polycyclic aromatic hydrocarbon (PAH) excitation in a sample of 25 nearby face-on spiral galaxies using the ratio of mid-infrared PAH emission to dust mass. Within 11 of the galaxies, we found that the PAH excitation was…

Astrophysics of Galaxies · Physics 2020-06-09 G. J. Bendo , N. Lu , A. Zijlstra

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of…

We present intrinsic extinction curves for 14 AGNs. The AGNs have reddenings, E(B-V), of up to 0.36 mag. The majority (13 out of 14) of the extinction curves are not steep in the UV. Of the seven best determined extinction curves, five have…

Astrophysics · Physics 2007-11-08 C. Martin Gaskell , A. J. Benker

We present the results of mid-infrared N-band spectroscopy of the Herbig Ae/Be system MWC1080 using the Cooled Mid-Infrared Camera and Spectrometer (COMICS) on board the 8m Subaru Telescope. The MWC1080 has a geometry such that the diffuse…

We present, for the first time, a systematic study of quasar-associated 2175 \AA\ dust absorbers using spectroscopic data from the Sloan Digital Sky Survey (SDSS) Data Release 16 (DR16). By analyzing the optical spectra and multi-band…

Astrophysics of Galaxies · Physics 2025-05-28 Shaohua Zhang , Yuchong Luo , Shangchun Xie , Chao Gao , Zhijian Luo , Chenggang Shu , Hubing Xiao

This study theoretically predicts the specific Polycyclic Aromatic Hydrocarbon (PAH) molecules to reproduce both astronomically observed Infrared Bands (IR) and Diffuse Interstellar Bands (DIB). In our recent paper, we could reproduce IR by…

Astrophysics of Galaxies · Physics 2023-11-23 Norio Ota

We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the…

The observed variations in profiles of the interstellar aromatic infrared bands correlate with the object type and are indicative of PAH populations existing i n different sources. Spectroscopic studies on PAHs can provide tools for the int…

Astrophysics · Physics 2009-11-13 Amit Pathak , Shantanu Rastogi