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We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…

Soft Condensed Matter · Physics 2013-07-19 Jiajia Zhou , Roman Schmitz , Burkard Duenweg , Friederike Schmid

We study the melting behavior of charged colloidal crystals, using a simulation technique that combines a continuous mean-field Poisson-Boltzmann description for the microscopic electrolyte ions with a Brownian-dynamics simulation for the…

Soft Condensed Matter · Physics 2009-11-13 J. Dobnikar , Y. Chen , R. Rzehak , H. H. von Grünberg

It is shown how the exchange interaction, the dipole-dipole interaction, and the Dzyaloshinsky-Moriya interaction between electronic spin-density fluctuations emerge naturally from a field-theoretic framework that couples electrons to the…

Strongly Correlated Electrons · Physics 2013-10-01 D. Belitz , T. R. Kirkpatrick

Euclidean quantum fields obtained as solutions of stochastic partial pseudo differential equations driven by a Poisson white noise have paths given by locally integrable functions. This makes it possible to define a class of ultra-violet…

Mathematical Physics · Physics 2010-01-15 S. Albeverio , H. Gottschalk , M. W. Yoshida

The Poisson-Boltzmann equation for a strongly charged plate inside a generic charge-asymmetric electrolyte is solved using the method of asymptotic matching. Both near field and far field asymptotic behaviors of the potential are…

Soft Condensed Matter · Physics 2015-06-05 Ming Han , Xiangjun Xing

We analyze the simplest problem of electrochemical relaxation in more than one dimension - the response of an uncharged, ideally polarizable metallic sphere (or cylinder) in a symmetric, binary electrolyte to a uniform electric field. In…

Materials Science · Physics 2009-11-11 Kevin T. Chu , Martin Z. Bazant

We derive a Debye-H\"uckel-like model of the electric ion-ion interaction for non-constant dielectric susceptibility, which does not depend on any kind of charging process due to its foundation in the general framework of non-equilibrium…

Chemical Physics · Physics 2025-02-24 Wolfgang Dreyer , Rüdiger Müller

A modified version of the spinless Anderson model is studied by means of the continuous-time quantum Monte Carlo method. This study is motivated by the peculiar heavy-fermion behavior observed in certain Samarium compounds, which is…

Strongly Correlated Electrons · Physics 2015-10-28 Annamaria Kiss , Yoshio Kuramoto , Junya Otsuki

The importance of electrostatic interactions in soft matter and biological systems can often be traced to non-uniform charge effects, which are commonly described using a multipole expansion of the corresponding charge distribution. The…

Soft Condensed Matter · Physics 2018-04-23 Anže Lošdorfer Božič

We present a Ginzburg-Landau theory of inhomogeneous polyelectrolytes with a polar solvent. First, we take into account the molecular (solvation) interaction among the ions, the charged monomers, the uncharged monomers, and the solvent…

Soft Condensed Matter · Physics 2009-03-10 Akira Onuki , Ryuichi Okamoto

Realistic charged macromolecules are characterized by discrete (rather than homogeneous) charge distributions. We investigate the effects of surface charge discretization on the counterion distribution at the level of mean-field theory…

Soft Condensed Matter · Physics 2007-05-23 Mark L. Henle , Christian D. Santangelo , Deena M. Patel , Philip A. Pincus

We consider a bosonic Josephson junction made of $N$ ultracold and dilute atoms confined by a quasi one-dimensional double-well potential within the two-site Bose-Hubbard model framework. The behaviour of the system is investigated at zero…

Quantum Gases · Physics 2015-03-19 Giovanni Mazzarella , Luca Salasnich , Alberto Parola , Flavio Toigo

Interactions between charged colloidal particles are profoundly influenced by charge regulation and charge renormalization, rendering the effective potential highly sensitive to local particle density. In this work, we investigate how a…

Soft Condensed Matter · Physics 2025-11-10 Laura Jansen , Thijs ter Rele , Marjolein Dijkstra

Assuming the charged particle to be a two-dimensional oscillator that scatters the classical background of zero-point field one can deduce the Coulomb force of the two interacting particles. The correct deduction of the force is conditioned…

General Physics · Physics 2021-06-09 Ion Simaciu , Zoltan Borsos , Viorel Drafta , Gheorghe Dumitrescu

Because micro-ions accumulate around highly charged colloidal particles in electrolyte solutions, the relevant parameter to compute their interactions is not the bare charge, but an effective (or renormalized) quantity, whose value is…

Soft Condensed Matter · Physics 2009-11-07 Lyderic Bocquet , Emmanuel Trizac , Miguel Aubouy

We examine electrolyte systems confined between two parallel, grounded metal plates using a field-theoretic approach truncated at one-loop order. For symmetric electrolytes, the density distribution of the ions is non-uniform, with a…

Soft Condensed Matter · Physics 2007-05-23 T. Brandes , L. Lue

We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…

Soft Condensed Matter · Physics 2013-04-22 Vincent Démery , David S. Dean , Rudolf Podgornik

We study a model for macroions in an electrolyte solution confined by a semipermeable membrane. The membrane finite thickness is considered and both membrane surfaces are uniformly charged. The model explicitly includes electrostatic and…

Soft Condensed Matter · Physics 2007-05-23 Felipe Jimenez-Angeles , Marcelo Lozada-Cassou

We study the electrophoretic mobility of spherical particles and the electrical conductivity in salt-free concentrated suspensions including finite ion size effects. An ideal salt-free suspension is composed of just charged colloidal…

Soft Condensed Matter · Physics 2017-09-13 Rafael Roa , Félix Carrique , Emilio Ruiz-Reina