Related papers: A quantitative theoretical model of the boson peak…
All solids, whether crystalline or disordered, support elastic wave propagation with a linear dispersion relation in the long-wavelength limit. These waves, corresponding to low-frequency phonons, feature a vibrational density of states…
Glasses have a large excess of low-frequency vibrational modes in comparison with continuous elastic body, the so-called Boson Peak, which appears to correlate with several crucial properties of glasses, such as transport or fragility. I…
Based on a description of an amorphous solid as a collection of coupled nanosize molecular clusters referred as basic blocks, we analyse the statistical properties of its Hamiltonian. The information is then used to derive the ensemble…
Glasses possess more low-frequency vibrational modes than predicted by Debye theory. These excess modes are crucial for the understanding the low temperature thermal and mechanical properties of glasses, which differ from those of…
We present an implementation of the analytical string theory recently applied to the description of glasses. These are modeled as continuum media with embedded elastic string heterogeneities, randomly located and randomly oriented, which…
Vibrational spectra of proteins and topologically disordered solids display a common anomaly at low frequencies, known as Boson peak. We show that such feature in globular proteins can be deciphered in terms of an energy landscape picture,…
A detailed pressure-dependence study of the low-energy excitations of glassy As2S3 is reported over a wide pressure range, up to 10 GPa. The spectral features of Boson peak are analysed as a function of pressure. Pressure effects on the…
We demonstrate using the classical density functional theory (DFT) model that an intermediate degree of mass localization in the amorphous state is essential for producing the boson peak. The localization length $\ell$ is identified from…
The low frequency vibrational anomaly known as Boson peak (BP) have been studied extensively in various disordered systems, however its origin and theoretical description are still under debate. In this work, as one of the simplest model…
We present a novel analytical model for glasses, starting from the first principle that the disorder in a glass mimics the disorder in a fluid. The origin of the boson peak is attributed to the intrinsically noncommutative geometry of the…
We study, analytically and numerically, an off-lattice model of scalar harmonic vibrations for structural glasses. The model has a Boson-Peak which we argue can be considered as a prototype for materials with a Boson Peak frequency that…
Amorphous solids manifest puzzling effects of mysterious degrees of freedom that give rise to a heat capacity and phonon scattering in great excess over what would be expected for a solid that has a unique vibrational ground state. Of…
We introduce an algorithm that constructs disordered mass-spring networks whose elastic properties mimic that of glasses by tuning the fluctuations of the local elastic properties, keeping fixed connectivity and controlling the prestress.…
Phonon spectra in solids often display anomalies that defy the simple Debye law, most prominently the van Hove singularity in crystals and the boson peak in glasses. Although traditionally regarded as distinct, both features are…
A close inspection of neutron spectra of glass formers in the frequency region above the boson peak does not show the constant eigenvalue density expected for a random dynamical matrix, but a slow decrease towards higher eigenvalues. In…
Besides the dynamical slowing down signaled by an enormous increase of the viscosity approaching the glass transition, structural glasses show interesting anomalous thermodynamic features at low temperatures that hint at peculiar deviations…
We perform extensive molecular dynamics simulations of the TIP4P/2005 model of water to investigate the origin of the Boson peak reported in experiments on supercooled water in nanoconfined pores, and in hydration water around proteins. We…
We develop an analytical model to describe the phonon dispersion relations of host-guest lattices with heavy guest atoms (rattlers). Crucially, the model also accounts for phonon damping arising from anharmonicity. The spectrum of low…
We conduct experiments on two-dimensional packings of colloidal thermosensitive hydrogel particles whose packing fraction can be tuned above the jamming transition by varying the temperature. By measuring displacement correlations between…
Glasses exhibit spatially localized vibrations in the low-frequency regime. These localized modes emerge below the boson peak frequency $\omega_\text{BP}$, and their vibrational densities of state follow $g(\omega) \propto \omega^4$…