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We present a consistent theory of energy balance and conversion in a single-molecule junction with strong interactions between electrons on the molecular linker (dot) and phonons in the nuclear environment where the Marcus-type electron…

Mesoscale and Nanoscale Physics · Physics 2020-01-22 Natalya A. Zimbovskaya , Abraham Nitzan

In the present work we theoretically analyze thermoelectric transport in single-molecule junctions (SMJ) characterized by strong interactions between electrons on the molecular linkers and phonons in their nuclear environments where…

Mesoscale and Nanoscale Physics · Physics 2024-01-17 Natalya A. Zimbovskaya

Charge and heat transport through a single molecule tunnel-coupled to external normal electrodes have been studied. The molecule with sufficiently strong interaction between lectrons and vibrational internal degrees of freedom can be…

Mesoscale and Nanoscale Physics · Physics 2012-04-16 Karol Izydor Wysokinski

The rate of electron transfer between a molecular species and a metal, each at a different local temperature, is examined theoretically through implementation of a bithermal (characterized by two temperatures) Marcus formalism. Expressions…

Mesoscale and Nanoscale Physics · Physics 2019-08-02 Galen T. Craven , Abraham Nitzan

We develop a general theory for thermal transport in anharmonic systems under the weak system-bath coupling approximation similar to the quantum master equation formalism. A current operator is derived, which is valid not only in the steady…

Mesoscale and Nanoscale Physics · Physics 2012-05-28 Juzar Thingna , J. L. García-Palacios , Jian-Sheng Wang

Motivated by recent experiments [Lee et al. Nature 498, 209 (2013)], we present here a detailed theoretical analysis of the Joule heating in current-carrying single-molecule junctions. By combining the Landauer approach for quantum…

While heating of a current carrying Ohmic conductors is an obvious consequence of the diffusive nature of the conduction in such systems, current induced cooling has been recently reported in some molecular conduction junctions. In this…

Mesoscale and Nanoscale Physics · Physics 2009-09-25 Michael Galperin , Keiji Saito , Alexander V. Balatsky , Abraham Nitzan

The thermoelectric transport through a molecular bridge is discussed, with an emphasis on the effects of inelastic processes of the transport electrons caused by the coupling to the vibrational modes of the molecule. In particular it is…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 O. Entin-Wohlman , Y. Imry , A. Aharony

We consider a molecular junction immersed in a solvent where the electron transfer is dominated by Marcus-type steps. However, the successive nature of the charge transfer through the junction does not imply that the solvent reach thermal…

Statistical Mechanics · Physics 2022-03-23 Henning Kirchberg , Abraham Nitzan

This thesis investigates the mechanically controlled break junctions, with a particular emphasis on elucidating the behaviour of molecular currents at room temperature. The core of this experimental investigation involves a detailed…

Mesoscale and Nanoscale Physics · Physics 2024-09-17 Giovanna Angelis Schmidt

Thermodynamic transport phenomena in the system consisting of many hard-disks confined in a circular tube with a temperature difference are discussed. Here, temperatures on parts of the walls of the tube are imposed by stochastic boundary…

Statistical Mechanics · Physics 2018-10-05 Tooru Taniguchi , Colin Bain McRae , Shin-ichi Sawada

Redox molecular junctions are molecular conduction junctions that involve more than one oxidation state of the molecular bridge. This property is derived from the ability of the molecule to transiently localize transmitting electrons,…

Mesoscale and Nanoscale Physics · Physics 2013-06-21 Agostino Migliore , Abraham Nitzan

We present a theoretical study of the heat dissipation in single-molecule junctions. In order to investigate the heat dissipation in the electrodes and the relationship between the transmission spectra and the electronic structures, we…

Mesoscale and Nanoscale Physics · Physics 2016-08-09 Yaghoob Naimi , Javad Vahedi

Metallic atomic junctions pose the ultimate limit to the scaling of electrical contacts. They serve as model systems to probe electrical and thermal transport down to the atomic level as well as quantum effects occurring in one-dimensional…

Mesoscale and Nanoscale Physics · Physics 2017-05-24 Nico Mosso , Ute Drechsler , Fabian Menges , Peter Nirmalraj , Siegfried Karg , Heike Riel , Bernd Gotsmann

We discuss how phase coherence manifests in the heat transport through superconducting single and multichannel Josephson junctions in time dependent situations. We consider the heat current driven through the junction by a temperature…

Superconductivity · Physics 2015-03-02 P. Virtanen , F. Giazotto

In this work we theoretically study properties of electric current driven by a temperature gradient through a quantum dot/molecule coupled to the source and drain charge reservoirs. We analyze the effect of Coulomb interactions between…

Mesoscale and Nanoscale Physics · Physics 2015-12-01 Natalya A. Zimbovskaya

The realization of single-molecule thermal conductance measurements has driven the need for theoretical tools to describe conduction processes that occur over atomistic length scales. In macroscale systems, the principle that is typically…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Galen T. Craven , Abraham Nitzan

We introduce a new class of mesoscopic heat engines consisting of a tunnel junction coupled to a linear thermal bath. Work is produced by transporting electrons up against a voltage bias like in ordinary thermoelectrics but heat is…

Mesoscale and Nanoscale Physics · Physics 2012-08-01 Tomi Ruokola , Teemu Ojanen

Controlling the direction and magnitude of both heat and electronic currents using rectifiers has significant implications for the advancement of molecular circuit design. In order to facilitate the implementation of new transport phenomena…

Mesoscale and Nanoscale Physics · Physics 2019-08-02 Galen T. Craven , Dahai He , Abraham Nitzan

We present an atomistic theory of electronic transport through single organic molecules that reproduces the important features of the current-voltage characteristics observed in recent experiments. We trace these features to their origin in…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Heurich , J. C. Cuevas , W. Wenzel , G. Schoen
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