Related papers: Ab initio methods for polariton chemistry
Polaritons in semiconductor microcavities are hybrid quasiparticles consisting of a superposition of photons and excitons. Due to the photon component, polaritons are characterized by a quantum coherence length in the several micron range.…
Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…
The large number of degrees of freedom involved in polaritonic chemistry processes considerably restricts the systems that can be described by any ab initio approach, due to the resulting high computational cost. Semiclassical methods that…
Photonic materials are an emerging platform to explore quantum matter and quantum dynamics. The development of Rydberg electromagnetically induced transparency provided a clear route to strong interactions between individual optical…
Collective strong coupling between a disordered ensemble of $N$ localized molecular vibrations and a resonant optical cavity mode gives rise to 2 polariton and $N-1\gg2$ dark modes. Thus, experimental changes in thermally-activated reaction…
We formulate a full quantum mechanical theory of the interaction between electromagnetic modes in photonic crystal slabs and quantum well excitons embedded in the photonic structure. We apply the formalism to a high index dielectric layer…
Polaritonic chemistry has garnered increasing attention in recent years due to pioneering experimental results, which show that site- and bond-selective chemistry at room temperature is achievable through strong collective coupling to field…
The prospect of controlling chemical reactivity using frequency-tunable optical microcavities has materialized over the past decade, evolving into a fascinating yet challenging new field of polaritonic chemistry, a multidisciplinary domain…
We review the recent developments of the polariton physics in microcavities featuring the exciton-photon strong coupling at room-temperature, and leading to the achievement of room-temperature polariton condensates. Such cavities embed…
The coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice is studied here in using a perturbation expansion in small atomic displacements. In the Mott insulator case…
Microcavity polaritons are light-matter quasiparticles that arise from the strong coupling between excitons and photons confined in a semiconductor microcavity. They typically operate at visible or near visible wavelengths. They combine the…
Polaritons are a superposition of light and matter, that combine Strong Interferences (of light) with Weak Interactions (of excitons), making them WISI (Weakly-Interacting, Strongly-Interfering) particles. Their condensation is the main…
Understanding the radiative decay of exciton-polaritons is essential for achieving long-lived polaritons - a key prerequisite for enhancing nonlinear and quantum polaritonic effects. However, conventional wisdom - the coupled oscillator…
Quantum dynamics of the photoisomerization of a single 3,3'-diethyl-2,2'-thiacynine iodide molecule embedded in an optical microcavity was theoretically studied. The molecule was coupled to a single cavity mode via the quantum Rabi…
We theoretically demonstrate that chemical reaction rate constant can be significantly suppressed by coupling molecular vibrations with an optical cavity, exhibiting both the collective coupling effect and the cavity-frequency modification…
We investigate the influence of exciton-phonon coupling on the dynamics of a strongly coupled quantum dot-photonic crystal cavity system and explore the effects of this interaction on different schemes for non-classical light generation. By…
We introduce a prototypical model for cavity polaritonic control of ultracold photochemistry by considering the resonant vibrational strong coupling of a rubidium dimer to a terahertz cavity. We demonstrate that at avoided crossings between…
Organic polaritons resulting from the strong hybridisation between photons and matter excitations have arisen as a suitable platform to device light-matter technological interfaces at room temperature. Despite their inherent complexity,…
We have investigated theoretically a dissipative polariton system in the ultrastrong light-matter coupling regime without using the rotating-wave approximation on system-reservoir coupling. Photons in a cavity and excitations in matter…
An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…