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Ultrafast optical excitation of metals induces a non-equilibrium energy distribution in the electronic system, with a characteristic step-structure determined by Pauli blocking. On a femtosecond timescale, electron-electron scattering…

Extreme electron-ion non-equilibrium states, generated by ultrafast laser excitation, lead to melting processes that are fundamentally different from those under conventional thermal equilibrium and remain not fully understood. Through…

Computational Physics · Physics 2025-11-27 Qiyu Zeng , Xiaoxiang Yu , Bo Chen , Shen Zhang , Kaiguo Chen , Dongdong Kang , Jiayu Dai

Electron dynamics in the bulk of large band gap dielectric crystals induced by intense femtosecond laser pulses at 800 nm is studied. With laser intensities under the ablation threshold (a few 10 TW/cm\textsuperscript{2}), electrons with…

The electron dynamics in dielectric materials induced by intense femtosecond laser pulses is theoretically addressed. The laser driven temporal evolution of the energy distribution of electrons in the conduction band is described by a…

Mesoscale and Nanoscale Physics · Physics 2016-11-23 L. Barilleau , G. Duchateau , B. Chimier , G. Geoffroy , V. Tikhonchuk

The femtosecond evolution of the electronic temperature of laser-excited gold nanoparticles is measured, by means of ultrafast time-resolved photoemission spectroscopy induced by extreme-ultraviolet radiation pulses. The temperature of the…

Promising applications in photonics are driven by the ability to fabricate crystal-quality metal thin films of controlled thickness down to a few nanometers. In particular, these materials exhibit a highly nonlinear response to optical…

Mesoscale and Nanoscale Physics · Physics 2023-08-21 A. Rodríguez Echarri , F. Iyikanat , S. Boroviks , N. Asger Mortensen , Joel D. Cox , F. Javier García de Abajo

We investigate the momentum-resolved dynamics of conduction electrons in noble metals following ultrashort optical excitation with linearly polarized light. Using a momentum-resolved Boltzmann equation approach for electron-phonon…

Mesoscale and Nanoscale Physics · Physics 2025-04-29 Jonas Grumm , Andreas Knorr

A semiempirical theory for the excitation and subsequent relaxation of nonthermal electrons is described. The theory, which is applicable to ultrafast-laser excited metals, is based on the Boltzmann transport equation for the carrier…

Materials Science · Physics 2023-07-12 D. M. Riffe , Richard B. Wilson

The simulation of non-equilibrium electron distributions is essential for capturing light-metal interactions and therefore the study of photoabsorption, photocatalysis, laser ablation, and many other phenomena. Current methodologies, such…

Materials Science · Physics 2025-03-13 M. Uehlein , H. T. Snowden , C. Seibel , T. Held , S. T. Weber , R. J. Maurer , B. Rethfeld

Electron-electron thermalization and electron-phonon relaxation processes in laser-excited solids are often assumed to occur on different timescales. This is true for the majority of the conduction band electrons in a metal. However,…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Sebastian T. Weber , Baerbel Rethfeld

We study the relaxation dynamics of laser-excited non-equilibrium electron distributions in the valence- and conduction band of a dielectric. We apply Boltzmann collision integrals to trace the influence of different scattering mechanisms…

Statistical Mechanics · Physics 2023-04-28 Nils Brouwer , Steffen Hirtle , Baerbel Rethfeld

A model calculation is given for the energy relaxation of a non-equilibrium distribution of hot electrons prepared in a metallic sample that has been subjected to homogeneous photo-excitation by a femtosecond laser pulse. The model assumes…

Statistical Mechanics · Physics 2009-11-11 Navinder Singh

The electronic behavior of various solid metals (Al, Ni, Cu, Au, Ti, and W) under ultrashort laser irradiation is investigated by means of density functional theory. Successive stages of extreme nonequilibrium on picosecond time scale…

Materials Science · Physics 2014-04-04 Emile Bévillon , Jean-Philippe Colombier , Vanina Recoules , Razvan Stoian

The structural evolution of laser-excited systems of gold has previously been measured through ultrafast MeV electron diffraction. However, there has been a long-standing inability of atomistic simulations to provide a consistent picture of…

Materials Science · Physics 2024-06-19 J. M. Molina , T. G. White

Efficient excitation and harvesting of hot carriers from nanoscale metals is central to many emerging photochemical, photovoltaic, and ultrafast optoelectronic applications. Yet direct experimental evidence of the relevant femtosecond…

Mesoscale and Nanoscale Physics · Physics 2023-06-13 Jacob Pettine , Paolo Maioli , Fabrice Vallee , Natalia Del Fatti , David J. Nesbitt

The yield of electrons generated by gold nanoparticles due to irradiation by fast charged projectiles is estimated. The results of calculations are compared to those obtained for pure water medium. It is demonstrated that a significant…

Atomic and Molecular Clusters · Physics 2016-10-07 Alexey V. Verkhovtsev , Andrei V. Korol , Andrey V. Solov'yov

We present a theoretical study of the ultrafast electron dynamics in transition metals using ultrashort pulsed laser beams. The significant influence of the contribution of the dynamics of produced nonthermal electrons to electron…

Materials Science · Physics 2016-12-14 George D. Tsibidis

We investigate a temperature-based model, called extended two-temperature model (eTTM), that describes the electronic non-equilibrium and its effect on energy dissipation in metals after ultrashort laser excitation. We derive and discuss…

Materials Science · Physics 2023-08-03 Markus Uehlein , Sebastian T. Weber , Baerbel Rethfeld

Ultrafast relaxation dynamics of an athermal electron distribution is investigated in silver films using a femtosecond pump-probe technique with 18 fs pulses in off-resonant conditions. The results yield evidence for an increase with time…

Strongly Correlated Electrons · Physics 2022-09-29 Natalia Del Fatti , Roland Bouffanais , Fabrice Vallée , Christos Flytzanis

Photoexcited hot carriers in solids can drive processes, such as photocatalytic reactions on the surface, beyond those available in thermal equilibrium. Hot-electron-mediated reaction pathways are limited by the thermalization of the…

Materials Science · Physics 2026-04-13 Christopher Seibel , Tobias Held , Markus Uehlein , Baerbel Rethfeld
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