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Machine learning interatomic potentials (MLIPs) enable efficient modeling of molecular interactions with quantum mechanical (QM) accuracy. However, constructing robust and representative training datasets that capture subtle,…

Chemical Physics · Physics 2026-01-28 Lejia Zeng , Xintong Zhang , Yuchan Pei , Lifeng Zhao , Lan Hua , Jincai Yang , Niu Huang

In the field of machine learning there is a growing interest towards more robust and generalizable algorithms. This is for example important to bridge the gap between the environment in which the training data was collected and the…

Machine Learning · Computer Science 2020-10-08 Wim Casteels , Peter Hellinckx

Properly spin-adapted coupled-cluster theory for general open-shell configurations remains an active area of research in electronic structure theory. In this contribution we examine Lindgren's normal-ordered exponential ansatz to correlate…

Chemical Physics · Physics 2024-10-02 Alexander Gunasekera , Nicholas Lee , David P. Tew

We present a measurement-cost efficient implementation of Strongly-Contracted $N$-Electron Valence Perturbation Theory (SC-NEVPT2) for use on near-term quantum devices. At the heart of our algorithm we exploit the properties of adaptive…

Quantum Physics · Physics 2024-05-27 Aaron Fitzpatrick , N. Walter Talarico , Roberto Di Remigio Eikås , Stefan Knecht

We propose a general approach to reducing basis set incompleteness error in electron correlation energy calculations. The correction is computed alongside the correlation energy in a single calculation by modifying the electron interaction…

Representing a strongly interacting multi-particle wave function in a finite product basis leads to errors. Simple rescaling of the contact interaction can preserve the low-lying energy spectrum and long-wavelength structure of wave…

Quantum Gases · Physics 2011-08-23 Thomas Ernst , David W. Hallwood , Jake Gulliksen , Hans-Dieter Meyer , Joachim Brand

Adiabatic connection models (ACMs), which interpolate between the limits of weak and strong interaction, are powerful tools to build accurate exchange-correlation functionals. If the exact weak-interaction expansion from second-order…

Chemical Physics · Physics 2022-09-08 S. Śmiga , F. Della Sala , P. Gori-Giorgi , E. Fabiano

We develop a cubic scaling approach to excited-state-specific second order perturbation theory in which the completeness of a local correlation treatment is carefully matched between the ground and excited state. With this matching, the…

Chemical Physics · Physics 2025-05-14 Rachel Clune , Eric Neuscamman

A multiconfigurational adiabatic connection (AC) formalism is an attractive approach to computing dynamic correlation within CASSCF and DMRG models. Practical realizations of AC have been based on two approximations: i) fixing one- and…

Chemical Physics · Physics 2023-02-15 Mikuláš Matoušek , Michał Hapka , Libor Veis , Katarzyna Pernal

We present a quantum linear response (qLR) approach within an active-space framework for computing indirect nuclear spin-spin coupling constants, a key ingredient in NMR spectra predictions. The method employs the unitary coupled cluster…

An externally corrected coupled cluster (CC) method, where an adaptive configuration interaction (ACI) wave function provides the external cluster amplitudes, named ACI-CC, is presented. By exploiting the connection between configuration…

Chemical Physics · Physics 2023-09-27 Gustavo J. R. Aroeira , Madeline M. Davis , Justin M. Turney , Henry F. Schaefer

We measure multi-time correlation functions of a set of Pauli operators on a two-level system, which can be used to retrieve its associated linear response functions. The two-level system is an effective spin constructed from the nuclear…

Quantum Physics · Physics 2017-10-30 Tao Xin , Julen S. Pedernales , Lucas Lamata , Enrique Solano , Gui-Lu Long

In a reaction to excite the resonant state followed by the sequential cluster-decay, the in-plane angular correlation method is usually applied to determine the spin of the mother nucleus. However, the correlation pattern exhibited in a…

Data Analysis, Statistics and Probability · Physics 2019-09-04 Biao Yang , Yan-Lin Ye , Jian-Ling Lou , Xiao-Fei Yang , Jing-Jing Li , Yang Liu , Wei Liu , HanZhou Yu

An improved unified formulation based on the effective field theory is introduced for a spin-1 Ising model with nearest neighbor interactions with arbitrary coordination number z. Present formulation is capable of calculating all the…

Statistical Mechanics · Physics 2016-08-14 Ümit Akıncı

High accuracy Monte Carlo simulation results for 1024*1024 Ising system with ferromagnetic impurity bonds are presented. Spin-spin correlation function at a critical point is found to be numerically very close to that of a pure system. This…

Condensed Matter · Physics 2007-05-23 Andrei Talapov , Vladimir Dotsenko

We apply a unified machine-learning framework based on Normalizing Flows (NFs) for the event-by-event reconstruction of invisible momenta and the subsequent evaluation of spin-sensitive observables in top-quark pair and dark-matter (DM)…

High Energy Physics - Phenomenology · Physics 2025-10-14 E. Abasov , L. Dudko , E. Iudin , A. Markina , P. Volkov , G. Vorotnikov , M. Perfilov , A. Zaborenko

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

By means of hybrid multi-particle collsion--particle-in-cell (MPC-PIC) simulations we study the dynamical scaling of energy and density correlations at equilibrium in moderately coupled 2D and quasi 1D plasmas. We find that the predictions…

Plasma Physics · Physics 2017-04-17 Pierfrancesco Di Cintio , Roberto Livi , Stefano Lepri , Guido Ciraolo

The self-consistent random phase approximation (RPA) based on a correlated realistic nucleon-nucleon interaction is used to evaluate correlation energies in closed-shell nuclei beyond the Hartree-Fock level. The relevance of contributions…

Nuclear Theory · Physics 2007-05-23 C. Barbieri , N. Paar , R. Roth , P. Papakonstantinou

The higher spin interaction currents for the conformally coupled scalar in $AdS_{4}$ space for both regular and irregular boundary condition corresponding to the free and interacting critical point of the boundary O(N) sigma model are…

High Energy Physics - Theory · Physics 2009-11-10 R. Manvelyan , W. Ruehl