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Recent advances in laser technology enable to follow electronic motion at its natural time-scale with ultrafast pulses, leading the way towards atto- and femtosecond spectroscopic experiments of unprecedented resolution. Understanding of…

Chemical Physics · Physics 2023-07-12 Marius Kadek , Lukas Konecny , Michal Repisky

In the presence of a (time-dependent) macroscopic electric field the electron dynamics of dielectrics cannot be described by the time-dependent density only. We present a real-time formalism that has the density and the macroscopic…

Materials Science · Physics 2016-07-27 M. Grüning , D. Sangalli , C. Attaccalite

The temporal evolution of electromagnetically induced transparency (EIT) and absorption (EIA) coherence resonances in pump-probe spectroscopy of degenerate two-level atomic transition is studied for light intensities below saturation.…

Quantum Physics · Physics 2009-11-07 P. Valente , H. Failache , A. Lezama

Within the framework of ab initio time-dependent density-functional theory (TD-DFT), we propose a static approximation to the exchange-correlation kernel based on the jellium-with-gap model. This kernel accounts for electron-hole…

Shaped laser pulses are a powerful tool to induce population transfer between electronic molecular states, and time-dependent perturbation theory is suitable for a description of such a transfer in weak external fields. The application of…

Mathematical Physics · Physics 2012-05-24 Klaus Renziehausen

Electron energy loss spectroscopy is consolidating as a powerful tool to explore electronic (as well as vibrational) excitations of matter, including molecules. Performed in a scanning transmission electron microscope, this technique is…

Chemical Physics · Physics 2021-03-05 Ciro A. Guido , Enzo Rotunno , Matteo Zanfrognini , Stefano Corni , Vincenzo Grillo

We present a novel semiclassical phase-space surface hopping approach that goes beyond the Born-Oppenheimer approximation and all existing surface hopping formalisms. We demonstrate that working with a correct phase-space electronic…

Chemical Physics · Physics 2024-10-03 Xuezhi Bian , Yanze Wu , Tian Qiu , Tao Zhen , Joseph E. Subotnik

We present ab initio absorption spectra of six three-dimensional semiconductors and insulators calculated using Gaussian-based periodic equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). The spectra are…

Chemical Physics · Physics 2021-07-13 Xiao Wang , Timothy C. Berkelbach

In this paper, we present a theoretical simulation of 87Rb absorption spectrum in a thermal cm-cell which is adaptive to the experimental observation. In experiment, the coupling and probe beams are configured to copropagate but…

Atomic Physics · Physics 2017-03-09 Hong Cheng , Shan-Shan Zhang , Pei-Pei Xin , Yuan Cheng , Hong-Ping Liu

Spectroscopies that probe electronic excitations from core levels into unoccupied orbitals, such as X-ray absorption spectroscopy and electron energy loss spectroscopy, are widely used to gain insight into the electronic and chemical…

Materials Science · Physics 2022-09-12 Marcus Annegarn , Juhan Matthias Kahk , Johannes Lischner

We present a combined imaginary-time/real-time time-dependent (TD) approach for evaluating linear absorption spectra of open-shell systems at the electron attachment (EA) and ionization potential (IP) equation-of-motion coupled-cluster…

Chemical Physics · Physics 2026-05-05 P. D. Varuna S. Pathirage , Stephen H. Yuwono , Xiaosong Li , A. Eugene DePrince

In this contribution we present calculations performed for interacting electron systems within a non-perturbative formulation of the cluster theory. Extrapolation of the model to describe the time dependence of the interacting systems is…

Atomic Physics · Physics 2009-11-13 M. Tomaselli , T. Kuehl , D. Ursescu , S. Fritzsche

We demonstrate a two-dimensional time-domain spectroscopy method to extract amplitude and phase modifications of excited atomic states caused by the interaction with ultrashort laser pulses. The technique is based on Fourier analysis of the…

Atomic Physics · Physics 2015-06-19 Alexander Blättermann , Christian Ott , Andreas Kaldun , Thomas Ding , Thomas Pfeifer

Time-domain sampling of arbitrary electric fields with sub-cycle resolution enables a complete time-frequency analysis of a system's response to electromagnetic illumination. This provides access to dynamic information that is not provided…

Owing to its numerical simplicity, a two-dimensional two-electron model atom, with each electron moving in one direction, is an ideal system to study non-perturbatively a fully correlated atom exposed to a laser field. Frequently made…

Atomic Physics · Physics 2009-10-30 D. Bauer

A semi-classical approach is used to calculate radiation emission in the collision of an electron with an intense focused laser pulse. The results are compared to predictions from the locally constant field and locally monochromatic…

Plasma Physics · Physics 2022-08-17 Christian F. Nielsen , Robert Holtzapple , Ben King

We theoretically investigate an electron transfer (ET) process in a dissipative environment by means of two-dimensional (2D) correlation spectroscopy. We extend the reduced hierarchy equations of motion approach to include both overdamped…

Chemical Physics · Physics 2013-10-29 Yoshitaka Tanimura

In the present work, a new time-dependent exchange theory is presented wherein the symmetry constraints, on a multi-electron wavefunction, are properly accounted for. In so doing, the equations of motion, incorporating the required…

Computational Physics · Physics 2007-05-23 Charles A. Weatherford

The influence of the quadrupole shape fluctuations on the dipole vibrations in transitional nuclei is investigated in the framework of the Instantaneous Shape Sampling Model, which combines the Interacting Boson Model for the slow…

Nuclear Theory · Physics 2011-03-02 I. Bentley , S. Brant , F. Doenau , S. Frauendorf , B. Kampfer , R. Schwengner , S. Zhang

The nonlinear Breit-Wheeler process is studied in the presence of strong and short laser pulses. We show that for a relativistically intense plane-wave laser field many features of the momentum distribution of the produced electron-positron…

High Energy Physics - Phenomenology · Physics 2016-04-25 Sebastian Meuren , Christoph H. Keitel , Antonino Di Piazza