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Battery degradation, which is the reduction of performance over time, is one of the main roadblocks to the wide deployment of lithium-ion batteries. Physics-based models, such as those based on the Doyle-Fuller-Newman model, are invaluable…

Chemical Physics · Physics 2023-06-06 Ferran Brosa Planella , W. Dhammika Widanage

The electrical double layer (EDL) is fundamental to the operation of devices for electrochemical energy storage and conversion. Existing models of EDL in solid electrolytes focus predominantly on the space charge layer and lack a complete…

Materials Science · Physics 2025-08-12 Zeeshan Ahmad

We introduce a novel three-dimensional (3D) traction force microscopy (TFM) method motivated by the recent discovery that cells adhering on plane surfaces exert both in-plane and out-of-plane traction stresses. We measure the 3D deformation…

We introduce a theoretical and numerical method to investigate the flow of charged fluid mixtures under extreme confinement. We model the electrolyte solution as a ternary mixture, comprising two ionic species of opposite charge and a third…

Mesoscale and Nanoscale Physics · Physics 2012-09-13 Umberto Marini Bettolo Marconi , Simone Melchionna

Accurate estimation of the internal states of lithium-ion batteries is key towards improving their management for safety, efficiency and longevity purposes. Various approaches exist in the literature in this context, among which designing…

Systems and Control · Electrical Eng. & Systems 2023-08-21 Mira Khalil , Romain Postoyan , Stéphane Raël

A novel mathematical model for fiber-reinforced materials is proposed. It is based on a 1-dimensional beam model for the thin fiber structures, a flexible and general 3-dimensional elasticity model for the matrix and an overlapping domain…

Computational Engineering, Finance, and Science · Computer Science 2021-05-12 Ustim Khristenko , Stefan Schuß , Melanie Krüger , Felix Schmidt , Barbara Wohlmuth , Christian Hesch

The surface coating of cathodes using insulator films has proven to be a promising method for high-voltage cathode stabilization in Li-ion batteries. However, there is still substantial uncertainty about how these films function,…

The unified 3D phase-field model for the description of the lithium-ion cell as a whole is developed. The model takes into account the realistic distribution of particles in porous electrodes, percolative transport of ions, and the…

Disordered Systems and Neural Networks · Physics 2021-05-11 Pavel E. L'vov , Mikhail Yu. Tikhonchev , Renat T. Sibatov

In this work, a two-dimensional time-fractional subdiffusion model is developed to investigate the underlying transport phenomena evolving in a binary medium comprised of two sub-domains occupied by homogeneous material. We utilise an…

Numerical Analysis · Mathematics 2021-02-05 Libo Feng , Ian Turner , Patrick Perre , Kevin Burrage

A nonlinear phase-field model is developed to simulate corrosion damage. The motion of the electrode$-$ electrolyte interface follows the usual kinetic rate theory for chemical reactions based on the Butler-Volmer equation. The model links…

Chemical Physics · Physics 2024-08-28 M. Makuch , S. Kovacevic , M. R. Wenman , E. Martínez-Pañeda

In Part I of this two part series, we presented a multi-neighbor dependent contact model for adhesive elastic-plastic particles built upon the method of dimensionality reduction that is valid for the elastic and fully-plastic contact…

Soft Condensed Matter · Physics 2023-09-15 William Zunker , Ken Kamrin

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

Materials Science · Physics 2020-05-05 Fan Wang , Ming Tang

In order to achieve a better understanding of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale is an important focus of current mathematical research. These models lead to…

Numerical Analysis · Mathematics 2018-03-09 Mario Ohlberger , Stephan Rave , Sebastian Schmidt , Shiquan Zhang

Thermal electrochemical models for porous electrode batteries (such as lithium ion batteries) are widely used. Due to the multiple scales involved, solving the model accounting for the porous microstructure is computationally expensive,…

Chemical Physics · Physics 2020-04-14 Matthew J. Hunt , Ferran Brosa Planella , Florian Theil , W. Dhammika Widanage

Liquid metal batteries (LMBs) are a promising grid-scale storage device however, the scalability of this technology and its electrochemical performance is limited by mass transport overpotentials. In this work, a numerical model of a…

Fluid Dynamics · Physics 2024-10-15 Declan Finn Keogh , Mark Baldry , Victoria Timchenko , John Reizes , Chris Menictas

A two-dimensional small bias model has been developed for a patterned metal current collector $|$ mixed oxygen ion and electronic conductor (MIEC) $|$ patterned metal current collector electrochemical cell in a symmetric gas environment.…

Chemical Physics · Physics 2009-03-20 Francesco Ciucci , William C. Chueh , Sossina M. Haile , David G. Goodwin

We present an efficient method for computing the zero frequency limit of transport coefficients in strongly coupled field theories described holographically by higher derivative gravity theories. Hydrodynamic parameters such as shear…

High Energy Physics - Theory · Physics 2010-02-23 Miguel F. Paulos

The prediction of battery rate performance traditionally relies on computation-intensive numerical simulations. While simplified analytical models have been developed to accelerate the calculation, they usually assume battery performance to…

Materials Science · Physics 2024-04-09 Hongxuan Wang , Fan Wang , Ming Tang

Two-scale models pose a promising approach in simulating reactive flow and transport in evolving porous media. Classically, homogenized flow and transport equations are solved on the macroscopic scale, while effective parameters are…

Analysis of PDEs · Mathematics 2022-02-01 Stephan Gärttner , Peter Knabner , Nadja Ray

Two-dimensional (2D) van der Waals semiconductors represent the thinnest, air stable semiconducting materials known. Their unique optical, electronic and mechanical properties hold great potential for harnessing them as key components in…

Mesoscale and Nanoscale Physics · Physics 2016-02-10 Song-Lin Li , Kazihito Tsukagoshi , Emanuele Orgiu , Paolo Samorì