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Related papers: Nonequilibrium interfacial properties of chemicall…

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We study chemical pattern formation in a fluid between two flat plates and the effect of such patterns on the formation of convective cells. This patterning is made possible by assuming the plates are chemically reactive or release reagents…

Fluid Dynamics · Physics 2023-11-07 Aiden Huffman , Henry Shum

Non-equilibrium phase coexistence is commonly observed in both biological and artificial systems, yet understanding it remains a significant challenge. Unlike equilibrium systems, where free energy provides a unifying framework, the absence…

Soft Condensed Matter · Physics 2025-07-09 R. Maire , A. Plati , F. Smallenburg , G. Foffi

Condensation of fluctuations is an interesting phenomenon conceptually distinct from condensation on average. One stricking feature is that, contrary to what happens on average, condensation of fluctuations may occurr even in the absence of…

Statistical Mechanics · Physics 2014-07-31 Marco Zannetti , Federico Corberi , Giuseppe Gonnella

Chemical affinities are responsible for driving active matter systems out of equilibrium. At the nano-scale, molecular machines interact with the surrounding environment and are subjected to external forces. The mechano-chemical coupling…

Soft Condensed Matter · Physics 2025-01-03 Michalis Chatzittofi , Jaime Agudo-Canalejo , Ramin Golestanian

A three-dimensional, volume-of-fluid (VOF) based CFD model is presented to investigate droplet formation in a microfluidic T-junction. Genesis of Newtonian droplets in non-Newtonian liquid is numerically studied and characterized in three…

Fluid Dynamics · Physics 2025-10-09 Somasekhara Goud Sontti , Arnab Atta

Recent experiments and simulations have demonstrated that particle-covered interfaces can exist in stable non-spherical shapes as a result of the steric jamming of the interfacially trapped particles, which confers the interface with…

Soft Condensed Matter · Physics 2010-11-23 Anand Bala Subramaniam , Manouk Abkarian , L. Mahadevan , Howard A. Stone

At equilibrium, a fluid element, within a larger heat bath, receives random impulses from the bath. Those impulses, which induce stochastic transitions in the system (the fluid element), respect the principle of detailed balance, because…

Statistical Mechanics · Physics 2009-11-13 Aditi Simha , R. M. L. Evans , A. Baule

The evolution of the interface separating a conduit of light, viscous fluid rising buoyantly through a heavy, more viscous, exterior fluid at small Reynolds numbers is governed by the interplay between nonlinearity and dispersion. Previous…

Fluid Dynamics · Physics 2015-06-16 Nicholas K. Lowman , Mark A. Hoefer

We study whether the stationary state of two bulk-driven systems slowly exchanging particles can be described by the equality of suitably defined nonequilibrium chemical potentials. Our main result is that in a weak contact limit, chemical…

Statistical Mechanics · Physics 2018-08-29 Jules Guioth , Éric Bertin

A wide variety of reactions are reported to be dramatically accelerated in aqueous microdroplets, making them a promising platform for environmentally clean chemical synthesis. However to fully utilize the microdroplets for accelerating…

Chemical Physics · Physics 2024-11-05 R. Allen LaCour , Joseph P. Heindel , Ruoqi Zhao , Teresa Head-Gordon

We analyze within mean-field theory as well as numerically a KPZ equation that describes nonequilibrium wetting. Both complete and critical wettitng transitions were found and characterized in detail. For one-dimensional substrates the…

Statistical Mechanics · Physics 2009-11-10 F. de los Santos , M. M. Telo da Gama , M. A. Munoz

Spontaneous emulsification, resulting from the assembly and accumulation of surfactants at liquid-liquid interfaces, is an interfacial instability where microdroplets are generated and diffusively spread from the interface until complete…

Phase separation dynamics with an initially non-uniform concentration are studied. Critical and off-critical behavior is observed simultaneously. A mechanism for an expanding phase separated region is demonstrated and the time dependence of…

Condensed Matter · Physics 2009-10-22 A. M. Lacasta , J. M. Sancho , Chuck Yeung

Motivated by recent experiments, the isotropic-nematic phase transition in chromonic liquid crystals is studied. As temperature decreases, nematic nuclei nucleate, grow, and coalesce, giving rise to tactoid microstructures in an isotropic…

Soft Condensed Matter · Physics 2017-08-25 Chiqun Zhang , Amit Acharya , Noel J. Walkington , Oleg D. Lavrentovich

Microfluidic devices can be used to produce highly controlled and monodisperse double or multiple emulsions. The presence of inner drops inside a jet of the middle phase introduces deformations in the jet, which leads to breakup into…

In continuum thermodynamics, models of two-phase mixtures typically obey the condition of pressure equilibrium across interfaces between the phases. We propose a new non-equilibrium model beyond that condition, allowing for microinertia of…

Fluid Dynamics · Physics 2023-12-18 Ilya Peshkov , Evgeniy Romenski , Michal Pavelka

A recently introduced particle-based model for fluid dynamics with continuous velocities is generalized to model fluids with excluded volume effects. This is achieved through the use of biased stochastic multi-particle collisions which…

Soft Condensed Matter · Physics 2007-05-23 Erkan Tuzel , Thomas Ihle , Daniel M. Kroll

Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent…

Chemical Physics · Physics 2019-09-11 Emanuele Penocchio , Riccardo Rao , Massimiliano Esposito

Liquid-liquid phase separation of liquids exhibiting interconversion between alternative states has been proposed as an underlying mechanism for fluid polyamorphism, and may be of relevance to protein function and intracellular…

Statistical Mechanics · Physics 2021-12-08 Betul Uralcan , Thomas J. Longo , Mikhail A. Anisimov , Frank H. Stillinger , Pablo G. Debenedetti

In studies of interfaces with dynamic chemical composition, bulk and interfacial quantities coupled via surface conservation laws of excess surface quantities. While this approach is for microscopically sharp interfaces, its applicability…

Chemical Physics · Physics 2007-05-23 Kevin T. Chu , Martin Z. Bazant