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Relaxor ferroelectrics, which can exhibit exceptional electromechanical coupling are some of the most important functional materials with applications ranging from ultrasound imaging to actuators and sensors in microelectromechanical…

Introducing structural and/or chemical heterogeneity into otherwise ordered crystals can dramatically alter material properties. Lead-based relaxor ferroelectrics are a prototypical example, with decades of investigation having connected…

Local inhomogeneities known as polar nanoregions (PNR) play a key role in governing the dielectric properties of relaxor ferroelectrics - a special class of material that exhibits an enormous electromechanical response and is easily…

Materials Science · Physics 2009-11-13 Guangyong Xu , Jinsheng Wen , C. Stock , P. M. Gehring

Relaxor ferroelectrics exhibit exceptional dielectric and electromechanical properties, yet their microscopic origins remain elusive due to the interplay of hierarchical polar structures and chemical complexity. While models based on polar…

Materials Science · Physics 2025-09-03 Yuan-Jinsheng Liu , Tyler C. Sterling , Shi Liu

\indent It is a generally accepted fact that the unique dielectric properties of relaxor ferroelectrics are related to the formation of polar nanoregion (PNRs). Less well recognized is the corollary that, because they are polar and…

Mesoscale and Nanoscale Physics · Physics 2018-10-31 Ling Cai , Radha Pattnaik , Joel Lundeen , Jean Toulouse

Relaxor ferroelectrics are applied in electronic devices such as actuators and sonars. Morphotrophic phase boundaries (MPBs) with monoclinic structures are known for their high piezoelectricity and electromechanical coupling factors in…

Ferroelectrics form domain patterns that minimize their energy subject to imposed boundary conditions. In a linear, constrained theory, that neglects domain wall energy, periodic domain patterns in the form of multi-rank laminates can be…

Materials Science · Physics 2018-03-20 Ananya Renuka Balakrishna , John E. Huber , Ingo Münch

The polarization and strain response of ferroelectric materials at fields below the macroscopic coercive field is of a paramount importance for the operation of many electronic devices. The response of real ferroelectric and related…

Materials Science · Physics 2021-06-08 Lukas M. Riemer , Li Jin , Hana Uršič , Mojca Otonicar , Tadej Rojac , Dragan Damjanovic

Polar skyrmions in ferroelectric superlattices are nanoscale topological polarization textures typically regarded as weakly coupled objects confined to individual layers, with a role secondary to that of the underlying symmetry-breaking…

Materials Science · Physics 2026-04-30 Zhiyang Wang , Fei Yang , Long-Qing Chen

Relaxor ferroelectrics are complex oxide materials which are rather unique to study the effects of compositional disorder on phase transitions. Here, we study the effects of quenched cubic random electric fields on the lattice instabilities…

Materials Science · Physics 2017-06-14 J. R. Arce-Gamboa , G. G. Guzmán-Verri

Combining our comprehensive investigations of polarization evolution, soft-mode by Raman scattering and microstructure by TEM, and the results reported in the literatures, we show that prototypical relaxor Pb(Mg1/3Nb2/3)O3 (PMN) is…

Materials Science · Physics 2013-01-17 Desheng Fu , Hiroki Taniguchi , Mitsuru Itoh , Shigeo Mori

Neutron and x-ray scattering studies on relaxor ferroelectric systems Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN), Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_3$ (PMN), and their solid solutions with PbTiO$_3$ (PT) have shown that inhomogeneities and disorder play…

Materials Science · Physics 2015-05-13 Guangyong Xu

Relaxor ferroelectrics are complex materials with distinct properties different from classic ferroelectrics. Probing frequency depended dielectric susceptibility is its trait. Other empirical laws build on classic ferroelectrics are still…

Materials Science · Physics 2022-09-07 Shiyi Zhang , Dongyan Zhang , Zhimin Li , Pangpang Wang , Ri-ichi Murakami

We have formulated a relaxation mechanism for ferrites and ferromagnetic metals whereby the coupling between the magnetic motion and lattice is based purely on continuum arguments concerning magnetostriction. This theoretical approach…

Materials Science · Physics 2015-05-13 C. Vittoria , S. D. Yoon , A. Widom

Short-range polar orders in the relaxor ferroelectric material PbMg$_{1/3}$Nb$_{2/3}$O$_3$-$28\%$PbTiO$_3$ (PMN-28PT) have been studied using neutron diffuse scattering. An external electric field along [110] direction can affect the…

Materials Science · Physics 2019-08-07 Zhijun Xu , Fei Li , Shujun Zhang , Christopher Stock , Jun Luo , Peter M. Gehring , Guangyong Xu

We propose a simple phenomenological picture to explain the unusual dielectric properties of the proto-typical ferroelectric relaxor lead magnesium niobate-titanate (PMN-PT). Our model assumes a specific, slowly changing, displacement…

Materials Science · Physics 2011-01-11 A. Bosak , D. Chernyshov , S. Vakhrushev , M. Krisch

Ferroelectric nematic (NF) liquid crystals combine liquid-like fluidity and orientational order of conventional nematics with macroscopic electric polarization comparable in magnitude to solid state ferroelectric materials. Here, we present…

Soft Condensed Matter · Physics 2025-02-04 Calum J. Gibb , Jordan Hobbs , Richard J. Mandle

Spatial variability of polarization relaxation kinetics in relaxor ferroelectric 0.9Pb(Mg1/3Nb2/3)O3-0.1PbTiO3 is studied using time-resolved Piezoresponse Force Microscopy. Local relaxation attributed to the reorientation of polar…

Materials Science · Physics 2013-05-29 S. V. Kalinin , B. J. Rodriguez , J. D. Budai , S. Jesse , A. N. Morozovska , A. A. Bokov , Z. -G. Ye

A complete understanding of the mechanisms for dielectric relaxation in relaxor ferroelectrics remains elusive. We used a structural refinement framework that integrates several types of experimental data to identify the nanoscale…

Heterostructured material systems devoid of ferroic components are presumed not to display ordering associated with ferroelectricity. In heterostructures composed of transition metal oxides, however, the disruption introduced by an…

Strongly Correlated Electrons · Physics 2012-09-25 K. Rogdakis , J. W. Seo , Z. Viskadourakis , Y. Wang , L. F. N. Ah Qune , E. Choi , J. D. Burton , E. Y. Tsymbal , J. Lee , C. Panagopoulos
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