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Understanding the reactivity and spectroscopy of aqueous solutions at the atomistic level is crucial for the elucidation and design of chemical processes. However, the simulation of these systems requires addressing the formidable…

Chemical Physics · Physics 2017-02-28 Ondrej Marsalek , Thomas E. Markland

A new approximate solution to the quantum-classical Liouville equation is derived starting from the formal solution of this equation in forward-backward form. The time evolution of a mixed quantum-classical system described by this equation…

Chemical Physics · Physics 2015-06-05 Chang-Yu Hsieh , Raymond Kapral

A multiscale theory of interacting continuum mechanics and thermodynamics of mixtures of fluids, electrodynamics, polarization and magnetization is proposed. The mechanical (reversible) part of the theory is constructed in a purely…

Classical Physics · Physics 2020-08-26 Petr Vagner , Michal Pavelka , Ogul Esen

We present a general approach to the classical dynamical systems simulation. This approach is based on classical systems extension to quantum states. The proposed theory can be applied to analysis of multiple (including non-Hamiltonian)…

Chaotic Dynamics · Physics 2019-06-18 Yu. I. Bogdanov , N. A. Bogdanova , D. V. Fastovets , V. F. Lukichev

We report the quantum computing of reacting flows by simulating the Hamiltonian dynamics. The scalar transport equation for reacting flows is transformed into a Hamiltonian system, mapping the dissipative and non-Hermitian problem in…

Fluid Dynamics · Physics 2024-07-30 Zhen Lu , Yue Yang

We propose mixed quantum-classical equations of motion that unify electronic coherence and phase evolution simultaneously within the exact factorization framework. Our derivation shows that incorporating the second-order electron-nuclear…

Chemical Physics · Physics 2026-03-03 Jong-Kwon Ha , Seong Ho Kim , Seung Kyu Min

We present a new approach to calculate real-time quantum dynamics in complex systems. The formalism is based on the partitioning of a system's environment into "core" and "reservoir" modes, with the former to be treated quantum mechanically…

Statistical Mechanics · Physics 2015-05-30 Timothy C. Berkelbach , David R. Reichman , Thomas E. Markland

Over the past decade the study of fluidic droplets bouncing and skipping (or ``walking'') on a vibrating fluid bath has gone from an interesting experiment to a vibrant research field. The field exhibits challenging fluids problems,…

Fluid Dynamics · Physics 2020-11-18 Aminur Rahman , Denis Blackmore

A novel dielectric scheme is proposed for strongly coupled electron liquids that handles quantum mechanical effects beyond the random phase approximation level and treats electronic correlations within the integral equation theory of…

Statistical Mechanics · Physics 2023-04-12 Panagiotis Tolias , Federico Lucco Castello , Tobias Dornheim

The increasing growth of data volume, and the consequent explosion in demand for computational power, are affecting scientific computing, as shown by the rise of extreme data scientific workflows. As the need for computing power increases,…

Emerging Technologies · Computer Science 2024-04-17 Sandeep Suresh Cranganore , Vincenzo De Maio , Ivona Brandic , Ewa Deelman

A formulation of quantum-classical hybrid dynamics is presented, which concerns the direct coupling of classical and quantum mechanical degrees of freedom. It is of interest for applications in quantum mechanical approximation schemes and…

Quantum Physics · Physics 2012-05-15 Hans-Thomas Elze

We describe recent developments in the hybrid atomistic/continuum modelling of dense fluids. We discuss the general implementation of mass, momentum and energy transfers between a region described by molecular dynamics and the neighbouring…

Computational Physics · Physics 2007-05-23 R. Delgado-Buscalioni , P. V. Coveney

We prove the existence of global in time, finite energy, weak solutions to a quantum magnetohydrodynamic system (QMHD) with large data, modeling a charged quantum fluid interacting with a self-generated electromagnetic field. The analysis…

Analysis of PDEs · Mathematics 2022-05-16 Paolo Antonelli , Pierangelo Marcati , Raffaele Scandone

Transition metal complexes for photochemical applications often feature a high density of electron-vibrational states characterized by nonadiabatic and spin-orbit couplings. Overall, the dynamics after photoexcitation is shaped by rapid…

Chemical Physics · Physics 2023-05-16 Olga Bokareva , Oliver Kühn

We describe here a model for inelastic collisions for electronic excitation and deexcitation processes in a general, multifluid plasma. The model is derived from kinetic theory, and applicable to any mixture and mass ratio. The principle of…

Plasma Physics · Physics 2015-10-08 H. P. Le , J. -L. Cambier

It has recently been shown that relativistic quantum theory leads to a local interpretation of quantum mechanics wherein the universal wavefunction in configuration space is entirely replaced with an ensemble of local fluid equations in…

Quantum Physics · Physics 2024-03-27 Mordecai Waegell

We develop a general kinetic theory framework to describe the hydrodynamics of strongly interacting, nonequilibrium quantum systems in which integrability is weakly broken, leaving a few residual conserved quantities. This framework is…

Statistical Mechanics · Physics 2021-03-03 Javier Lopez-Piqueres , Brayden Ware , Sarang Gopalakrishnan , Romain Vasseur

Very recently [Phys. Rev. E 82, 021921 (2010)] a simple mechanism was presented by which a molecule subjected to forced oscillations, out of thermal equilibrium, can maintain quantum entanglement between two of its quantum degrees of…

Quantum Physics · Physics 2012-07-16 Gian Giacomo Guerreschi , Jianming Cai , Sandu Popescu , Hans J. Briegel

Multiphase systems are ubiquitous in engineering, biology, and materials science, where understanding their complex interactions and rheological behavior is crucial for advancing applications ranging from emulsion stability to cellular…

Fluid Dynamics · Physics 2025-10-27 Andres Santiago Espinosa-Moreno , Nicolas Moreno , Marco Ellero

Molecular dynamics simulations are indispensable for exploring the behavior of atoms and molecules. Grounded in quantum mechanical principles, quantum molecular dynamics provides high predictive power but its computational cost is dominated…

Chemical Physics · Physics 2025-09-10 Siu Wun Cheung , Youngsoo Choi , Jean-Luc Fattebert , Daniel Osei-Kuffuor