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We present an approach for carrying out non-adiabatic molecular dynamics simulations of systems in which non-adiabatic transitions arise from the coupling between the classical atomic motions and a quasi-continuum of electronic quantum…

Computational Physics · Physics 2018-11-21 Jerome Daligault , Dmitry Mozyrsky

The dynamics of a wide range of technologically important quantum systems are dominated by their interaction with just a few environmental modes. Such highly structured environments give rise to long-lived bath correlations that induce…

We present an overview of the role of quantum coherence in influencing nonadiabatic processes in the condensed phase. Equations of motion for mixed quantum-classical dynamics are derived from the Consistent Histories interpretation of…

Chemical Physics · Physics 2008-02-03 Eric R. Bittner

Interacting spin-boson models encompass a large class of physical systems, spanning models with a single spin interacting with a bosonic bath -- a paradigm of quantum impurity problems -- to models with many spins interacting with a cavity…

Quantum Physics · Physics 2023-09-22 Naushad A. Kamar , Mohammad Maghrebi

Based on the Koopman-van Hove (KvH) formulation of classical mechanics introduced in Part I, we formulate a Hamiltonian model for hybrid quantum-classical systems. This is obtained by writing the KvH wave equation for two classical…

Mathematical Physics · Physics 2021-07-05 Cesare Tronci , François Gay-Balmaz

Quasiclassical methods for non-adiabatic quantum dynamics can reveal new features of quantum effects, such as tunneling evolution, that are harder to reveal in standard treatments based on wave functions of stationary states. Here, these…

General Relativity and Quantum Cosmology · Physics 2022-05-06 Martin Bojowald , Pip Petersen

We consider the interaction dynamics of a classical oscillator and a quantum two-level system for different pure-dephasing Hamiltonians of the type $\widehat{H}(q,p)=H_C(q,p)\boldsymbol{1}+H_I(q,p)\widehat\sigma_z$. This type of systems…

Chemical Physics · Physics 2023-03-15 Giovanni Manfredi , Antoine Rittaud , Cesare Tronci

Quantum computers have the potential to simulate chemical systems beyond the capability of classical computers. Recent developments in hybrid quantum-classical approaches enable the determinations of the ground or low energy states of…

Quantum Physics · Physics 2021-12-06 Chee-Kong Lee , Jonathan Wei Zhong Lau , Liang Shi , Leong Chuan Kwek

We have conducted a triple-scale simulation of liquid water by concurrently coupling atomistic, mesoscopic, and continuum models of the liquid. The presented triple-scale hydrodynamic solver for molecular liquids enables the insertion of…

Soft Condensed Matter · Physics 2009-12-29 Rafael Delgado-Buscalioni , Kurt Kremer , Matej Praprotnik

Confined granular fluids, placed in a shallow box that is vibrated vertically, can achieve homogeneous stationary states thanks to energy injection mechanisms that take place throughout the system. These states can be stable even at high…

Soft Condensed Matter · Physics 2015-06-12 Ricardo Brito , Dino Risso , Rodrigo Soto

Many suspensions contain particles with complex shapes that are affected not only by hydrodynamics, but also by thermal fluctuations, internal kinematic constraints and other long-range non-hydrodynamic interactions. Modeling these systems…

Soft Condensed Matter · Physics 2025-07-31 Blaise Delmotte , Florencio Balboa Usabiaga

We present a novel mixed quantum-classical approach to the coupled electron-nuclear dynamics based on the exact factorization of the electron-nuclear wave function, recently proposed in [A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys.…

Chemical Physics · Physics 2015-06-18 Ali Abedi , Federica Agostini , E. K. U. Gross

Quantum physics is a linear theory, so it is somewhat puzzling that it can underlie very complex systems such as digital computers and life. This paper investigates how this is possible. Physically, such complex systems are necessarily…

Quantum Physics · Physics 2024-03-12 George F R Ellis

Recent advancements of intermediate-scale quantum processors have triggered tremendous interest in the exploration of practical quantum advantage. The simulation of fluid dynamics, a highly challenging problem in classical physics but vital…

Constraints in power consumption and computational power limit the skill of operational numerical weather prediction by classical computing methods. Quantum computing could potentially address both of these challenges. Herein, we present…

Quantum Physics · Physics 2026-05-13 Reuben Demirdjian , Daniel Gunlycke , Carolyn A. Reynolds , James D. Doyle , Sergio Tafur

The Madelung equations offer a hydrodynamic description of quantum systems, from single particles to quantum fluids. In this formulation, the probability density is mapped onto the fluid density and the phase is treated as a scalar…

Fluid Dynamics · Physics 2026-04-20 Christopher Triola

Starting with the exact factorization of the molecular wavefunction, this paper presents the results from the numerical implementation in nonadiabatic molecular dynamics of the recently proposed bohmion method. Within the context of quantum…

Chemical Physics · Physics 2021-10-06 Darryl D. Holm , Jonathan I. Rawlinson , Cesare Tronci

Semiclassical approximations for quantum dynamic simulations in complex chemical systems range from rigorously accurate methods that are computationally expensive to methods that exhibit near-classical scaling with system size but are…

Chemical Physics · Physics 2022-09-09 Shreyas Malpathak , Matthew S. Church , Nandini Ananth

Correlated many-fermion systems emerge in a broad range of phenomena in warm dense matter, plasmonics, and ultracold atoms. Quantum hydrodynamics (QHD) complements common first-principles methods for many-fermion systems and enables…

Plasma Physics · Physics 2022-02-17 Zh. A. Moldabekov , T. Dornheim , G. Gregori , F. Graziani , M. Bonitz , A. Cangi

Real numbers provide a sufficient description of classical physics and all measurable phenomena; however, complex numbers are occasionally utilized as a convenient mathematical tool to aid our calculations. On the other hand, the formalism…

Quantum Physics · Physics 2023-09-01 Matthew Albert , Xiaoyi Bao , Liang Chen