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We establish the foundations of a nonequilibrium theory of quantum thermodynamics for noninteracting open quantum systems strongly coupled to their reservoirs within the framework of the nonequilibrium Green functions (NEGF). The energy of…

Statistical Mechanics · Physics 2015-03-18 Massimiliano Esposito , Maicol A. Ochoa , Michael Galperin

We explore driven lattice gases for the existence of an intensive thermodynamic variable which could determine "equilibration" between two nonequilibrium steady-state systems kept in weak contact. In simulations, we find that these systems…

Statistical Mechanics · Physics 2015-05-07 Punyabrata Pradhan , Christian P. Amann , Udo Seifert

Thermodynamics, and in particular its first law, is of fundamental importance to Science, and therefore of great general interest to all physicists. The first law, although undoubtedly true, and believed by everyone to be true because of…

Statistical Mechanics · Physics 2007-05-23 S. Martinez , A. Plastino , B. H. Soffer

We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the…

High Energy Physics - Theory · Physics 2013-03-14 Jyotirmoy Bhattacharya , Masahiro Nozaki , Tadashi Takayanagi , Tomonori Ugajin

Motivated by the possibility of electrochemical control of phase separation, a variational theory of thermodynamic stability is developed for driven reactive mixtures, based on a nonlinear generalization of the Cahn-Hilliard and Allen-Cahn…

Chemical Physics · Physics 2017-11-01 Martin Z. Bazant

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

Statistical Mechanics · Physics 2007-05-23 D. Reguera , J. M. Rubi , J. M. G. Vilar

We consider viscous, heat conducting mixtures of molecularly miscible chemical species forming a fluid in which the constituents can undergo chemical reactions. Assuming a common temperature for all components, we derive a closed system of…

Fluid Dynamics · Physics 2016-04-01 Dieter Bothe , Wolfgang Dreyer

A few decades after Hill's work on nano-thermodynamics, the development of a thermodynamic framework, to account consistently for the fluctuations of small systems due to their interactions with the surrounding environment, is still…

Statistical Mechanics · Physics 2019-09-23 Salvatore Calabrese , Lamberto Rondoni , Amilcare Porporato

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

The variational method is very important in mathematical and theoretical physics because it allows us to describe the natural systems by physical quantities independently from the frame of reference used. A global and statistical approach…

Mathematical Physics · Physics 2011-01-10 Umberto Lucia

We study the energy exchange between two bosonic systems that interact via bilinear transformations in the mode operators. The first mode is considered as the thermodynamic system, while the second is regarded as the bath. This work finds…

Quantum Physics · Physics 2020-06-23 Chiara Macchiavello , Alberto Riccardi , Massimiliano F. Sacchi

The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this letter, we…

Statistical Mechanics · Physics 2020-07-01 S. N. Saadatmand , Tim Gould , E. G. Cavalcanti , J. A. Vaccaro

A simplified climate model based on maximum entropy production, described by a variational principle, is revisited and an analytical solution to its Euler-Lagrange equation is found. Mindful of controversy about maximum or minimum entropy…

Atmospheric and Oceanic Physics · Physics 2020-10-22 Valerio Faraoni

This paper addresses the derivation of a two-phase flow model accounting for surface tension effects, by means of the Stationary Action Principle (SAP). The Lagrangian functional, defining the Action, is composed of a kinetic energy,…

Analysis of PDEs · Mathematics 2023-12-05 Hélène Mathis

We use the work done on and the heat removed from a system to maintain it in a nonequilibrium steady state for a thermodynamic-like description of such a system as well as of its fluctuations. Based on a generalized Onsager-Machlup theory…

Statistical Mechanics · Physics 2008-02-10 Tooru Taniguchi , E. G. D. Cohen

We provide some new properties of entanglement of formation. In particular, we obtain an additive lower bound for entanglement of formation. Subsequently we develop the concept of local orthogonality of ensembles which leads to the mixed…

Quantum Physics · Physics 2007-05-23 Pawel Horodecki , Ryszard Horodecki , Michal Horodecki

In equilibrium, the collective behaviour of particles interacting via steep, short-ranged potentials is well captured by the virial expansion of the free energy at low density. Here, we extend this approach beyond equilibrium to the case of…

Soft Condensed Matter · Physics 2023-06-21 Yuting Irene Li , Rosalba Garcia-Millan , Michael E. Cates , Étienne Fodor

There is a common view in thermodynamics that the behavior of a macroscopic system can be described by only a few state variables. Although this is true for many cases, it is unclear whether it is meaningful to ask how many state variables…

Statistical Mechanics · Physics 2022-01-05 Koun Shirai

A "minimal" generalization of Quantum Mechanics is proposed, where the Lagrangian or the action functional is a mapping from the (classical) states of a system to the Lie algebra of a general compact Lie group, and the wave function takes…

Quantum Physics · Physics 2007-05-23 Yu Tian

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura