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The well-known thermal capillary wave theory, which describes the capillary spectrum of the free surface of a liquid film, does not reveal the transient dynamics of surface waves, e.g., the process through which a smooth surface becomes…

Fluid Dynamics · Physics 2021-09-17 Yixin Zhang , James E. Sprittles , Duncan A. Lockerby

A theoretical study is presented of surface waves at a monomolecular surfactant film between an isotropic liquid and a nematic liquid crystal for the case when the surfactant film is in the isotropic two-dimensional fluid phase and induces…

Soft Condensed Matter · Physics 2008-04-15 S. V. Lishchuk

The effect of confining walls on the fluctuation of a nanoscale thin film's free surface is studied using stochastic thin-film equations (STFEs). Two canonical boundary conditions are employed to reveal the influence of the confinement: (1)…

Fluid Dynamics · Physics 2023-01-25 Jingbang Liu , Chengxi Zhao , Duncan A. Lockerby , James E. Sprittles

We study the effect of insoluble surfactants on the wave dynamics of vertically-falling liquid films. We use three-dimensional numerical simulations and employ a hybrid interface-tracking/level-set method, taking into account Marangoni…

Motivated by recent experimental studies probing i) the existence of a mobile layer at the free surface of glasses, and ii) the capillary leveling of polymer nanofilms, we study the evolution of square-wave patterns at the free surface of a…

Soft Condensed Matter · Physics 2019-09-18 Ioannis Tanis , Kostas Karatasos , Thomas Salez

A multispecies diffuse interface model is formulated in a fluctuating hydrodynamics framework for the purpose of simulating surfactant interfaces at the nanoscale. The model generalizes previous work to ternary mixtures, employing a…

Fluid Dynamics · Physics 2025-08-26 John B. Bell , Andrew Nonaka , Alejandro L. Garcia

We consider thin fluid films placed on thermally conductive substrates and exposed to time-dependent spatially uniform heat source. The evolution of the films is considered within the long-wave framework in the regime such that both…

Soft Condensed Matter · Physics 2016-06-16 Nanyi Dong , Lou Kondic

The relaxation dynamics of thermal capillary waves for nanoscale liquid films on anisotropic-slip substrates are investigated, using both molecular dynamics (MD) simulations and a Langevin model. The anisotropy of slip on substrates is…

Fluid Dynamics · Physics 2021-09-17 Yixin Zhang , Duncan A. Lockerby , James E. Sprittles

Experiments over the last 50 years have suggested a tentative correlation between the surface (shear) viscosity and the stability of a foam or emulsion. We examine this link theoretically using small-amplitude capillary waves in the…

Fluid Dynamics · Physics 2018-07-04 Li Shen , Fabian Denner , Neal Morgan , Berend van Wachem , Daniele Dini

We present three-dimensional numerical simulations, employing the well-established lattice Boltzmann method, and investigate similarities and differences between surfactants and nanoparticles as additives at a fluid-fluid interface. We…

Soft Condensed Matter · Physics 2012-07-26 Stefan Frijters , Florian Günther , Jens Harting

A systematically designed study has been conducted to understand and clearly demarcate the degree of contribution by the constituting elements to the surface tension of nanocolloids. The effects of elements such as surfactants, particles…

Soft Condensed Matter · Physics 2016-10-20 A R Harikrishnan , Purbarun Dhar , PK Agnihotri , Sateesh Gedupudi , Sarit K Das

The dewetting of thin nanofilms is significantly impacted by thermal fluctuations, liquid-solid slip, and disjoining pressure, which can be described by lubrication equations augmented by appropriately scaled noise terms, known as…

Fluid Dynamics · Physics 2024-10-29 Yixin Zhang

We study the effect of insoluble surfactants on the impact of surfactant-free droplets on surfactant-laden thin liquid films via a fully three-dimensional direct numerical simulations approach that employs a hybrid…

Thin liquid films are ubiquitous across many natural and engineering systems, including films which are laden with surface active molecules, i.e. surfactants. The presence of surfactants may have a destabilising effect on the film owing to…

Statistical Mechanics · Physics 2026-05-25 Toby Kay , Serafim Kalliadasis

The van der Waals forces across a very thin liquid layer (nanofilm) in contact with a plane solid wall make the liquid nonhomogeneous. The dynamics of such flat liquid nanofilms is studied in isothermal case. The Navier-Stokes equations are…

Classical Physics · Physics 2008-09-23 Henri Gouin , Sergey Gavrilyuk

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and stress tensors are not any more spherical as in homogeneous bulks. The aim of this article is to show that a square-gradient functional…

Classical Physics · Physics 2017-08-23 Henri Gouin

The behavior of thin liquid films is known to be strongly affected by the presence of surfactants at the interfaces. The detailed mechanism by which the latter enhance film stability is still a matter of debate, in particular concerning the…

Soft Condensed Matter · Physics 2019-07-24 Lorène Champougny , Benoit Scheid , Frédéric Restagno , Jan Vermant , Emmanuelle Rio

Coalescence of micrometer-scale droplets is impacted by several parameters, including droplet size, viscosities of the two phases, droplet velocity and angle of approach, as well as interfacial tension and surfactant coverage. The dynamics…

Surface tension-driven flow techniques have recently emerged as an efficient means of shedding light into the rheology of thin polymer films. Motivated by experimental and theoretical approaches in films bearing a varying surface…

Soft Condensed Matter · Physics 2017-04-26 Ioannis Tanis , Hendrik Meyer , Thomas Salez , Elie Raphaël , Anthony C. Maggs , Jörg Baschnagel

Surfactant transport is central to a diverse range of natural phenomena, and for many practical applications in physics and engineering. Surprisingly, this process remains relatively poorly understood at the molecular scale. This study…

Soft Condensed Matter · Physics 2025-04-16 Muhammad Rizwanur Rahman , James P. Ewen , Li Shen , D. M. Heyes , Daniele Dini , E. R. Smith
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