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The evolution of star-forming regions and their thermal balance are strongly influenced by their chemical composition, that, in turn, is determined by the physico-chemical processes that govern the transition between the gas phase and the…

Millimeter and centimeter observations are discovering an increasing number of interstellar complex organic molecules (iCOMs) in a large variety of star forming sites, from the earliest stages of star formation to protoplanetary disks and…

Instrumentation and Methods for Astrophysics · Physics 2021-06-09 Maria Angela Corazzi , John Robert Brucato , Giovanni Poggiali , Linda Podio , Davide Fedele , Claudio Codella

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

Since molecules are ubiquitous in space, the study of the 'Molecular Universe' could unfold the mystery of the existing Interstellar medium. Star formation is linked to the chemical evolution processes. Thus, an analysis of the formation of…

Astrophysics of Galaxies · Physics 2024-05-29 Bratati Bhat

The recent discovery of terrestrial-type organic species such as methyl formate and dimethyl ether in the cold interstellar gas has proved that the formation of organic matter in the Galaxy begins at a much earlier stage of star formation…

Astrophysics of Galaxies · Physics 2015-06-15 A. I. Vasyunin , Eric Herbst

To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…

Astrophysics of Galaxies · Physics 2024-04-04 F. Kruczkiewicz , F. Dulieu , A. V. Ivlev , P. Caselli , B. M. Giuliano , C. Ceccarelli , P. Theulé

We present experimental measurements of photodesorption from ices of astrophysical relevance. Layers of benzene and water ice were irradiated with a laser tuned to an electronic transition in the benzene molecule. The translational energy…

We present a method for modelling star-forming clouds that combines two different models of the thermal evolution of the interstellar medium (ISM). In the combined model, where the densities are low enough that at least some part of the…

Solar and Stellar Astrophysics · Physics 2015-03-19 Matthew R. Bate , Eric R. Keto

In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…

Astrophysics of Galaxies · Physics 2018-10-12 Y. Oba , T. Tomaru , T. Lamberts , A. Kouchi , N. Watanabe

Temperature programmed desorption (TPD) is a well-known technique to study gas-surface processes, and it is characterized by two main quantities: the adsorbate binding energy and the pre-exponential factor. While the former has been well…

Astrophysics of Galaxies · Physics 2025-08-06 S. Pantaleone , L. Tinacci , V. Bariosco , A. Rimola , C. Ceccarelli , P. Ugliengo

Aims: The gas-phase abundance of methanol in dark quiescent cores in the interstellar medium cannot be explained by gas-phase chemistry. In fact, the only possible synthesis of this species appears to be production on the surfaces of dust…

Astrophysics · Physics 2009-11-13 R. T. Garrod , V. Wakelam , E. Herbst

Thermal annealing of interstellar ices takes place in several stages of star formation. Knowledge of this process comes from a combination of astronomical observations and laboratory simulations under astrophysically relevant conditions.…

Solar and Stellar Astrophysics · Physics 2014-06-03 Rafael Martín-Doménech , Guillermo M. Muñoz Caro , Juan Bueno , Fred Goesmann

Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the chemical composition of comets forming in circumstellar disks. From observations, most volatile species are found in…

Earth and Planetary Astrophysics · Physics 2011-09-01 Edith C. Fayolle , Karin I. Oberg , Herma M. Cuppen , Ruud Visser , Harold Linnartz

The standard model of cosmic ray heating-induced desorption of interstellar ices is based on a continuous representation of the sporadic desorption of ice mantle components from classical (0.1 micron) dust grains. This has been re-evaluated…

Solar and Stellar Astrophysics · Physics 2022-08-17 Jonathan M. C. Rawlings

The desorption characteristics of molecules on interstellar dust grains are important for modelling the behaviour of molecules in icy mantles and, critically, in describing the solid-gas interface. In this study, a series of laboratory…

Solar and Stellar Astrophysics · Physics 2015-06-03 J. A. Noble , E. Congiu , F. Dulieu , H. J. Fraser

Computational identification of unknown adsorption and desorption rates is discussed in conjunction with reactive flow considered at pore scale. The reactive transport is governed by incompressible Stokes equations, coupled with…

Numerical Analysis · Mathematics 2019-12-10 Vasiliy V. Grigoriev , Oleg Iliev , Petr N. Vabishchevich

Currently ~36 different absorption bands have been detected in the infrared spectra of cold, dense interstellar and circumstellar environments. These are attributed to the vibrational transitions of ~17 different molecules frozen on dust…

Astrophysics · Physics 2007-05-23 A. C. A. Boogert , P. Ehrenfreund

In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…

Solar and Stellar Astrophysics · Physics 2017-11-08 S. Cazaux , R. Martin-Domenech , Y. J. Chen , G. M. Munoz Caro , C. Gonzalez Diaz

A new experimental set-up INterStellar Ice-Dust Experiment (INSIDE), was designed for studying cosmic grain analogues represented by ice-coated carbon- and silicate-based dust grains. In the new instrument, we can simulate physical and…

Instrumentation and Methods for Astrophysics · Physics 2019-07-24 Alexey Potapov , Cornelia Jäger , Thomas Henning

Dust grains in the interstellar medium interact with photons across the electromagnetic spectrum. They are generally photon energy converters, absorbing short wavelength radiation and emitting long wavelength radiation. Sixty years ago in…

Astrophysics of Galaxies · Physics 2026-01-19 Yancy L. Shirley , Jeffrey G. Mangum , Desika Narayanan , James Di Francesco
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