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In the $GW$ approximation, the screened interaction $W$ is a non-local and dynamical potential that usually has a complex frequency dependence. A full description of such dependence is possible but often computationally demanding. For this…

We investigate the behaviour of randomly cross-linked (co)polymer blends using a combination of replica theory and large-scale molecular dynamics simulations. In particular, we derive the analogue of the random phase approximation for…

Soft Condensed Matter · Physics 2009-11-13 A. V. Klopper , Carsten Svaneborg , Ralf Everaers

We investigate static correlation and delocalization errors in the self-consistent GW and random-phase approximation (RPA) by studying molecular dissociation of the H_2 and LiH molecules. Although both approximations contain topologically…

Strongly Correlated Electrons · Physics 2015-04-10 Maria Hellgren , Fabio Caruso , Daniel R. Rohr , Xinguo Ren , Angel Rubio , Matthias Scheffler , Patrick Rinke

The ground-state correlation energy calculated in the random-phase approximation (RPA) is known to be identical to that calculated using a subset of terms appearing in coupled-cluster theory with double excitations. In particular, this…

Chemical Physics · Physics 2019-04-16 Timothy C. Berkelbach

Floating-point arithmetic (FPA) is a mechanical representation of real arithmetic (RA), where each operation is replaced with a rounded counterpart. Various numerical properties can be verified by using SMT solvers that support the logic of…

Logic in Computer Science · Computer Science 2021-12-07 Daisuke Ishii , Takashi Tomita , Toshiaki Aoki

Using Green-function many-body theory, we present the details of a formally exact adiabatic-connection fluctuation-dissipation density-functional theory based on range separation, which was sketched in Toulouse, Gerber, Jansen, Savin and…

Chemical Physics · Physics 2010-09-13 Julien Toulouse , Wuming Zhu , Janos G. Angyan , Andreas Savin

We develop and implement a formalism which enables calculating the analytical gradients of particle-hole random-phase approximation (RPA) ground-state energy with respect to the atomic positions within the atomic orbital basis set…

Chemical Physics · Physics 2021-09-03 Muhammad N. Tahir , Tong Zhu , Honghui Shang , Jia Li , Volker Blum , Xinguo Ren

Several approaches to photonuclear reactions, based on the time-dependent density-functional theory, have been developed recently. The standard linearization leads to the random-phase approximation (RPA) or the quasiparticle-random-phase…

The focus of the present work is the application of the random phase approximation (RPA), derived for inhomogeneous fluids [Frydel and Ma, Phys. Rev. E 93, 062112 (2016)], to penetrable-spheres. As penetrable-spheres transform into…

Statistical Mechanics · Physics 2017-05-17 Yan Xiang , Derek Frydel

We present a method to approximate post-Hartree-Fock correlation energies by using approximate natural orbitals obtained by the random phase approximation (RPA). We demonstrate the method by applying it to the helium atom, the hydrogen and…

Chemical Physics · Physics 2021-03-22 Benjamin Ramberger , Zoran Sukurma , Tobias Schäfer , Georg Kresse

Particle-number projection within the Lipkin-Nogami (LN) method is applied to the self-consistent quasiparticle random-phase approximation (SCQRPA), which is tested in an exactly solvable multi-level pairing model. The SCQRPA equations are…

Nuclear Theory · Physics 2014-11-18 Nguyen Quang Hung , Nguyen Dinh Dang

Biologically functional liquid-liquid phase separation of intrinsically disordered proteins (IDPs) is driven by interactions encoded by their amino acid sequences. Little is currently known about the molecular recognition mechanisms for…

Biomolecules · Quantitative Biology 2017-11-15 Yi-Hsuan Lin , Jacob P. Brady , Julie D. Forman-Kay , Hue Sun Chan

The optimized random phase approximation (ORPA) for classical liquids is re-examined in the framework of the generating functional approach to the integral equations. We show that the two main variants of the approximation correspond to the…

Chemical Physics · Physics 2009-10-30 G. Pastore , O. Akinlade , F. Matthews , Z. Badirkhan

A nonlinear description of the interaction of charged particles penetrating a solid has become of basic importance in the interpretation of a variety of physical phenomena. Here we develop a many-body theoretical approach to the quadratic…

Materials Science · Physics 2009-10-31 T. del Rio Gaztelurrutia , J. M. Pitarke

Recurrence quantification analysis (RQA) is a widely used tool for studying complex dynamical systems, but its standard implementation requires computationally expensive calculations of recurrence plots (RPs) and line length histograms.…

Chaotic Dynamics · Physics 2026-01-06 Norbert Marwan

An application of a self-consistent version of RPA to quantum field theory with broken symmetry is presented. Although our approach can be applied to any bosonic field theory, we specifically study the $\phi^4$ theory in 1+1 dimensions. We…

High Energy Physics - Phenomenology · Physics 2007-05-23 H. Hansen , G. Chanfray , D. Davesne , P. Schuck

We recently introduced an efficient methodology to perform density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) calculations and an extension to it we called "corrected" HF DFT (C(HF)-DFT). In this work, we take a further…

Chemical Physics · Physics 2023-11-10 Daniel Graf , Alex J. W. Thom

The dynamical effects of ground state correlations for excitation energies and transition strengths near the superfluid phase transition are studied in the soluble two level pairing model, in the context of the particle-particle self…

Nuclear Theory · Physics 2008-11-26 E. J. V. de Passos , A. F. R. de Toledo Piza , F. Krmpotić

The particle-particle random phase approximation (ppRPA) within the hole-hole channel was recently proposed as an efficient tool for computing excitation energies of point defects in solids [J. Phys. Chem. Lett. 2024, 15, 2757-2764]. In…

Chemical Physics · Physics 2024-06-27 Jiachen Li , Yu Jin , Jincheng Yu , Weitao Yang , Tianyu Zhu

Real-time optimization with persistent parameter adaptation (ROPA) is an RTO approach, where the steady-state model parameters are updated dynamically using transient measurements. Consequently, we avoid waiting for a steady-state before…

Systems and Control · Electrical Eng. & Systems 2022-06-02 J. Matias , J. P. C. Oliveira , G. A. C. Le Roux , J. Jaschke
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