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"A battery powers a device" can be read as "work stored in the battery is being transported to the device." In quantum batteries, the total amount of stored work can be measured by ergotropy, which is the maximal work extractable by unitary…

Quantum Physics · Physics 2025-01-20 Rick P. A. Simon , Janet Anders , Karen V. Hovhannisyan

In this article a definition of reversible processes in terms of differences in intensive Thermodynamics properties (Affinities) is proposed. This definition makes it possible to both define reversible processes before introducing the…

Classical Physics · Physics 2016-08-09 Hernán A. Ritacco

Shannon's entropy and other entropy-based concepts are derived from the new, more general concept of relative divergence of one "grading' function on a linearly ordered set from another such function. The definition of relative divergence…

Probability · Mathematics 2019-03-14 Alexander Dukhovny

Machine learning is usually defined in behaviourist terms, where external validation is the primary mechanism of learning. In this paper, I argue for a more holistic interpretation in which finding more probable, efficient and abstract…

Artificial Intelligence · Computer Science 2017-11-07 Johan Loeckx

A unified thermodynamic formalism describing the efficiency of learning is proposed. First, we derive an inequality, which is more strength than Clausius's inequality, revealing the lower bound of the entropy-production rate of a subsystem.…

Statistical Mechanics · Physics 2025-04-15 Shanhe Su , Ousi Pan , Shihao Xia , Jincan Chen , Chikako Uchiyama

Informational entropy is often identified as physical entropy. This is surprising because the two quantities are differently defined and furthermore the former is a subjective quantity while the latter is an objective one. We describe the…

Quantum Physics · Physics 2014-05-01 Won-Young Hwang

Learning systems acquire structured internal representations from data, yet classical information-theoretic results state that deterministic transformations do not increase information. This raises a fundamental question: how can learning…

Machine Learning · Computer Science 2026-01-29 Daisuke Okanohara

Partial differential equations are ubiquitous in almost all applications of mathematics, where they provide a natural mathematical description of many phenomena involving change in physical, chemical, biological, and social processes. The…

Analysis of PDEs · Mathematics 2013-11-07 John M. Ball , Gui-Qiang G. Chen

Entropy production is a fundamental concept that plays a crucial role in the second law of thermodynamics and the measure of irreversibility. It imposes rigorous constraints on the kinds of transformations allowed in thermodynamic…

We first present open questions related to the foundations of thermodynamics and statistical physics. We then argue that in principle one can not have "closed systems", and that a universal background should exist. We propose that the…

Condensed Matter · Physics 2009-10-31 Eshel Ben-Jacob , Ziv Hermon , Alexsander Shnirman

In recent years we have witnessed a concentrated effort to make sense of thermodynamics for small-scale systems. One of the main difficulties is to capture a suitable notion of work that models realistically the purpose of quantum machines,…

Quantum Physics · Physics 2016-11-23 R. Gallego , J. Eisert , H. Wilming

We address the emergence of entropy production in the non-equilibrium process of an open quantum system from the viewpoint of the environment. By making use of a dilation-based approach akin to Stinespring theorem, we derive an expression…

Entropy production characterizes irreversibility. This viewpoint allows us to consider the thermodynamic uncertainty relation, which states that a higher precision can be achieved at the cost of higher entropy production, as a relation…

Statistical Mechanics · Physics 2021-12-09 Yoshihiko Hasegawa

In this work we analyze the deviations of reversible cycles (for both heat engines and refrigerators) from the corresponding Carnot cycle operating between the same extreme temperatures and deviations of irreversible cycles from its…

Statistical Mechanics · Physics 2024-02-13 J. Gonzalez-Ayala , F. Angulo-Brown , A. Calvo Hernández , S. Velasco

Given the evolution of an arbitrary open quantum system, we formulate a general and unambiguous method to separate the internal energy change of the system into an entropy-related contribution and a part causing no entropy change,…

Quantum Physics · Physics 2022-10-26 S. Alipour , A. T. Rezakhani , A. Chenu , A. del Campo , T. Ala-Nissila

Thermodynamics teaches that if a system initially off-equilibrium is coupled to work sources, the maximum work that it may yield is governed by its energy and entropy. For finite systems this bound is usually not reachable. The maximum…

Statistical Mechanics · Physics 2009-11-10 A. E. Allahverdyan , R. Balian , Th. M. Nieuwenhuizen

Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to…

Physics Education · Physics 2015-06-26 Clinton D. Stoner

Different notions of entropy play a fundamental role in the classical theory of dynamical systems. Unlike many other concepts used to analyze autonomous dynamics, both measure-theoretic and topological entropy can be extended quite…

Dynamical Systems · Mathematics 2017-08-03 Christoph Kawan

In many real-world situations, there are constraints on the ways in which a physical system can be manipulated. We investigate the entropy production (EP) and extractable work involved in bringing a system from some initial distribution $p$…

Statistical Mechanics · Physics 2022-11-22 Artemy Kolchinsky , David H. Wolpert

It is generally admitted in thermodynamics that, for a given change in volume, the work done by a system is greater in conditions of reversibility than in conditions of irreversibility. If the basic conventions of physics are strictly…

General Physics · Physics 2007-10-31 Jean-Louis Tane