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Polaritons in semiconductor microcavities are hybrid quasiparticles consisting of a superposition of photons and excitons. Due to the photon component, polaritons are characterized by a quantum coherence length in the several micron range.…

We propose collective nuclear polaritons formed by hybridizing a 229Th nuclear ensemble with a vacuum-ultraviolet cavity mode generated via four-wave mixing, achieving a collective light-matter coupling that scales as $\sqrt{N}$. In the…

Quantum Physics · Physics 2026-03-17 Liufeng Yang , Jinling Wang , Huijun Li , Junhui Cao , Alexey Kavokin , Congjun Wu

The experimental realization of strong light-matter coupling with molecules initiated the rapidly evolving field of molecular polaritonics. Most studies focus on how exciton polaritons, which combine electronic excitations with confined…

Chemical Physics · Physics 2025-09-10 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

The observation that materials can change their properties when placed inside or near an optical resonator, has sparked a fervid interest in understanding the effects of strong light-matter coupling on molecular dynamics, and several…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Gerrit Groenhof

Strong coupling of molecules to the vacuum field of micro cavities can modify the potential energy surfaces opening new photophysical and photochemical reaction pathways. While the influence of laser fields is usually described in terms of…

Quantum Physics · Physics 2016-02-08 Markus Kowalewski , Kochise Bennett , Shaul Mukamel

The formation of the composite photonic-excitonic particle, known as a polariton, is a phenomenon emerging in materials possessing strong coupling to light. The organic-based materials besides the strong light-matter coupling also…

Chemical Physics · Physics 2023-01-19 Vladimir Al. Osipov , Boris Fainberg

Altering chemical reactivity and material structure in confined optical environments is on the rise, and yet, a conclusive understanding of the microscopic mechanisms remains elusive. This originates mostly from the fact that accurately…

Chemical Physics · Physics 2024-03-22 Christian Schäfer , Jakub Fojt , Eric Lindgren , Paul Erhart

We introduce a theoretical framework that allows for the systematic and efficient description of the ultrafast nonlinear response of molecular polaritons, i.e., hybrid light-matter states, in the collective regime of large numbers of…

Quantum Physics · Physics 2025-05-22 Michael Reitz , Arghadip Koner , Joel Yuen-Zhou

Polaritons are quasi-particles originating from the coupling of light with matter that demonstrated quantum phenomena at the many-particle mesoscopic level, such as BEC and superfluidity. A highly sought and long-time missing feature of…

We develop coupled-cluster theory for systems of electrons strongly coupled to photons, providing a promising theoretical tool in polaritonic chemistry with a perspective of application to all types of fermion-boson coupled systems. We show…

Exciton polaritons in two-dimensional semiconductors inside microcavities are powerful platforms to explore hybrid light-matter quantum systems. Here, we study a macroscopic coherent population of the lowest energy state of…

Mesoscale and Nanoscale Physics · Physics 2021-10-26 Aleksi Julku , Miguel. A. Bastarrachea-Magnani , Arturo Camacho-Guardian , Georg M. Bruun

Cavity exciton--polaritons are quasiparticles that form when quantum well excitons hybridize with a cavity mode. Here, we carry out photon correlation measurements under continuous wave resonant laser excitation to demonstrate quantum…

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

Chemical Physics · Physics 2020-05-05 Tamás Szidarovszky , Gábor J. Halász , Ágnes Vibók

Ultracold atoms uniformly filling an optical lattice can be treated like an artificial crystal. An implementation including the atomic occupation of a single excited atomic state can be represented by a two-component Bose-Hubbard model. Its…

Quantum Gases · Physics 2013-07-31 Hashem Zoubi , Helmut Ritsch

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

We propose a mechanism to realize high-yield molecular formation from ultracold atoms. Atom pairs are continuously excited by a laser, and a collective decay into the molecular ground state is induced by a coupling to a lossy cavity mode.…

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large…

Exciton-polaritons (EP), half-light half-matter quasiparticles that form in optical cavities, are attractive platforms for creating macroscopic coherent states like BECs. EPs based on organic molecules are of particular interest for…

Recent years have witnessed a surge of experimental and theoretical interest in controlling the properties of matter, such as its chemical reactivity, by confining it in optical cavities, where the enhancement of the light-matter coupling…

We show that a system of polaritons - combined atom and photon excitations - in an array of coupled cavities, under an experimental set-up usually considered in electromagnetically induced transparency, is described by the Bose-Hubbard…

Quantum Physics · Physics 2007-05-23 Fernando G. S. L. Brandao , Michael J. Hartmann , Martin B. Plenio