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Polariton chemistry exploits the strong interaction between quantized excitations in molecules and quantized photon states in optical cavities to affect chemical reactivity. Molecular polaritons have been experimentally realized by the…

Chemical Physics · Physics 2023-09-06 Jonathan J. Foley , Jonathan F. McTague , A. Eugene DePrince

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations…

Mesoscale and Nanoscale Physics · Physics 2018-02-26 Raphael F. Ribeiro , Luis A. Martínez-Martínez , Matthew Du , Jorge Campos-Gonzalez-Angulo , Joel Yuen-Zhou

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be…

Light-matter interaction not only plays an instrumental role in characterizing materials' properties via various spectroscopic techniques but also provides a general strategy to manipulate material properties via the design of novel…

Chemical Physics · Physics 2023-08-30 Braden M. Weight , Xinyang Li , Yu Zhang

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Polaritonic chemistry exploits strong light-matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both…

Optics · Physics 2022-08-25 Jacopo Fregoni , Francisco J. García-Vidal , Johannes Feist

Gas-phase molecules are a promising platform through which to elucidate the mechanisms of action and scope of polaritons for optical control of chemistry. Polaritons arise from the strong coupling of a dipole-allowed molecular transition…

Chemical Physics · Physics 2024-08-20 Jane C. Nelson , Marissa L. Weichman

Exciton-polaritons are hybrid elementary excitations of light and matter that, thanks to their nonlinear properties, enable a plethora of physical phenomena ranging from room temperature condensation to superfluidity. While polaritons are…

Mesoscale and Nanoscale Physics · Physics 2022-03-23 Davide Nigro , Vincenzo D'Ambrosio , Daniele Sanvitto , Dario Gerace

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

The polariton, a quasiparticle formed by strong coupling of a photon to a matter excitation, is a fundamental ingredient of emergent photonic quantum systems ranging from semiconductor nanophotonics to circuit quantum electrodynamics.…

Quantum Gases · Physics 2024-03-21 Joonhyuk Kwon , Youngshin Kim , Alfonso Lanuza , Dominik Schneble

Polaritons are quantum mechanical superpositions of photon states with elementary excitations in molecules and solids. The light-matter admixture causes a characteristic frequency-momentum dispersion shared by all polaritons irrespective of…

Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

Exciton-polaritons - coherently hybridized states of excitons and photons - are instrumental for solid-state nonlinear optics and quantum simulations. To enable engineered polariton energy landscapes and interactions, local control over the…

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

Polaritonic states arise when a bright optical transition of a molecular ensemble is resonantly matched to an optical cavity mode frequency. Here, we lay the groundwork to study the behavior of polaritons in clean, isolated systems by…

Chemical Physics · Physics 2023-10-20 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Two-dimensional semiconductors inside optical microcavities have emerged as a versatile platform to explore new hybrid light-matter quantum states. The strong light-matter coupling leads to the formation of exciton-polaritons, which in turn…

Mesoscale and Nanoscale Physics · Physics 2021-11-05 Miguel Angel Bastarrachea-Magnani , Jannie Thomsen , Arturo Camacho-Guardian , Georg M. Bruun

We study a hybrid system formed from an optomechanical resonator and a cavity mode strongly coupled to an excitonic transition inside a quantum well. We show that due to the mixing of cavity photon and exciton states, the emergent…

Mesoscale and Nanoscale Physics · Physics 2014-03-04 O. Kyriienko , T. C. H. Liew , I. A. Shelykh
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