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We present an overview of the role of quantum coherence in influencing nonadiabatic processes in the condensed phase. Equations of motion for mixed quantum-classical dynamics are derived from the Consistent Histories interpretation of…

Chemical Physics · Physics 2008-02-03 Eric R. Bittner

Nonequilibrium states of closed quantum many-body systems defy a thermodynamic description. As a consequence, constraints such as the principle of equal a priori probabilities in the microcanonical ensemble can be relaxed, which can lead to…

Statistical Mechanics · Physics 2019-03-27 Markus Heyl

Many physical and chemical processes in the condensed phase environment exhibit non-Markovian quantum dynamics. As such simulations are challenging on classical computers, we developed a variational quantum algorithm that is capable of…

Quantum Physics · Physics 2024-03-11 Peter L. Walters , Joachim Tsakanikas , Fei Wang

We address the nonadiabatic quantum dynamics of macrosystems with several coupled electronic states, taking into account the possibility of multi-state conical intersections. The general situation of an arbitrary number of states and…

Chemical Physics · Physics 2009-11-13 Etienne Gindensperger , Lorenz S. Cederbaum

Direct dynamics methods using Gaussian wavepackets have to rely only on local properties, such as gradients and hessians at the center of the wavepacket, so as to be compatible with the usual quantum chemistry methods. Matrix elements of…

Chemical Physics · Physics 2016-04-26 Alexander Humeniuk , Roland Mitric

Time evolution of quantum systems is of interest in physics, in chemistry, and, more recently, in computer science. Quantum computers are suggested as one route to propagating quantum systems far more efficiently than ordinary numerical…

Quantum Physics · Physics 2015-02-13 James Daniel Whitfield

Nonadiabatic geometric quantum computation provides a means to perform fast and robust quantum gates. It has been implemented in various physical systems, such as trapped ions, nuclear magnetic resonance and superconducting circuits.…

Quantum Physics · Physics 2017-12-06 P. Z. Zhao , Xiao-Dan Cui , G. F. Xu , Erik Sjöqvist , D. M. Tong

The adiabatic quantum algorithm has drawn intense interest as a potential approach to accelerating optimization tasks using quantum computation. The algorithm is most naturally realised in systems which support Hamiltonian evolution, rather…

Quantum Physics · Physics 2019-10-02 Liming Zhao , Carlos A. Perez-Delgado , Simon C. Benjamin , Joseph F. Fitzsimons

Computing using a continuous-time evolution, based on the natural interaction Hamiltonian of the quantum computer hardware, is a promising route to building useful quantum computers in the near-term. Adiabatic quantum computing, quantum…

Quantum Physics · Physics 2019-03-06 James G. Morley , Nicholas Chancellor , Sougato Bose , Viv Kendon

Digital quantum computers provide a computational framework for solving the Schr\"{o}dinger equation for a variety of many-particle systems. Quantum computing algorithms for the quantum simulation of these systems have recently witnessed…

Quantum Physics · Physics 2022-03-21 Mario Motta , Julia Rice

Computational methods are the most effective tools we have besides scientific experiments to explore the properties of complex biological systems. Progress is slowing because digital silicon computers have reached their limits in terms of…

Quantum Physics · Physics 2020-04-03 Viv Kendon

We develop a unified quantum geometric framework to understand reactive quantum dynamics. The critical roles of the quantum geometry of adiabatic electronic states in both adiabatic and non-adiabatic quantum dynamics are unveiled. A…

Chemical Physics · Physics 2025-05-19 Yujuan Xie , Ruoxi Liu , Bing Gu

We review a scheme for the systematic design of quantum control protocols based on shortcuts to adiabaticity in few-level quantum systems. The adiabatic dynamics is accelerated by introducing high-frequency modulations in the control…

Quantum Physics · Physics 2024-02-08 Francesco Petiziol , Florian Mintert , Sandro Wimberger

The simulation of non-Markovian quantum dynamics plays an important role in the understanding of charge and exciton dynamics in the condensed phase environment, and yet it remains computationally expensive on classical computers. We have…

Quantum Physics · Physics 2024-12-03 Peter L. Walters , Mohammad U. Sherazi , Fei Wang

The nonadiabatic quantum kinetic equations and Dirac-Heisenberg-Wigner formalism for Schwinger pair production in a spatially uniform and time-varying electric field with multiple components are derived and proven to be equivalent. The…

High Energy Physics - Theory · Physics 2025-03-05 Z. L. Li , R. Z. Jiang , Y. J. Li

A quantum computer is proposed in which information is stored in the two lowest electronic states of doped quantum dots (QDs). Many QDs are located in a microcavity. A pair of gates controls the energy levels in each QD. A Controlled Not…

Quantum Physics · Physics 2019-08-17 Mark S. Sherwin , Atac Imamoglu , Thomas Montroy

We provide model reduction formulas for open quantum systems consisting of a target component which weakly interacts with a strongly dissipative environment. The time-scale separation between the uncoupled dynamics and the interaction…

Exposing a molecule to intense light pulses may bring this molecule to a nonstationary quantum state, thus launching correlated dynamics of electronic and nuclear subsystems. Although much had been achieved in the understanding of…

Chemical Physics · Physics 2024-04-11 Nikolay V. Golubev , Jiří Vaníček

Geometric quantum computation is the idea that geometric phases can be used to implement quantum gates, i.e., the basic elements of the Boolean network that forms a quantum computer. Although originally thought to be limited to adiabatic…

Quantum Physics · Physics 2016-09-16 Erik Sjöqvist , Vahid Azimi Mousolou , Carlo M. Canali

Simulating charge and energy transfer in extended molecular networks requires an effective model to include the environment because it significantly affects the quantum dynamics. A prototypical effect known as Environment-Assisted Quantum…

Quantum Physics · Physics 2022-02-04 Federico Gallina , Matteo Bruschi , Barbara Fresch
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