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An efficient description of the structures of liquids and, in particular, the structural changes that happen with liquids on supercooling remains to be a challenge. The systems composed of soft particles are especially interesting in this…

Soft Condensed Matter · Physics 2020-09-09 V. A. Levashov , R. E. Ryltsev , N. M. Chtchelkatchev

Strong correlations between equilibrium fluctuations of the configurational parts of pressure and energy are found in the Lennard-Jones liquid and other simple liquids, but not in hydrogen-bonding liquids like methanol and water. The…

Statistical Mechanics · Physics 2009-11-13 Ulf R. Pedersen , Nicholas Bailey , Thomas B. Schrøder , Jeppe C. Dyre

We identify the pattern of microscopic dynamical relaxation for a two dimensional glass forming liquid. On short timescales, bursts of irreversible particle motion, called cage jumps, aggregate into clusters. On larger time scales, clusters…

Soft Condensed Matter · Physics 2010-10-04 R. Candelier , A. Widmer-Cooper , J. K. Kummerfeld , O. Dauchot , G. Biroli , P. Harrowell , D. R. Reichman

We study the spatio-temporal dynamics of a model of polar active fluid in two dimensions. The system exhibits a transition from an isotropic to a polarized state as a function of density. The uniform polarized state is, however, unstable…

Soft Condensed Matter · Physics 2011-12-08 Luca Giomi , M. Cristina Marchetti

We study the dynamics of water confined between hydrophobic flat surfaces at low temperature. At different pressures, we observe different behaviors that we understand in terms of the hydrogen bonds dynamics. At high pressure, the formation…

Soft Condensed Matter · Physics 2015-05-13 Giancarlo Franzese , Francisco de los Santos

We consider the effect of weak uncorrelated quenched disorder (point defects) on a strongly fluctuating flux-line liquid. We use a hydrodynamic model which is based on mapping the flux-line system onto a quantum liquid of relativistic…

Superconductivity · Physics 2009-11-11 Panayotis Benetatos , M. Cristina Marchetti

Intermolecular correlations in liquid water at ambient conditions have generally been characterized through short range density fluctuations described through the atomic pair distribution functions (PDF). Recent numerical and experimental…

Soft Condensed Matter · Physics 2016-03-23 Upayan Baul , J. Maruthi Pradeep Kanth , Ramesh Anishetty , Satyavani Vemparala

We perform molecular dynamics simulation on a glass-forming liquid binary mixture with the soft-core potential in three dimensions. We investigate crossover of the configuration changes caused by stringlike jump motions. With lowering the…

Soft Condensed Matter · Physics 2015-06-11 Takeshi Kawasaki , Akira Onuki

We present the results of a large scale molecular dynamics computer simulation study in which we investigate whether a supercooled Lennard-Jones liquid exhibits dynamical heterogeneities. We evaluate the non-Gaussian parameter for the self…

Disordered Systems and Neural Networks · Physics 2009-10-30 Walter Kob , Claudio Donati , Steven J. Plimpton , Peter H. Poole , Sharon C. Glotzer

Compressing or cooling a fluid typically enhances its static interparticle correlations. However, there are notable exceptions. Isothermal compression can reduce the translational order of fluids that exhibit anomalous waterlike trends in…

Soft Condensed Matter · Physics 2008-04-11 William P. Krekelberg , Jeetain Mittal , Venkat Ganesan , Thomas M. Truskett

This paper is the fourth in a series devoted to identifying and explaining the properties of strongly correlating liquids, i.e., liquids where virial and potential energy correlate better than 90% in their thermal equilibrium fluctuations…

Soft Condensed Matter · Physics 2013-01-29 Nicoletta Gnan , Thomas B. Schrøder , Ulf R. Pedersen , Nicholas P. Bailey , Jeppe C. Dyre

Dynamic heterogeneity as one of the most important properties in supercooled liquids has been found for several decades. However, its structural origin remains open for many systems. Here, we propose a new structural parameter to…

Disordered Systems and Neural Networks · Physics 2015-10-16 S. P. Pan , S. D. Feng , J. W. Qiao , W. M. Wang , J. Y. Qin

A growing body of theoretical and experimental evidence strongly supports the existence of a second liquid-liquid critical point (LLCP) in deeply supercooled water leading to the co-existence of two phases: a high-and low-density liquid…

Soft Condensed Matter · Physics 2026-04-17 Cesare Malosso , Edward Danquah Donkor , Stefano Baroni , Ali Hassanali

While the water molecule is simple, its condensed phase liquid behavior is so complex that no consensus description has emerged despite three centuries of effort. Here we identify features of its behavior that are the most peculiar, hence…

Chemical Physics · Physics 2014-04-16 Stacey L. Meadley , C. Austen Angell

In the present study, we performed molecular-dynamics simulations and investigated dynamical heterogeneity in a supercooled liquid under a steady shear flow. Dynamical heterogeneity can be characterized by three quantities: the correlation…

Soft Condensed Matter · Physics 2012-04-25 Hideyuki Mizuno Ryoichi Yamamoto

One of the basic concepts of modern physics with a long prehistory is a fluid, which means a substance that flows under an applied shear stress. In this sense fluids form a wide subset of the phases of matter that includes liquids, dense…

Statistical Mechanics · Physics 2022-07-12 Ihor Mryglod , Vasyl' Ignatyuk

Liquids generally become more ordered upon cooling. However, it has been a long-standing debate on whether such structural ordering in liquid water takes place continuously or discontinuosly: continuum vs. mixture models. Here, by computer…

Soft Condensed Matter · Physics 2020-02-25 Rui Shi , Hajime Tanaka

Using molecular dynamics simulations, we have determined that the nature of dynamical heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly attractive systems differ little from dense hard-sphere and…

Soft Condensed Matter · Physics 2007-05-23 David R. Reichman , Eran Rabani , Phillip L. Geissler

We investigate the structural properties of liquid water at near ambient conditions using first-principles molecular dynamics simulations based on a semilocal density functional augmented with nonlocal van der Waals interactions. The…

Soft Condensed Matter · Physics 2016-08-01 Giacomo Miceli , Stefano de Gironcoli , Alfredo Pasquarello

The dynamic slowdown in glass-forming liquids remains a central topic in condensed matter science. Here, we report a theoretical investigation of the microscopic origin of the slowdown in amorphous silica, a prototypical strong glass former…

Soft Condensed Matter · Physics 2026-05-27 Shubham Kumar , Zhiye Tang , Shinji Saito