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The factorized form of the unitary coupled-cluster approximation is one of the most promising methodologies to prepare trial states for strongly correlated systems within the variational quantum eigensolver framework. The factorized form of…

Quantum Physics · Physics 2022-01-05 Luogen Xu , Joseph T. Lee , J. K. Freericks

H\"uckel molecular orbital (HMO) theory provides a semi-empirical treatment of the electronic structure in conjugated {\pi}-electronic systems. A scalable system-agnostic execution of HMO theory on a quantum computer is reported here based…

Quantum Physics · Physics 2024-05-22 Harshdeep Singh , Sonjoy Majumder , Sabyashachi Mishra

Currently, quantum hardware is restrained by noises and qubit numbers. Thus, a quantum virtual machine that simulates operations of a quantum computer on classical computers is a vital tool for developing and testing quantum algorithms…

Quantum Physics · Physics 2022-06-10 Chuong Nguyen Quoc , Le Bin Ho , Lan Nguyen Tran , Hung Q. Nguyen

We describe the experimental implementation of a recently proposed quantum algorithm involving quantum entanglement at the level of two qubits using NMR. The algorithm solves a generalisation of the Deutsch problem and distinguishes between…

Quantum Physics · Physics 2009-11-06 Kavita Dorai , Arvind , Anil Kumar

We propose incorporating multi-qubit nonunitary operations in Variational Quantum Thermalizers (VQTs). VQTs are hybrid quantum-classical algorithms that generate the thermal (Gibbs) state of a given Hamiltonian, with applications in quantum…

Quantum Physics · Physics 2025-03-28 Elias Zapusek , Kristina Kirova , Walter Hahn , Michael Marthaler , Florentin Reiter

In this work, we study the projective quantum eigensolver (PQE) approach to optimizing unitary coupled cluster wave functions on quantum hardware, as introduced in arXiv:2102.00345. The projective quantum eigensolver is a hybrid…

Quantum Physics · Physics 2026-01-28 Martin Plazanet , Thomas Ayral

Strong/static electronic correlation mediates the emergence of remarkable phases of matter, and underlies the exceptional reactivity properties in transition metal-based catalysts. Modeling strongly correlated molecules and solids calls for…

Chemical Physics · Physics 2024-04-18 Carlos Mejuto-Zaera

We present a shuffle realization of the GKLO-type homomorphisms for shifted quantum affine, toroidal, and quiver algebras, thus generalizing its rational version of arXiv:2104.14518 and the type A construction of arXiv:1811.12137. As an…

Representation Theory · Mathematics 2023-02-20 Alexander Tsymbaliuk

A new basis adaptive algorithm for hybrid quantum-classical platforms is introduced to efficiently find the ground-state (gs) properties of quantum many-body systems. The method addresses limitations of many algorithms, such as Variational…

Strongly Correlated Electrons · Physics 2025-12-16 Anutosh Biswas , Sayan Ghosh , Ritajit Majumdar , Mostafizur Rahaman , Manoranjan Kumar

Quantum algorithms offer significant speedups over their classical counterparts for a variety of problems. The strongest arguments for this advantage are borne by algorithms for quantum search, quantum phase estimation, and Hamiltonian…

Quantum Physics · Physics 2021-12-14 John M. Martyn , Zane M. Rossi , Andrew K. Tan , Isaac L. Chuang

Quantum computers have the potential to help solve a range of physics and chemistry problems, but noise in quantum hardware currently limits our ability to obtain accurate results from the execution of quantum-simulation algorithms. Various…

Quantum Physics · Physics 2022-01-13 Eliott Rosenberg , Paul Ginsparg , Peter L. McMahon

We introduce the generative quantum eigensolver (GQE), a new quantum computational framework that operates outside the variational quantum algorithm paradigm by applying classical generative models to quantum simulation. The GQE algorithm…

Current universal quantum computers have a limited number of noisy qubits. Because of this, it is difficult to use them to solve large-scale complex optimization problems. In this paper we tackle this issue by proposing a quantum…

Quantum Physics · Physics 2023-06-30 Pablo Bermejo , Roman Orus

The VQE algorithm has turned out to be quite expensive to run given the way we currently access quantum processors (i.e. over the cloud). In order to alleviate this issue, we introduce Quantum Sampling Regression (QSR), an alternative…

Quantum Physics · Physics 2020-12-07 Pedro Rivero , Ian C. Cloët , Zack Sullivan

We introduce an optimisation method for variational quantum algorithms and experimentally demonstrate a 100-fold improvement in efficiency compared to naive implementations. The effectiveness of our approach is shown by obtaining…

Quantum computing brings a promise of new approaches into computational quantum chemistry. While universal, fault-tolerant quantum computers are still not available, we want to utilize today's noisy quantum processors. One of their flagship…

By allowing measurements of observables other than the state of the qubits in a quantum computer, one can find eigenvectors very quickly. If a unitary operation U is implemented as a time-independent Hamiltonian, for instance, one can…

Quantum Physics · Physics 2021-08-26 Michael Stay

Quantum computers promise to revolutionize our ability to simulate molecules, and cloud-based hardware is becoming increasingly accessible to a wide body of researchers. Algorithms such as Quantum Phase Estimation and the Variational…

Quantum Physics · Physics 2021-12-21 Kyle Sherbert , Frank Cerasoli , Marco Buongiorno Nardelli

Hybrid quantum-classical algorithms have been proposed to circumvent noise limitations in quantum computers. Such algorithms delegate only a calculation of the expectation value to the quantum computer. Among them, the Variational Quantum…

Strongly Correlated Electrons · Physics 2022-11-02 Baptiste Anselme Martin , Pascal Simon , Marko J. Rančić

Variational quantum algorithms involve training parameterized quantum circuits using a classical co-processor. An important variational algorithm, designed for combinatorial optimization, is the quantum approximate optimization algorithm.…

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