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We determine the fundamental electronic and optical properties of the high-thermal-conductivity III-V semiconductor boron arsenide (BAs) using density functional and many body perturbation theory including quasiparticle and spin-orbit…

Materials Science · Physics 2019-01-17 Kyle Bushick , Kelsey Mengle , Nocona Sanders , Emmanouil Kioupakis

Cubic boron arsenide (BAs) is an emerging semiconductor material with a record-high thermal conductivity of 1300 W/mK. However, many fundamental properties of BAs remain unexplored experimentally. Here, for the first time, we report the…

Materials Science · Physics 2019-11-27 Joon Sang Kang , Man Li , Huan Wu , Huuduy Nguyen , Yongjie Hu

Boron arsenide, the typically-ignored member of the III-V arsenide series BAs-AlAs-GaAs-InAs is found to resemble silicon electronically: its Gamma conduction band minimum is p-like (Gamma_15), not s-like (Gamma_1c), it has an X_1c-like…

Materials Science · Physics 2014-12-18 Gus L. W. Hart , Alex Zunger

Through first-principles calculations, the phonon-limited transport properties of cubic boron-V compounds (BP, BAs and BSb) are studied. We find that the high optical phonon frequency in these compounds leads to the substantial suppression…

Materials Science · Physics 2018-09-26 Te-Huan Liu , Bai Song , Laureen Meroueh , Zhiwei Ding , Qichen Song , Jiawei Zhou , Mingda Li , Gang Chen

We compute the electronic band structure and optical properties of boron arsenide using the relativistic quasiparticle self-consistent $GW$ approach, including electron-hole interactions through solution of the Bethe-Salpeter equation. We…

Materials Science · Physics 2019-06-07 John Buckeridge , David O. Scanlon

Recent measurements of an unusual high thermal conductivity of around 1000 W m-1 K-1 at room temperature in cubic boron arsenide (BAs) confirm predictions from theory and suggest potential applications of this semiconductor compound for…

Materials Science · Physics 2019-07-03 Xi Chen , Chunhua Li , Fei Tian , Geethal Amila Gamage , Sean Sullivan , Jianshi Zhou , David Broido , Zhifeng Ren , Li Shi

BAs is III-V semiconductor with ultra-high thermal conductivity, but many of its electronic properties are unknown. This work applies predictive atomistic calculations to investigate the properties of BAs heterostructures, such as strain…

Materials Science · Physics 2019-09-05 Kyle Bushick , Sieun Chae , Zihao Deng , John Heron , Emmanouil Kioupakis

The ultrahigh thermal conductivity of boron arsenide makes it a promising material for next-generation electronics and optoelectronics. In this work, we report measured optical properties of cubic boron arsenide crystals including the…

The electronic band structure of CaSnN$_2$ in the wurtzite-based $Pna2_1$ structure is calculated using the Quasiparticle Self-consistent (QS)GW$^{BSE}$ method, including ladder diagrams in the screened Coulomb interaction W$^{BSE}$ and is…

Materials Science · Physics 2026-04-20 Ilteris K. Turan , Sarker Md. Sadman , Walter R. L. Lambrecht

We report a comprehensive first-principles study of the electronic and optical properties of recently identified exfoliable one-dimensional semiconducting materials, focusing on chalcogenide-based atomic chains derived from van der…

Cubic boron arsenide (BAs) is a promising semiconductor for next-generation electronics due to its outstanding ambipolar mobility and thermal conductivity, the latter of which is attributed to the suppression of three-phonon scattering.…

For a wide class of technologically relevant compound III-V and II-VI semiconductor materials AC and BC mixed crystals (alloys) of the type A(x)B(1-x)C can be realized. As the electronic properties like the bulk band gap vary continuously…

Materials Science · Physics 2015-06-03 Daniel Mourad , Gerd Czycholl

Materials with high thermal conductivity are needed to conduct heat away from hot spots in high power electronics and optoelectronic devices. Cubic boron arsenide (c-BAs) has a high thermal conductivity due to its special phonon dispersion…

Excitonic Bose-Einstein condensation (EBEC) has drawn increasing attention recently with the emergence of 2D materials. A general criterion for EBEC, as expected in an excitonic insulator (EI) state, is to have negative exciton formation…

Strongly Correlated Electrons · Physics 2023-05-05 Gurjyot Sethi , Martin Cuma , Feng Liu

The quasiparticle band structure and optical properties of single-walled zigzag and armchair SiC nanotubes (SiC-NTs) as well as single SiC sheet are investigated by ab initio many-body calculations using the GW and the GW plus…

Mesoscale and Nanoscale Physics · Physics 2011-08-23 H. C. Hsueh , G. Y. Guo , Steven G. Louie

A first principles many-body approach is employed to calculate the band structure and optical response of nanometer sized ribbons of SiC. Many-body effects are incorporated using the GW approximation, and excitonic effects are included…

Materials Science · Physics 2016-02-25 Naresh Alaal , Vaideesh Loganathan , Nikhil Medhekar , Alok Shukla

Boron arsenide (BAs) with a zinc blende structure has recently been discovered to exhibit unusual and ultrahigh thermal conductivity (k), providing a new outlook for research on BAs and other high thermal conductivity materials. Technology…

The optical excitation spectra and excitonic resonances are investigated in systematically functionalized SiC with Fluorine and/or Chlorine utilizing density functional theory in combination with many-body perturbation theory. The latter is…

Materials Science · Physics 2017-11-22 L. B. Drissi , F. Z. Ramadan , S. Lounis

The high thermal conductivity of boron arsenide (BAs) makes it a promising material for optoelectronic applications in which thermal management is central. In this work, we study the finite temperature optoelectronic properties of BAs by…

Materials Science · Physics 2019-06-18 Ivona Bravić , Bartomeu Monserrat

Electrons and holes can spontaneously form excitons and condense in a semimetal or semiconductor, as predicted decades ago. This type of Bose condensation can happen at much higher temperatures in comparison with dilute atomic gases.…

Mesoscale and Nanoscale Physics · Physics 2023-02-24 Qiang Gao , Yang-hao Chan , Yuzhe Wang , Haotian Zhang , Jinxu Pu , Shengtao Cui , Yichen Yang , Zhengtai Liu , Dawei Shen , Zhe Sun , Juan Jiang , Tai C. Chiang , Peng Chen
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