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This paper presents a multiscale approach to evaluate perovskite solar cell performance which determines material properties at the atomistic scale with first-principles calculations, and applies them in macro-scale device models. This work…

Metal halide perovskites (MHPs) are gaining increasing attention as low-cost, high-performance semiconductors for optoelectronics. In particular, their solution processing is compatible with the large-scale manufacturing of thin-film…

Chemical Physics · Physics 2021-10-26 Junke Jiang , José Manuel Vicent-Luna , Shuxia Tao

Hexagonal perovskites with face-sharing octahedral connectivity are an underexplored class of materials. We propose quantitative design principles for stabilizing face-sharing ABX3 hexagonal perovskites based on a comparative analysis of…

Materials Science · Physics 2026-02-09 M. J. Swamynadhan , Gwan Yeong Jung , Pravan Omprakash , Rohan Mishra

Determining the finite temperature structure of the hybrid perovskite MAPbI3 is a challenge for both experimental and theoretical methods. A very powerful computational method that can resolve the atomic structure is molecular dynamics…

Materials Science · Physics 2018-07-25 Jonathan Lahnsteiner , Georg Kresse , Jurn Heinen , Menno Bokdam

Despite the rapid rise in perovskite solar cell efficiency, poor reproducibility remains a major barrier to commercialization. Film crystallization and device performance are highly sensitive to environmental factors during fabrication, yet…

Explainable machine learning can help to discover new physical relationships for material properties. To understand the material properties that govern the activation energy for oxygen diffusion in perovskites and pyrochlores, we build a…

Materials Science · Physics 2025-11-06 Grace M. Lu , Dallas R. Trinkle

Due to the subtle balance of intermolecular interactions that govern structure-property relations, predicting the stability of crystal structures formed from molecular building blocks is a highly non-trivial scientific problem. A…

Chemical Physics · Physics 2022-12-26 Rose K. Cersonsky , Maria Pakhnova , Edgar A. Engel , Michele Ceriotti

High-pressure phases of the hybrid perovskite MAPbBr3 have been investigated in detail using a novel machine learning force field (MLFF). MLFF simulations successfully reproduce the sequence of pressure-induced phase transitions from the…

Materials Science · Physics 2025-11-21 Rashid Rafeek V Valappil , Sayan Maity , Varadharajan Srinivasan

Lead halide perovskites are a remarkable class of materials that have emerged over the past decade as being suitable for application in a broad range of devices, such as solar cells, light-emitting diodes, lasers, transistors, and memory…

Applied Physics · Physics 2020-08-03 Katelyn P. Goetz , Alexander D. Taylor , Fabian Paulus , Yana Vaynzof

The potential of lead-halide perovskites for realistic applications is currently hindered by their limited long-term stability under functional activation. While the role of lattice flexibility in the thermal response of perovskites has…

Metal halides perovskites (MHPs) are attracting considerable interest for optoelectronic applications, with Cs$_2$AgBiBr$_6$ one of the main contenders among lead-free systems. Cs$_2$AgBiBr$_6$ crystallizes in a nominally double-perovskite…

The molybdate oxides SrMoO$_3$, PbMoO$_3$, and LaMoO$_3$ are a class of metallic perovskites that exhibit interesting properties including high mobility, and unusual resistivity behavior. We use first-principles methods based on density…

Materials Science · Physics 2021-08-20 Jeremy Lee-Hand , Alexander Hampel , Cyrus E. Dreyer

Main physical characteristics, crystal, magnetic and electronic structures, of cerium-based perovskites CeTmO3 [Tm3+ = Sc, Ti, V] are systematically investigated via the first-principles computations. Full-potential linear augmented…

Materials Science · Physics 2020-09-22 M. Musa Saad H. -E

Understanding the structural and magnetic properties in layered hybrid organic-inorganic metal halide perovskites (HOIPs) is key for their design and integration in spin-electronic devices. Here, we have conducted a systematic study on ten…

Spintronics in halide perovskites has drawn significant attention in recent years, due to highly tunable spin-orbit fields and intriguing interplay with lattice symmetry. Spin lifetime -- a key parameter that determines the applicability of…

Materials Science · Physics 2023-10-25 Junqing Xu , Kejun Li , Uyen N. Huynh , Jinsong Huang , Ravishankar Sundararaman , Valy Vardeny , Yuan Ping

With their celebrated structural and chemical flexibility, perovskite oxides have served as a highly adaptable material platform for exploring emergent phenomena arising from the interplay between different degrees of freedom. Molecular…

Materials Science · Physics 2023-11-16 Jing Wu , Jiyuan Yang , Yuan-Jinsheng Liu , Duo Zhang , Yudi Yang , Yuzhi Zhang , Linfeng Zhang , Shi Liu

Lead-halide perovskites are a promising material platform as semiconductors in next-generation solar cells because of their solution processability, defect tolerance, and tunable optoelectronic properties. While iodide-bromide perovskite…

Halide perovskites constitute a chemically-diverse class of crystals with great promise as photovoltaic absorber materials, featuring band gaps between about 1 and 3.5 eV depending on composition. Their diversity calls for a general…

Materials Science · Physics 2019-10-23 Linn Leppert , Tonatiuh Rangel , Jeffrey B. Neaton

Solar to power conversion certified efficiencies of formamidinium lead iodide based single-junction perovskite solar cell is now 26%, all perovskite-perovskite tandem $\sim$28%, and the perovskite-silicon tandem solar cell is $\sim$34%…

Materials Science · Physics 2023-06-27 Paramvir Ahlawat

Ba2CaMoO6 was synthesized by solid state method. The crystal structure adopts cubic Fm-3m space group at room temperature with lattice parameters of 8.378231(5) {angstroms}. Upon cooling, Ba2CaMoO6 was determined to have a structural phase…

Materials Science · Physics 2020-11-03 Loi T. Nguyen , Robert J. Cava , Allyson M. Fry-Petit