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Because most chemical or biological experiments are performed under conditions of controlled pressure and temperature, it is important to simulate the isobaric-isothermal ensemble at the atomic level to reveal the microscopic mechanism. By…

Statistical Mechanics · Physics 2025-04-14 Weihao Liang , Sihan Wang , Cong Wang , Weizhou Wang , Xinchen She , Chongbin Wang , Jiushu Shao , Jian Liu

Energy-based generative models, such as restricted Boltzmann machines (RBMs), require unbiased Boltzmann samples for effective training. Classical Markov chain Monte Carlo methods, however, converge slowly and yield correlated samples,…

Quantum Physics · Physics 2026-03-16 Gilhan Kim , Ju-Yeon Gyhm , Daniel K. Park

Bayesian feature allocation models are a popular tool for modelling data with a combinatorial latent structure. Exact inference in these models is generally intractable and so practitioners typically apply Markov Chain Monte Carlo (MCMC)…

Computation · Statistics 2020-01-28 Alexandre Bouchard-Côté , Andrew Roth

Machine learning has become a central technique for modeling in science and engineering, either complementing or as surrogates to physics-based models. Significant efforts have recently been devoted to models capable of predicting field…

Statistical Mechanics · Physics 2024-12-06 Brian H. Lee , Kat Nykiel , Ava E. Hallberg , Brice Rider , Alejandro Strachan

Generative Bayesian Filtering (GBF) provides a powerful and flexible framework for performing posterior inference in complex nonlinear and non-Gaussian state-space models. Our approach extends Generative Bayesian Computation (GBC) to…

Methodology · Statistics 2025-11-07 Edoardo Marcelli , Sean O'Hagan , Veronika Rockova

We investigate the possibility of discrete groups furnishing a kinematic framework for systems whose thermodynamic behaviour may be given by non-additive entropies. Relying on the well-known result of the growth rate of balls of nilpotent…

Statistical Mechanics · Physics 2015-06-19 Nikos Kalogeropoulos

The present paper is a review of the phenomena related to non-equilibrium electron relaxation in bulk and nano-scale metallic samples. The workable Two-Temperature Model (TTM) based on Boltzmann-Bloch-Peierls (BBP) kinetic equation has been…

Statistical Mechanics · Physics 2009-03-23 Navinder Singh

Inexpensive machine learning potentials are increasingly being used to speed up structural optimization and molecular dynamics simulations of materials by iteratively predicting and applying interatomic forces. In these settings, it is…

Chemical Physics · Physics 2023-09-12 Jonas Busk , Mikkel N. Schmidt , Ole Winther , Tejs Vegge , Peter Bjørn Jørgensen

We introduce a non-linear differential flow equation for density matrices that provides a monotonic decrease of the free energy and reaches a fixed point at the Gibbs thermal state. We use this equation to build a variational approach for…

Superconductivity · Physics 2020-11-04 Tao Shi , Eugene Demler , J. Ignacio Cirac

We develop two cutting-edge approaches to construct deep neural networks representing the purified finite-temperature states of quantum many-body systems. Both methods commonly aim to represent the Gibbs state by a highly expressive…

Strongly Correlated Electrons · Physics 2021-08-10 Yusuke Nomura , Nobuyuki Yoshioka , Franco Nori

The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…

Statistical Mechanics · Physics 2020-07-01 Sheldon Goldstein , Joel L. Lebowitz , Roderich Tumulka , Nino Zanghi

Grain boundary (GB) properties greatly influence the mechanical, electrical, and thermal response of polycrystalline materials. Most computational studies of GB properties at finite temperatures use molecular dynamics (MD), which is…

Materials Science · Physics 2025-06-06 Miguel Spínola , Shashank Saxena , Prateek Gupta , Brandon Runnels , Dennis M. Kochmann

By molecular dynamics simulations and free energy calculations based on Monte Carlo method, the detailed balance between Pt cluster isomers was investigated. For clusters of n<=50, stationary equilibrium is achieved in 100 ns in the…

Chemical Physics · Physics 2014-12-16 Zheng-Zhe Lin

In this article we focus on kinetic equations for gas mixtures since in applications one often has to deal with mixtures instead of a single gas. In particular we consider an approximation of the Boltzmann equation, the…

Analysis of PDEs · Mathematics 2022-03-30 Marlies Pirner , Sandra Warnecke

We introduce what we call the second-order Boltzmann-Gibbs principle, which allows to replace local functionals of a conservative, one-dimensional stochastic process by a possibly nonlinear function of the conserved quantity. This…

Probability · Mathematics 2015-06-17 Patricia Gonçalves , Milton Jara

Gaussian Boson Sampling (GBS) generate random samples of photon-click patterns from a class of probability distributions that are hard for a classical computer to sample from. Despite heroic demonstrations for quantum supremacy using GBS,…

Quantum Physics · Physics 2024-02-07 Mushkan Sureka , Saikat Guha

Phase diagrams serve as a highly informative tool for materials design, encapsulating information about the phases that a material can manifest under specific conditions. In this work, we develop a method in which Bayesian inference is…

Materials Science · Physics 2023-09-06 Timofei Miryashkin , Olga Klimanova , Vladimir Ladygin , Alexander Shapeev

The preparation of quantum Gibbs states at finite temperatures is a cornerstone of quantum computation, enabling applications in quantum simulation of many-body systems, machine learning via quantum Boltzmann machines, and optimization…

Quantum Physics · Physics 2026-04-17 Rui-Hao Li , Semeon Valgushev , Khadijeh Najafi

Generative diffusion models have achieved spectacular performance in many areas of machine learning and generative modeling. While the fundamental ideas behind these models come from non-equilibrium physics, variational inference and…

Machine Learning · Statistics 2024-06-21 Luca Ambrogioni

In this paper we discuss how the information contained in atomistic simulations of homogeneous nucleation should be used when fitting the parameters in macroscopic nucleation models. We show how the number of solid and liquid atoms in such…

Statistical Mechanics · Physics 2017-10-11 Bingqing Cheng , Gareth A. Tribello , Michele Ceriotti