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We propose a numerical scheme to solve the time dependent linear Schr\"odinger equation. The discretization is carried out by combining a Runge-Kutta time-stepping scheme with a finite element discretization in space. Since the…

Numerical Analysis · Mathematics 2018-03-07 Jens Markus Melenk , Alexander Rieder

We report the implementation of equation-of-motion coupled-cluster (EOMCC) method in the four-component relativistic framework with the spherical atomic potential to generate the excited states from a closed-shell atomic configuration. This…

Atomic Physics · Physics 2015-06-19 D. K. Nandy , Yashpal Singh , B. K. Sahoo

In this paper, we present a comprehensive account of quantum dissipation theories with the quadratic environment couplings. The theoretical development includes the Brownian solvation mode embedded hierarchical quantum master equations, a…

Quantum Physics · Physics 2023-02-07 Zi-Hao Chen , Yao Wang , Rui-Xue Xu , YiJing Yan

We discuss the analytic and diagrammatic structure of ionization potential (IP) and electron affinity (EA) equation-of-motion coupled-cluster (EOM-CC) theory, in order to put it on equal footing with the prevalent $GW$ approximation. The…

Chemical Physics · Physics 2019-04-16 Malte F. Lange , Timothy C. Berkelbach

The implementation of the discrete adjoint method for exponential time differencing (ETD) schemes is considered. This is important for parameter estimation problems that are constrained by stiff time-dependent PDEs when the discretized PDE…

Optimization and Control · Mathematics 2016-10-11 Kai Rothauge , Eldad Haber , Uri Ascher

We present a cost-effective treatment of the triple excitation amplitudes in the time-dependent optimized coupled-cluster (TD-OCC) framework called TD-OCCDT(4) for studying intense laser-driven multielectron dynamics. It considers triple…

Chemical Physics · Physics 2021-07-07 Himadri Pathak , Takeshi Sato , Kenichi L. Ishikawa

When a time propagator $e^{\delta t A}$ for duration $\delta t$ consists of two noncommuting parts $A=X+Y$, Trotterization approximately decomposes the propagator into a product of exponentials of $X$ and $Y$. Various Trotterization…

Quantum Physics · Physics 2023-11-08 Tatsuhiko N. Ikeda , Asir Abrar , Isaac L. Chuang , Sho Sugiura

In the present work, a new time-dependent exchange theory is presented wherein the symmetry constraints, on a multi-electron wavefunction, are properly accounted for. In so doing, the equations of motion, incorporating the required…

Computational Physics · Physics 2007-05-23 Charles A. Weatherford

We propose an efficient algorithmic framework for time domain circuit simulation using exponential integrator. This work addresses several critical issues exposed by previous matrix exponential based circuit simulation research, and makes…

Computational Engineering, Finance, and Science · Computer Science 2016-11-17 Hao Zhuang , Wenjian Yu , Ilgweon Kang , Xinan Wang , Chung-Kuan Cheng

Integrals of motion and statistical properties of quantized electromagnetic field (e.-m. field) in time-dependent linear dielectric and conductive media are considered, using Choi-Yeon quantization, based on Caldirola-Kanai type…

Quantum Physics · Physics 2015-04-08 A. K. Angelow , D. A. Trifonov

We present a time-dependent extension of logarithmic perturbation theory for nonrelativistic quantum dynamics governed by the Schr\"odinger equation, in which the logarithm of the wave function is expanded in powers of a coupling constant.…

Quantum Physics · Physics 2026-04-17 Juan Carlos del Valle , Paul Bergold , Karolina Kropielnicka

The Schroedinger equation with an energy-dependent complex absorbing potential, associated with a scattering system, can be reduced for a special choice of the energy-dependence to a harmonic inversion problem of a discrete pseudo-time…

Chemical Physics · Physics 2009-11-07 A. Neumaier , V. A. Mandelshtam

Hamiltonian simulation is a central task in quantum computing, with wide-ranging applications in quantum chemistry, condensed matter physics, and combinatorial optimization. A fundamental challenge lies in approximating the unitary…

Quantum Physics · Physics 2025-05-15 Molena Nguyen , Naihuan Jing

In this work, we introduce new integral formulations based on the convolution quadrature method for the time-domain modeling of perfectly electrically conducting scatterers that overcome some of the most critical issues of the standard…

Numerical Analysis · Mathematics 2023-11-28 Pierrick Cordel , Alexandre Dély , Adrien Merlini , Francesco P. Andriulli

Representing the time-evolution operator as a tensor network constitutes a key ingredient in several algorithms for studying quantum lattice systems at finite temperature or in a non-equilibrium setting. For a Hamiltonian composed of…

Strongly Correlated Electrons · Physics 2026-02-26 Sander De Meyer , Atsushi Ueda , Yuchi He , Nick Bultinck , Jutho Haegeman

This report discusses two new ideas for using perturbation methods to solve the time-independent Schr\"odinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix…

Quantum Physics · Physics 2013-10-25 Gerald I. Kerley

We derive the coupled-cluster doubles (CCD) amplitude equations by introduction of the particle-hole-time decoupled electronic self-energy. The resulting analysis leads to an expression for the ground state correlation energy that is…

Strongly Correlated Electrons · Physics 2025-09-09 Christopher J. N. Coveney

The construction of quantum computer simulators requires advanced software which can capture the most significant characteristics of the quantum behavior and quantum states of qubits in such systems. Additionally, one needs to provide valid…

We propose new methods designed to numerically approximate the solution to the time dependent Schr{\"o}dinger equation, based on two types of ansatz: tensors, and approximation by a linear combination of gaussian wave packets. In both…

Analysis of PDEs · Mathematics 2025-09-17 Mi-Song Dupuy , Virginie Ehrlacher , Clément Guillot

The electron attachment variant of equation-of-motion coupled-cluster theory (EOM-EA-CC) is generalized to the case of strong light-matter coupling within the framework of cavity quantum electrodynamics (QED). The resulting EOM-EA-QED-CC…

Chemical Physics · Physics 2022-02-23 Marcus D. Liebenthal , Nam Vu , A. Eugene DePrince