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Although most two-dimensional (2D) materials are non-ferroelectric with highly symmetric lattices, symmetry breaking may take place in their bilayers upon certain stacking order, giving rise to so-called sliding ferroelectricity where the…

Mesoscale and Nanoscale Physics · Physics 2023-04-10 Liu Yang , Menghao Wu

Ferroelectricity is intriguing for its spontaneous electric polarization, which is switchable by an external electric field. Expanding ferroelectric materials to two-dimensional limit will provide versatile applications for the development…

Mesoscale and Nanoscale Physics · Physics 2024-04-05 Le Zhang , Jing Ding , Hanxiao Xiang , Naitian Liu , Wenqiang Zhou , Linfeng Wu , Na Xin , Kenji Watanabe , Takashi Taniguchi , Shuigang Xu

Two-dimensional ferroelectrics can maintain vertical polarization up to room temperature, and are, therefore, promising for next-generation nonvolatile memories. Although natural two-dimensional ferroelectrics are few, moir\'{e}…

Mesoscale and Nanoscale Physics · Physics 2024-04-30 Renjun Du , Jingkuan Xiao , Di Zhang , Xiaofan Cai , Siqi Jiang , Fuzhuo Lian , Kenji Watanabe , Takashi Taniguchi , Lei Wang , Geliang Yu

Interfacial ferroelectricity emerges in heterostructures consisting of nonpolar van der Waals (vdW) layers, greatly expanding the scope of two dimensional ferroelectrics. In particular, the unconventional moire ferroelectricity observed in…

Ferroelectricity (Valasek, J. Phys. Rev. 1921, 17, 475) - a spontaneous formation of electric polarisation - is a solid state phenomenon, usually, associated with ionic compounds or complex materials. Here we show that, atypically for…

Materials Science · Physics 2023-05-29 Aitor Garcia-Ruiz , Vladimir Enaldiev , Andrew McEllistrim , Vladimir I. Fal'ko

When the atomic layers in a non-centrosymmetric van der Waals structure slide against each other, the interfacial charge transfer results in a reversal of the structures spontaneous polarization. This phenomenon is known as sliding…

According to the recent studies on sliding/moire ferroelectricity, most 2D van der Waals nonferroelectric monolayers can become ferroelectric via multilayer stacking. In this paper we propose that similar strategy can be used to induce…

Materials Science · Physics 2025-07-24 Yuxuan Sheng , Junwei Liu , Jia Zhang , Menghao Wu

A ferroelectric is a material with a polar structure whose polarity can be reversed by applying an electric field. In metals, the itinerant electrons tend to screen electrostatic forces between ions, helping to explain why polar metals are…

2D ferroelectrics with robust polarization down to atomic thicknesses provide novel building blocks for functional heterostructures. Experimental reports, however, remain scarce because of the requirement of a layered polar crystal. Here,…

Mesoscale and Nanoscale Physics · Physics 2021-06-04 Kenji Yasuda , Xirui Wang , Kenji Watanabe , Takashi Taniguchi , Pablo Jarillo-Herrero

Low dimensional ferroelectrics are highly desired for applications and full of exotic physics. Here a functionalized MXene Hf$_2$CF$_2$ monolayer is theoretically studied, which manifests a nonpolar to polar transition upon moderate biaxial…

Materials Science · Physics 2021-11-17 Ziwen Wang , Ning Ding , Churen Gui , Shanshan Wang , Ming An , Shuai Dong

Going beyond the bistability paradigm of the charge polarizations in ferroelectrics is highly desired for ferroelectric (FE) memory devices toward ultra-high-density information storage. Here, we propose to build multistates by combining…

Materials Science · Physics 2025-03-03 Chuhan Tang , Zhiqiang Tian , Tao Ouyang , Anlian Pan , Mingxing Chen

Through stacking engineering of two-dimensional (2D) materials, a switchable interface polarization can be generated through interlayer sliding, so called sliding ferroelectricity, which is advantageous over the traditional ferroelectricity…

Materials Science · Physics 2024-08-01 Qingrong Liang , Guozhong Zheng , Liu Yang , Shoujun Zheng

Two-dimensional (2D) ferroelectrics, which is rare in nature, enable high-density non-volatile memory with low energy consumption. Here, we propose a theory of bilayer stacking ferroelectricity (BSF), in which, two stacked layers of the…

Materials Science · Physics 2023-04-19 Junyi Ji , Changsong Xu , H. J. Xiang

The synergy of ferroicity with altermagnetism offers a novel platform for designing multifunctional altermagnetic-spintronic device technology. In this work, we propose a mechanism to achieve nonvolatile electrical manipulation of spin and…

Materials Science · Physics 2026-03-12 Rui Peng , Guangxu Su , Yangyang Fan , Jiaan Li , Fanxin Liu , Yee Sin Ang

Understanding the nature of sliding ferroelectricity is of fundamental importance for the discovery and application of two-dimensional ferroelectric materials. In this work, we investigate the phenomenon of switchable polarization in a…

Mesoscale and Nanoscale Physics · Physics 2023-11-22 Dongyang Yang , Jing Liang , Jingda Wu , Yunhuan Xiao , Jerry I. Dadap , Kenji Watanabe , Takashi Taniguchi , Ziliang Ye

Bilayers of two-dimensional van der Waals materials that lack an inversion centre can show a novel form of ferroelectricity, where certain stacking arrangements of the two layers lead to an interlayer polarization. Under an external…

Superconductivity · Physics 2024-06-27 Gaurav Chaudhary , Ivar Martin

We propose ferroelectric layer sliding as a new approach to realize and manipulate topological quantum states in two-dimensional (2D) bilayer magnetic van der Waals materials. We show that stacking monolayer ferromagnetic topological states…

Materials Science · Physics 2025-08-13 Ning-Jing Yang , Jian-Min Zhang , Xiao-Ping Li , Zeying Zhang , Zhi-Ming Yu , Zhigao Huang , Yugui Yao

Two-dimensional sliding ferroelectrics, with their unique stacking degrees of freedom, offer a different approach to manipulate polarization by interlayer sliding. Bending sliding ferroelectrics inevitably leads to interlayer sliding…

Materials Science · Physics 2024-08-02 Ri He , Hua Wang , Fenglin Deng , Yuxiang Gao , Binwen Zhang , Yubai Shi , Run-Wei Li , Zhicheng Zhong

Two-dimensional materials with ferroelectric properties break the size effect of conventional ferroelectric materials and unlock unprecedented potentials of ferroelectric-related application at small length scales. In this work, using…

Materials Science · Physics 2022-03-25 Bo Xu , Junkai Deng , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

Sliding ferroelectrics built from stacked nonpolar monolayers enable out-of-plane polarization and unconventional switching via interlayer sliding, yet the microscopic sliding dynamics remain unclear. Using machine-learning molecular…

Materials Science · Physics 2026-04-23 Jia-Wen Li , Sheng Meng , Xinghua Shi , Jin Zhang , Wei-Hai Fang
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