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Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields within nano-metric volumes. As a consequence, the molecules experience a remarkably strong interaction with the electromagnetic field, to such an extent…

Chemical Physics · Physics 2021-09-01 Jacopo Fregoni , Tor S. Haugland , Silvio Pipolo , Tommaso Giovannini , Henrik Koch , Stefano Corni

Preferential selection of a given enantiomer over its chiral counterpart becomes increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to…

Quantum Physics · Physics 2023-04-14 Christian Schäfer , Denis G. Baranov

We introduce crystal polaritons, hybrid excitations formed when the collective excitations of a periodic quantum-emitter array strongly couple to the resonant Bloch modes of a metasurface. This realizes a cavity-QED platform in which…

Cavity quantum electrodynamics provides a powerful tool to manipulate material properties, yet it remains a matter of debate whether and how quantized fields affect the periodicity of crystals. Here, we extend Bloch's theorem to crystals…

Materials Science · Physics 2026-01-14 Giovanna Bruno , Rosario Roberto Riso , Henrik Koch , Enrico Ronca

The derivation of linear response theory within polarizable embedding is carried out from a rigorous quantum-mechanical treatment of a composite system. Two different subsystem decompositions (symmetric and nonsymmetric) of the linear…

Chemical Physics · Physics 2017-10-09 Nanna Holmgaard List , Patrick Norman , Jacob Kongsted , Hans Jørgen Aagaard Jensen

We formulate a full quantum mechanical theory of the interaction between electromagnetic modes in photonic crystal slabs and quantum well excitons embedded in the photonic structure. We apply the formalism to a high index dielectric layer…

Soft Condensed Matter · Physics 2009-11-10 D. Gerace , M. Agio , L. C. Andreani

Strong light-matter interactions in both the single-emitter and collective strong coupling regimes attract significant attention due to emerging quantum and nonlinear optics applications, as well as opportunities for modifying…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Tuomas P. Rossi , Timur Shegai , Paul Erhart , Tomasz J. Antosiewicz

The field of 2D materials-based nanophotonics has been growing at a rapid pace, triggered by the ability to design nanophotonic systems with in situ control, unprecedented degrees of freedom, and to build material heterostructures from…

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

This paper provides explicit and detailed quantum field theory (QFT) computations of polarizations correlations of emerging particles in several processes in QED, Electroweak Theory, and even in particle productions from strings, and hence…

High Energy Physics - Theory · Physics 2013-09-10 N. Yongram , E. B. Manoukian

A reduced-density-matrix (RDM)-based approach to {\em ab initio} cavity quantum electrodynamics (QED) is developed. The expectation value of the Pauli-Fierz Hamiltonian is expressed in terms of one- and two-body electronic and photonic…

Chemical Physics · Physics 2022-11-23 Joel D. Mallory , A. Eugene DePrince

Condensed matter physics and quantum electrodynamics (QED) have been long considered as distinct disciplines. This situation is changing by the progress in cavity QED materials. Motivated by these advances we aim to bridge these fields by…

Quantum Physics · Physics 2022-01-06 Vasil Rokaj

Quantum-matter theory (QMT), based on the Schr\"odinger or Dirac equations, is firmly established for both intra- and intermolecular interactions. However, there are two key issues with QMT. First, its applicability to large molecular…

Chemical Physics · Physics 2026-03-19 Reza Karimpour , Matteo Gori , Alexandre Tkatchenko

We construct a model describing the response of a hybrid system where the electromagnetic field - in particular, surface plasmon polaritons - couples strongly with electronic excitations of atoms or molecules. Our approach is based on the…

Quantum Physics · Physics 2020-01-01 K. S. U. Kansanen , A. Asikainen , J. J. Toppari , G. Groenhof , T. T. Heikkilä

One of the overarching goals of nuclear physics is to rigorously compute properties of hadronic systems directly from the fundamental theory of strong interactions, Quantum Chromodynamics (QCD). In particular, the hope is to perform…

High Energy Physics - Lattice · Physics 2015-06-22 Raúl A. Briceño , Zohreh Davoudi , Thomas C. Luu

Exciton-polaritons are hybrid elementary excitations of light and matter that, thanks to their nonlinear properties, enable a plethora of physical phenomena ranging from room temperature condensation to superfluidity. While polaritons are…

Mesoscale and Nanoscale Physics · Physics 2022-03-23 Davide Nigro , Vincenzo D'Ambrosio , Daniele Sanvitto , Dario Gerace

Light-matter interaction not only plays an instrumental role in characterizing materials' properties via various spectroscopic techniques but also provides a general strategy to manipulate material properties via the design of novel…

Chemical Physics · Physics 2023-08-30 Braden M. Weight , Xinyang Li , Yu Zhang

The formation of the composite photonic-excitonic particle, known as a polariton, is a phenomenon emerging in materials possessing strong coupling to light. The organic-based materials besides the strong light-matter coupling also…

Chemical Physics · Physics 2023-01-19 Vladimir Al. Osipov , Boris Fainberg

We present a first-principles approach for calculating phonon-polariton dispersion relations. In this approach, phonon-photon interaction is described by quantization of a Hamiltonian that describes harmonic lattice vibrations coupled with…

Materials Science · Physics 2026-01-13 Olle Hellman , Leeor Kronik